铁,加合(1:1)铑 | 12062-95-2

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 中文名称: 铁,加合(1:1)铑
• 英文名称: rhodium-iron wire
• 英文别名: iron-rhodium；rhodium-iron；Iron;rhodium
• CAS: 12062-95-2
• 化学式: FeRh
• 分子量: 158.752
• InChiKey: OMEXLMPRODBZCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铁粉 、 铑 以 melt 为溶剂， 反应 48.01h， 生成 铁,加合(1:1)铑
  参考文献：
  名称：

  x = 50，51的感应熔炼Fe 100-x Rh x块状合金的磁弹性转变和磁热效应

  摘要：

  通过电弧熔化生产的几乎等原子的Fe-Rh合金中的大体磁弹性转变（METs）可能显示出较差的重现性，这与化学均匀性不足和浓度可变的杂质相的存在有关。为了更好地理解能够可靠地生产具有可复制MET特性的块状FeRh材料的合成条件，Fe 100- x Rh x合金与x= 50、50.5和51 at。通过在相同条件下的感应熔炼和热退火制备％（％）。将制成的样品切成几片，然后使用等温和等场磁化，差示扫描量热法以及直接测量磁热效应来表征每个切片中的MET。所有切片均在AFM和FM状态之间表现出METs，但是当x = 50.5和51时，跃迁会以几乎相同的磁化强度变化ΔM突变，而对于x = 50合金，跃迁会在较宽的温度范围内扩散间隔和ΔM可能会从一个样本到另一个样本波动多达10％。x的磁热响应的比较=提出了50和51种材料。磁场在两个方向上的跃迁上明显不同的影响会导致可逆性和磁场感应的熵和绝热温度变化的最大

  DOI：

  10.1016/j.jallcom.2021.159586

文献信息

• Synthesis and magnetic properties of self-assembled FeRh nanoparticles
  作者：Z. Jia、J. W. Harrell、R. D. K. Misra

  DOI：10.1063/1.2952956

  日期：2008.7.14

  We report here the synthesis and magnetization behavior of tunable FeRh magnetic nanoparticles with both controllable composition and size. FexRh1−x (x=0.35,0.44,0.51) nanoparticles of 4–20nm size range were fabricated using a polyol coreduction process. The stoichiometry of FexRh1−x nanoparticles was altered by tuning the molar ratio of rhodium acetylacetonate and iron acetylacetonate. The particle

  我们在这里报告了具有可控成分和尺寸的可调 FeRh 磁性纳米粒子的合成和磁化行为。FexRh1−x (x=0.35,0.44,0.51) 4-20nm 尺寸范围的纳米粒子是使用多元醇还原工艺制造的。FexRh1-x 纳米粒子的化学计量通过调整乙酰丙酮铑和乙酰丙酮铁的摩尔比而改变。粒径可通过控制表面活性剂浓度进行调节。对浇铸在硅晶片上的颗粒薄膜进行磁性测量。Fe51Rh49 纳米粒子的矫顽力在室温下在 700°C 下退火 2 小时后约为 250Oe，表明 CsCl 型相变。
• Magneto-Volume and Tetragonal Elongation Effects on Magnetic Phase Transitions of Body-Centered Tetragonal FeRh_1-<i>x</i>Pt_<i>x</i>
  作者：Shinji Yuasa、Hideki Miyajima、Yoshichika Otani

  DOI：10.1143/jpsj.63.3129

  日期：1994.8.15

  Magnetic properties of FeRh1-xPtx system with body-centered cubic and body-centered tetragonal (bct) structures were studied by means of X-ray diffractometry, magnetometry and Mossbauer spectroscopy, and the phase diagram in a temperature-composition plane was determined. With substituting Pt for Rh, the axial ratio c/a was increased and the bct phase was stabilized. With increasing temperature, the bct alloys with 0.72
• Magnetism of Body-Centered Tetragonal FeRh_1-<i>x</i>Pd_<i>x</i>Alloys (I) Magnetic Properties
  作者：Shinji Yuasa、Hideki Miyajima、Yoshichika Otani、Akimasa Sakuma

  DOI：10.1143/jpsj.64.4906

  日期：1995.12.15

  Crystalline structures and magnetic properties of the FeRh1-xPdx system were investigated. Substitution of Pd for Rh stabilized body-centered tetragonal (bct) structure of the ordered CuAu-type with increasing axial ratio c/a from 1.18 to 1.36. The bet alloys in the range x = 0.530 similar to 0.61 exhibited a first-order phase transition from antiferromagnetic to ferromagnetic state, while the bet alloys with x < 0.530 exhibited a first-order phase transition from antiferromagnetic to Curie paramagnetic state. Both the axial ratio and the volume increased abruptly at the transitions. A new ferromagnetic phase with orthorhombic structure with the space group C-mmm was found in the bct alloys with x = 0.525 similar to 0.61 below room temperature. This ferromagnetic phase possesses a larger magnetic moment than that of the bet phase. Reduction of the crystalline symmetry may have enhanced the magnetic moment.
• Synthesis, Crystal Structure, and Magnetic Properties of the Semihard Itinerant Ferromagnet RhFe3N
  作者：Andreas Houben、Paul Müller、Jörg von Appen、Heiko Lueken、Rainer Niewa、Richard Dronskowski

  DOI：10.1002/anie.200502579

  日期：2005.11.11
• Atomic structure of a {110} surface of the FeRh alloy
  作者：S. K. Kim、Y. Tian、F. Jona、P. M. Marcus

  DOI：10.1103/physrevb.56.9858

  日期：——

  The atomic structure of a 110} surface of the ordered binary alloy FeRh is studied with quantitative low-energy electron diffraction. The structure of a surface with stoichiometric composition is found to be bulklike (1x1), but with a pronounced buckling, the Fe subplane being raised 0.15 Angstrom over the Rh subplane of the first layer, and the first interlayer spacing, measured from the Rh subplane of the first to the (bulklike and planar) second atomic layer, is contracted by 0.05 Angstrom (2.4%). Nonstoichiometric (probably Fe-poor) islands are found to have a reconstruction that may be labeled 3 x 1 when referred to the oblique unit mesh of FeRh110}, but whose structure is unknown. A relation between specimen size and angular diffraction width is derived.