Palladium, ruthenium on alumina

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Palladium, ruthenium on alumina
• 英文别名: palladium;ruthenium
• 化学式: Pd₀Ru₀
• 分子量: 105.885
• InChiKey: OYJSZRRJQJAOFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  [Pd(Py)₄][RuNO(NO₂)₄OH] 生成 Palladium, ruthenium on alumina
  参考文献：
  名称：

  双络合物盐[PdL4] [RuNO（NO2）4OH]（L = NH3，Py）的合成，结构及双金属亚稳态固溶体Pd0.5Ru0.5的制备

  摘要：

  摘要制备了两种含[RuNO（NO2）4OH] 2-阴离子和[PdL4] 2+阳离子（L = NH3，Py）的双络合物盐，并用红外光谱，单晶和粉末XRD对其进行了描述。两种化合物的晶体结构均由复杂的钯阳离子和复杂的钌阴离子组成。在[Pd（NH3）4] [RuNO（NO2）4OH]阳离子和阴离子被NH3和NO2配体之间的氢键结合的情况。在惰性和还原性气氛下检查了盐的热分解。两种络合物都在几个阶段分解，根据IR光谱的第一阶段包括阴离子的OH基团的裂解，进一步的分解经历了NH 3和NO 2配体的去除。在[Pd（NH3）4] [RuNO（NO2）4OH]的情况下，还原性气氛中热分解的最终温度为250–270°C，最终产物对应于亚稳的Pd0.5Ru0.5固溶体。通过XRD和EDX数据确认了金属固溶体的组成。检查了制备的固溶体的电化学和催化性能。

  DOI：

  10.1016/j.poly.2018.11.065

文献信息

• Sub-5 nm Pd-Ru Nanoparticle Alloys as Efficient Catalysts for Formic Acid Electrooxidation
  作者：Dongshuang Wu、Minna Cao、Min Shen、Rong Cao

  DOI：10.1002/cctc.201400086

  日期：2014.6

  However, Pd–Ru nanoparticle (NP) alloys are rarely reported so far, owing to the limitations described by Hume‐Rothery. Herein, we successfully synthesized Pd–Ru NP alloys over the whole composition range using a facile atomic‐diffusion‐based strategy, and we carefully investigated the corresponding formation mechanism. For the first time, we confined the size of all alloy NPs at 3–5 nm, which is

  Pd和Ru都是电化学中的重要元素。然而，由于休姆-雷特里（Hume-Rothery）所描述的局限性，迄今为止，极少报道Pd-Ru纳米粒子（NP）合金。在这里，我们使用一种基于原子扩散的策略成功地合成了整个组成范围内的Pd-Ru NP合金，并仔细研究了相应的形成机理。我们首次将所有合金纳米颗粒的尺寸限制在3-5 nm，这在直接甲酸燃料电池中是有利的。实验数据表明，由于电子从Pd转移到Ru，Pd的核心能级结合能正向移动。这种电子效应可以有效地调节电催化过程中反应性分子的吸附强度。在所有这些影响的驱使下，这些Pd-Ru合金具有很高的活性，并且对甲酸氧化稳定。组成-活性研究进一步表明，Pd60 Ru 40表现出最好的质量活性，是商业Pd / C的4.1倍。
• Double complex salts [M(NH3)5Cl][M′Br4] (M = Rh, Ir, Co, Cr, Ru; M′ = Pt, Pd): Synthesis, x-ray diffraction characterization, and thermal properties
  作者：Yu. V. Shubin、A. V. Zadesenets、A. B. Venediktov、S. V. Korenev

  DOI：10.1134/s0036023606020070

  日期：2006.2

  Double complex salts (DCSs) with [M(NH3)(5)Cl](2+) (M = Rh, Ir, Co, Cr, Ru) cations and [PtBr4](2-) anions were prepared in high yields. The salts were two-phase mixtures of the anhydrous and monohydro DCSs. Anhydrous analogues containing [PdBr4](2-) anions with M = Cr or Ru were synthesized. All the compounds were characterized using a set of physicochemical methods. The crystal structure of chloropentaamminechromium(III) tetrabromopalladate(II) was solved: space group Pnma, Z = 4, a = 17.068(2) angstrom, b = 8.315(12) angstrom, c = 9.653(14) angstrom. The [M(NH3)(5)Cl][M'X-4] (M = Rh, Ir, Co, Cr, Ru; M' = Pd, Pt; X = Cl, Br) compounds were shown to be isostructural. The [M(NH3)(5)Cl][PtBr4] center dot H2O monohydrates are isostructural to the [M(NH3)(5)Cl][PdCl4] center dot H2O monohydrates (space group P2(1)/c, z = 4). The properties of the compounds were comparatively analyzed. The tendencies of the thermal stability of the complexes were elucidated. The thermolysis products of the double complex salts obtained under a helium or hydrogen atmosphere were studied.
• Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability
  作者：Kohei Kusada、Hirokazu Kobayashi、Ryuichi Ikeda、Yoshiki Kubota、Masaki Takata、Shoichi Toh、Tomokazu Yamamoto、Syo Matsumura、Naoya Sumi、Katsutoshi Sato、Katsutoshi Nagaoka、Hiroshi Kitagawa

  DOI：10.1021/ja409464g

  日期：2014.2.5

  PdxRu1-x solid solution alloy nanoparticles were successfully synthesized over the whole composition range through a chemical reduction method, although Ru and Pd are immiscible at the atomic level in the bulk state. From the XRD measurement, it was found that the dominant structure of PdxRu1-x changes from fcc to hcp with increasing Ru content. The structures of PdxRu1-x nanoparticles in the Pd composition range of 30-70% consisted of both solid solution fcc and hcp structures, and both phases coexist in a single particle. In addition, the reaction of hydrogen with the PdxRu1-x nanoparticles changed from exothermic to endothermic as the Ru content increased. Furthermore, the prepared PdxRu1-x nanoparticles demonstrated enhanced CO-oxidizing catalytic activity; Pd0.5Ru0.5 nanoparticles exhibit the highest catalytic activity. This activity is much higher than that of the practically used CO-oxidizing catalyst Ru and that of the neighboring Rh, between Ru and Pd.
• Shubin; Korenev, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 11, p. 1663 - 1667
  作者：Shubin、Korenev

  DOI：——

  日期：——
• Double complex salts [PdL4][RuNO(NO2)4OH] (L = NH3, Py) synthesis, structure and preparation of bimetallic metastable solid solution Pd0.5Ru0.5
  作者：G.A. Kostin、P.E. Plyusnin、E. Yu. Filatov、N.V. Kuratieva、A.A. Vedyagin、D.B. Kal'nyi

  DOI：10.1016/j.poly.2018.11.065

  日期：2019.2

  Abstract Two double complex salts containing [RuNO(NO2)4OH]2− anion and [PdL4]2+ cations (L = NH3, Py) were prepared and described by IR-spectroscopy, single crystal and powder XRD. The crystal structure of both compounds is composed by complex palladium cations and complex ruthenium anions. In case of [Pd(NH3)4][RuNO(NO2)4OH] cations and anions are bounded by hydrogen bonds between NH3 and NO2 ligands

  摘要制备了两种含[RuNO（NO2）4OH] 2-阴离子和[PdL4] 2+阳离子（L = NH3，Py）的双络合物盐，并用红外光谱，单晶和粉末XRD对其进行了描述。两种化合物的晶体结构均由复杂的钯阳离子和复杂的钌阴离子组成。在[Pd（NH3）4] [RuNO（NO2）4OH]阳离子和阴离子被NH3和NO2配体之间的氢键结合的情况。在惰性和还原性气氛下检查了盐的热分解。两种络合物都在几个阶段分解，根据IR光谱的第一阶段包括阴离子的OH基团的裂解，进一步的分解经历了NH 3和NO 2配体的去除。在[Pd（NH3）4] [RuNO（NO2）4OH]的情况下，还原性气氛中热分解的最终温度为250–270°C，最终产物对应于亚稳的Pd0.5Ru0.5固溶体。通过XRD和EDX数据确认了金属固溶体的组成。检查了制备的固溶体的电化学和催化性能。