dibutyl(chloromethylene)ammonium chloride

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 亚胺酰卤
• 英文名称: dibutyl(chloromethylene)ammonium chloride
• 英文别名: Dibutyl(chloromethylidene)azanium;chloride
• 化学式: C₉H₁₉ClN*Cl
• 分子量: 212.163
• InChiKey: QDBQEIRPCGXXKT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.13
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dibutyl(chloromethylene)ammonium chloride 、 PMEADiPE 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Transprotection of N-Benzoylated Nucleobase Derivatives by Dialkylaminomethylene Group

  摘要：

  The use of(chloromethylene)dialkylammonium chloride in selective transprotection of N-benzoylated nucleobase derivatives is reported along with the evaluation of the stability of various protecting groups widely used in nucleoside and/or nucleotide chemistry.

  DOI：

  10.1080/07328319708002565
• 作为产物：
  描述：

  N,N-二丁基甲酰胺 在 氯化亚砜 作用下， 以 二氯甲烷 为溶剂， 生成 dibutyl(chloromethylene)ammonium chloride
  参考文献：
  名称：

  Transprotection of N-Benzoylated Nucleobase Derivatives by Dialkylaminomethylene Group

  摘要：

  The use of(chloromethylene)dialkylammonium chloride in selective transprotection of N-benzoylated nucleobase derivatives is reported along with the evaluation of the stability of various protecting groups widely used in nucleoside and/or nucleotide chemistry.

  DOI：

  10.1080/07328319708002565

文献信息

• Synthesis, characterization and catalytic application of secondary carbene palladium(II) complexes obtained by oxidative addition reaction
  作者：Süleyman Gülcemal、Salih Günnaz、Jean-Claude Daran、Bekir Çetinkaya

  DOI：10.1016/j.ica.2012.01.031

  日期：2012.5

  secondary carbene palladium(II) complexes (1b–3b) were synthesized via oxidative insertion of Pd2(dba)3 (dba = dibenzylideneacetone) into the C–Cl bond of dialkyl(chloromethylene)ammonium chloride salts ([R2NCHCl]+Cl−). All complexes have been characterized by 1H, 13C, and 31P NMR analysis. X-ray diffraction studies on single crystal of 3b confirm the cis square planar geometry. Complexes (1b–3b) have been

  通过将Pd 2（dba）3（dba =二苄叉基丙酮）氧化插入二烷基（氯亚甲基）氯化铵盐的C–Cl键中，合成了三种新的二级卡宾钯（II）配合物（1b – 3b）（[R 2 NCHCl ] +氯- ）。所有配合物的特征在于1 H，13 C和31 P NMR分析。3b单晶的X射线衍射研究证实了顺式正方形的平面几何形状。复合体（1b – 3b）已被证明是在苯乙烯与4-溴苯乙酮的Heck偶联中有效的催化剂。
• [EN] TRIAZOLOPYRIMIDINE DERIVATIVES<br/>[FR] DERIVES DE TRIAZOLOPYRIMIDINE
  申请人：BAYER AGROCHEM KK

  公开号：WO2000009508A1

  公开（公告）日：2000-02-24

  Novel triazolopyrimidine derivatives of formula (I) in which R1, R2, X and Y have the meanings given in the specification, processes for their preparation and their use as fungicides. Intermediates of formulae (II), (V) and (IV) in which R?1, R3, R4, R5¿, X, Y and Z have the meanings given in the specification, and processes for the preparation of the novel intermediates.