4-(1-methylheptyloxycarbonyl)phenyl 4'-[11-(2-cyclohexylacetoxy)undecyloxy]biphenyl-4-carboxylate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(1-methylheptyloxycarbonyl)phenyl 4'-[11-(2-cyclohexylacetoxy)undecyloxy]biphenyl-4-carboxylate
• 英文别名: 4'-[11-(2-cyclohexylacetoxy)-undecyloxyl]-biphenyl-4-carboxylic acid 4-(1-methylheptyloxycarbonyl)-phenyl ester；(4-Octan-2-yloxycarbonylphenyl) 4-[4-[11-(2-cyclohexylacetyl)oxyundecoxy]phenyl]benzoate
• 化学式: C₄₇H₆₄O₇
• 分子量: 741.021
• InChiKey: NIESEUJONAUKMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.8
• 重原子数：
  54
• 可旋转键数：
  28
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  氰基联苯酚 在 4-二甲氨基吡啶 、 sodium hydroxide 、 potassium carbonate 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 乙醇 、 二氯甲烷 、 N,N-二甲基甲酰胺 、 丁酮 为溶剂， 生成 4-(1-methylheptyloxycarbonyl)phenyl 4'-[11-(2-cyclohexylacetoxy)undecyloxy]biphenyl-4-carboxylate
  参考文献：
  名称：

  A chiral electrooptic response in a racemic liquid crystal

  摘要：

  近年来，对手性修改的近晶液晶的电光性质关注甚少，但在本文中，我们将报道一种手性修改在其同线性的近晶C相下对施加电场的手性响应。

  DOI：

  10.1039/b416884b

文献信息

• [EN] BIPHENYL-4-CARBOXYLIC ACID ALKYLOXYCARBONYL PHENYL ESTERS AND USES THEREOF<br/>[FR] MATIERES
  申请人：UNIV HULL

  公开号：WO2005019156A3

  公开（公告）日：2005-09-22
• [EN] MATERIALS<br/>[FR] MATIERES
  申请人：UNIV HULL

  公开号：WO2005019156A2

  公开（公告）日：2005-03-03

  The present invention relates to a compound of the general structure of formula (I): X-Alkylene1-A-1-Alkylene2-A2-(Z1)x-B-(Z2)y-C-(Z3)z-A3-Alkyl3 in which A1, A2 and A3, which may be the same or different, are each -O-, -COO-, -OCO- or -S-; Z1, Z2 and Z3, which may be the same or different, may each be selected from the group : Formula (a) : in which the cyclic rings may be laterally substituted by hydrogen, -CH3, -CF3, -CN, -NO2, halogen, e.g., F, Cl, Br, B and C, which may be the same or different, are each selected from the group: single bond, -COO-, -OCO-, -CH2O-, -CF=CF- or -C=C-; X is selected from the group: cycloalkyl, bicycloalkyl and polycycloalkyl; and x, y and z, which may be the same or different, are each an integer, being 1 or 2, as the racemate, the S or the R enantiomers or mixtures thereof.
• A chiral electrooptic response in a racemic liquid crystal
  作者：Stephen J. Cowling、Alan W. Hall、John W. Goodby

  DOI：10.1039/b416884b

  日期：——

  Over recent years, little attention has been paid to the electrooptic properties of racemic modifications of smectic liquid crystals, however, in this communication we report on a chiral response of a racemic modification to an applied electrical field while in its synclinic smectic C phase.

  近年来，对手性修改的近晶液晶的电光性质关注甚少，但在本文中，我们将报道一种手性修改在其同线性的近晶C相下对施加电场的手性响应。