diaminochlorotriazine | 1314910-56-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: diaminochlorotriazine
• 英文别名: 6-chlorotriazine-4,5-diamine
• CAS: 1314910-56-9
• 化学式: C₃H₄ClN₅
• mdl: MFCD19205784
• 分子量: 145.551
• InChiKey: YBGBJEGPLMRYPL-UHFFFAOYSA-N

物化性质

• 沸点：
  388.5±52.0 °C(Predicted)
• 密度：
  1.700±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  90.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  diaminochlorotriazine 、 二甘醇胺 以 sodium hydroxide 、 水 为溶剂， 生成 2-[2-[(4,6-二氨基-1,3,5-三嗪-2-基)氨基]乙氧基]乙醇
  参考文献：
  名称：

  Hydroxyoxaalkylmelamines

  摘要：

  通式I的羟基氧杂烷基三聚胺，其中基团R可以相同也可以不同，每个基团为氢或通式II中的基团H--(--O--CHR'--CHR'--)--.sub.n (II)，其中基团R'可以相同也可以不同，每个基团为氢或C.sub.1 -C.sub.4 -烷基，n为2或3，以及这些混合物，可用于尿素酯的制备和改性氨基酸树脂。

  公开号：

  US04886882A1

文献信息

• Melamine derivatives as stabilizers for chloride-containing polymers
  申请人：Ciba-Geigy Corporation

  公开号：US05272192A1

  公开（公告）日：1993-12-21

  Compositions containing a) a chlorine-containing polymer, b) 0.01 to 1% by weight, relative to the chlorine-containing polymer, of a compound of the formula I and/or its hydrochloride, ##STR1## in which R is C.sub.6 -C.sub.20 alkyl, C.sub.3 -C.sub.20 alkyl interrupted by 1 to 5 oxygen atoms, C.sub.1 -C.sub.20 alkyl substituted by 1 to 5 OH, C.sub.3 -C.sub.20 alkenyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.3 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.11 phenylalkyl, C.sub.7 -C.sub.11 phenylalkyl which is substituted on the phenyl by 1 to 3 radicals, these radicals, independently of one another, being hydroxyl, chlorine, C.sub.1 -C.sub.4 alkyl, methoxy or ethoxy, or R is furthermore a group of the formula IIa or IIb, ##STR2## in which X is C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.20 alkylthio, phenyloxy, phenylthio, benzyloxy or benzylthio, and R.sub.1, R.sub.2 and R.sub.3, independently of one another, are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.20 alkythio, C.sub.2 -C.sub.12 alkyloxycarbonyl, C.sub.2 -C.sub.12 alkanoyl, phenyl, phenyloxy, phenylthio, hydroxyl, mercapto or chlorine, and c) 0.01 to 5% by weight, relative to the chlorine-containing polymer, of an Me(II) carboxylate and/or Me(II)-phenolate, in which Me(II) is Ba, Ca, Mg, Cd or Zn. Some of the compounds of the formula I are novel.

  本发明涉及一种组合物，包含a)含氯聚合物，b)相对于含氯聚合物重量为0.01至1％的化合物I式和/或其盐酸盐，其中R为C.sub.6-C.sub.20烷基，C.sub.3-C.sub.20被1至5个氧原子中断的烷基，C.sub.1-C.sub.20被1至5个OH取代的烷基，C.sub.3-C.sub.20烯基，C.sub.3-C.sub.8环烷基，C.sub.1-C.sub.4烷基取代的C.sub.3-C.sub.8环烷基，C.sub.7-C.sub.11苯基烷基，C.sub.7-C.sub.11苯基烷基在苯环上被1至3个基团取代，这些基团独立地是羟基、氯、C.sub.1-C.sub.4烷基、甲氧基或乙氧基，或R还是IIa或IIb式的基团，其中X是C.sub.1-C.sub.20烷氧基、C.sub.1-C.sub.20烷硫基、苯氧基、苯硫基、苄氧基或苄硫基，R.sub.1、R.sub.2和R.sub.3独立地是氢、C.sub.1-C.sub.20烷基、C.sub.1-C.sub.20烷氧基、C.sub.1-C.sub.20烷硫基、C.sub.2-C.sub.12烷氧羰基、C.sub.2-C.sub.12烷酰基、苯基、苯氧基、苯硫基、羟基、巯基或氯，以及c)相对于含氯聚合物重量为0.01至5％的Me（II）羧酸盐和/或Me（II）酚盐，其中Me（II）是Ba、Ca、Mg、Cd或Zn。其中，化合物I的一些是新颖的。
• Aminoalkylmelamines
  申请人：BASF Aktiengesellschaft

  公开号：US04670558A1

  公开（公告）日：1987-06-02

  Preparation of amidoalkylmelamines and aminoalkylmelamines of the formula I ##STR1## where R.sup.1 is an amidoalkyl group --(CH.sub.2).sub.n --NHZ or an aminoalkyl group --(CH.sub.2).sub.n --NH.sub.2, n is from 2 to 10, preferably from 2 to 6, Z is an amino protective group and R.sup.2 and R.sup.3 independently of one another are each hydrogen or have the same meanings as R.sup.1, are prepared by a process in which a chlorotriazine is reacted with a diamine of the formula H.sub.2 N--(CH.sub.2).sub.n --NHZ, where n and Z have the above meanings, to give an amidoalkylmelamine, and, if required, the group Z is eliminated.

  公式I的amidoalkylmelamines和aminoalkylmelamines的制备方法 R1为amidoalkyl基团--(CH2)n--NHZ或aminoalkyl基团--(CH2)n--NH2，n为2至10，优选为2至6，Z为氨基保护基团，R2和R3独立地为氢或具有与R1相同的含义。该方法通过将三氯氮杂环与公式H2N-(CH2)n-NHZ的二胺反应来制备amidoalkylmelamine，如果需要，则消除Z基团。
• Hydroxyoxaalkylmelamines
  申请人：BASF Aktiengesellschaft

  公开号：US04886882A1

  公开（公告）日：1989-12-12

  Hydroxyoxaalkylmelamines of the general formula I ##STR1## where the radicals R may be identical or different and are each hydrogen or a radical of the general formula II H--(--O--CHR'--CHR'--)--.sub.n (II) where the radicals R' may be indentical or different and are each hydrogen or C.sub.1 -C.sub.4 -alkyl and n is 2 or 3, and mixtures of these, are useful intemediates for the preparation of urethanes and for modifying aminoplast resins.

  通式I的羟基氧杂烷基三聚胺，其中基团R可以相同也可以不同，每个基团为氢或通式II中的基团H--(--O--CHR'--CHR'--)--.sub.n (II)，其中基团R'可以相同也可以不同，每个基团为氢或C.sub.1 -C.sub.4 -烷基，n为2或3，以及这些混合物，可用于尿素酯的制备和改性氨基酸树脂。