(2-氨基异丙基)三乙氧基硅烷 | 36957-84-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: (2-氨基异丙基)三乙氧基硅烷
• 英文名称: (2-amino-1-methylethyl)triethoxysilane
• 英文别名: 2-(Triethoxysilyl)propylamine；2-triethoxysilylpropan-1-amine
• CAS: 36957-84-3
• 化学式: C₉H₂₃NO₃Si
• 分子量: 221.372
• InChiKey: RYRGXTAWWFMZRN-UHFFFAOYSA-N

物化性质

• 沸点：
  224℃
• 密度：
  0.938
• 闪点：
  89℃

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  53.7
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  三甲基硅醇 、 (2-氨基异丙基)三乙氧基硅烷 以73%的产率得到3-(2-amino-1-methylethyl)-3-ethoxy-1,1,1,5,5,5-hexamethyltrisiloxane
  参考文献：
  名称：

  Kovyazin, V. A.; Kopylov, V. M., Journal of general chemistry of the USSR, 1992, vol. 62, # 4.2., p. 694 - 696

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烯胺 、 三乙氧基硅烷 生成 (2-氨基异丙基)三乙氧基硅烷
  参考文献：
  名称：

  INABA, SINITI;KIMAEH, JOITI

  摘要：

  DOI：

文献信息

• Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Trimethoxysilane
  作者：Zhenhuan Pan、Minglun Liu、Chaoyue Zheng、Deqing Gao、Wei Huang

  DOI：10.1002/cjoc.201700024

  日期：2017.8

  The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Ptn(H2C=CHSiMe2OSiMe2CH=CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane

  氢化硅烷化是合成有机硅化合物的最重要方法之一。Karstedt催化剂[Pt n（H 2 C = CHSiMe 2 OSiMe 2 CH = CH 2）m ]是一种广泛用于氢化硅烷化的铂催化剂。在本文中，我们研究了Karstedt催化剂在用三甲氧基硅烷和三乙氧基硅烷加氢烯烃，特别是胺化烯烃时的催化活性，并在产率和选择性方面表现出优异的性能。
• (Dicyclopentadiene) platinum(II) dichloride: An efficient catalyst for the hydrosilylation reaction between alkenes and triethoxysilane
  作者：Huarui Wu、Chaoyue Zheng、Naiwu Chen、Jie Zhu、Deqing Gao

  DOI：10.1016/j.tetlet.2017.03.017

  日期：2017.4

  (Dicyclopentadiene) platinum(II) dichloride was found to be an efficient hydrosilylation catalyst (homogeneous) upon a wide variety of functionalized alkenes and alkenes terminated with chemical moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-). It is noteworthy that the hydrosilylation of aminated alkenes with triethoxysilane exhibited the yield of over 70% and the selectivity (γ-isomer/β-isomer)

  （二环戊二烯）二氯化铂（II）被发现是一种有效的氢化硅烷化催化剂（均相），适用于多种官能化的烯烃和以化学部分（二苯基氨基，N-咔唑-和N-异二氢吲哚-1,3-终止）的烯烃dione-）。值得注意的是，胺化烯烃与三乙氧基硅烷的氢化硅烷化显示出超过70％的收率和超过3/1的选择性（γ-异构体/β-异构体）。由于空间障碍降低了马尔可夫尼科夫概率，具有大末端部分的烯烃（二苯基氨基，N-咔唑-和N-异吲哚啉-1,3-二酮-）呈现出较高的抗马尔可夫尼科异构体比例。开发了保护的二氨基螯合烯烃的氢化硅烷化策略。
• The influence of additives to the Speier catalyst on hydrosilylation of functionalized alkenes
  作者：E. A. Chernyshev、Z. V. Belyakova、L. K. Knyazeva、M. G. Pomerantseva、L. A. Efimova

  DOI：10.1007/bf02495569

  日期：1998.7

  Hydrosilylation of several unsaturated compounds with triethoxysilane in the presence of the Speier catalyst with various additives influencing the reaction rate and selectivity was studied. The mechanism of hydrosilylation is discussed.
• Transetherification of Organosilicon Amines with Cellosolve and Trimethylsilanol
  作者：V. A. Kovyazin、A. V. Nikitin、V. M. Kopylov、I. B. Sokol'skaya

  DOI：10.1023/b:rugc.0000015983.75580.9c

  日期：2003.9

  Kinetics of transetherification of (3-aminopropyl)trimethoxysilane, [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane and (3-aminopropyl)triethoxysilana with Cellosolve and trimethylsilanol were studied. The example of [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane was used to show that the activation energies of the direct and reverse reactions are equal to each other both in the first and in the second stages, which points to independence of the equilibrium constant on temperature (DeltaHapproximate to0). With methoxysilanes, the rate constant of the reverse reaction in the second stage of the transetherification with Cellosolve is higher than that of the direct reaction.
• MARCINIEC, BOGDAN;GULINSKI, JACEK;MIRECKI, JANUSZ;NOWICKA, TERESA
  作者：MARCINIEC, BOGDAN、GULINSKI, JACEK、MIRECKI, JANUSZ、NOWICKA, TERESA

  DOI：——

  日期：——