(4-甲氧基-1,3-丁二烯基)三正丁基锡烷 | 92208-27-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 中文名称: (4-甲氧基-1,3-丁二烯基)三正丁基锡烷
• 英文名称: 1-methoxy-4-(tributylstannyl)buta-1,3-diene
• 英文别名: 1-tri-n-butylstannyl-4-methoxybuta-1,3-diene；vinylstannane；(4-methoxy-1,3-butadienyl)tri-n-butylstannane；tributyl(4-methoxy-1E,3E-butadienyl)stannane；tributyl-[(1E,3E)-4-methoxybuta-1,3-dienyl]stannane
• CAS: 92208-27-0
• 化学式: C₁₇H₃₄OSn
• 分子量: 373.166
• InChiKey: REMIMYLWFHNIHY-JPPHFFHZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.09
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (4-甲氧基-1,3-丁二烯基)三正丁基锡烷 在 正丁基锂 作用下， 生成 2,4-戊二烯醛,5-(4-甲氧基-5-甲基-2-羰基-2H-吡喃-6-基)-,(2E,4E)-
  参考文献：
  名称：

  Patel, Prakash; Pattenden, Gerald, Journal of the Chemical Society. Perkin transactions I, 1991, # 8, p. 1941 - 1945

  摘要：

  DOI：
• 作为产物：
  描述：

  、 (E)-1-methoxybut-1-en-3-yne 、 三正丁基氢锡 、 偶氮二异丁腈 以to give tributyl(4-methoxy-1E,3E-butadienyl)stannane which的产率得到(4-甲氧基-1,3-丁二烯基)三正丁基锡烷
  参考文献：
  名称：

  3-oxiranyl benzoic acids and derivatives thereof

  摘要：

  本发明涉及下列公式的化合物## STR1 ##或其药学上可接受的盐，其中R是12个碳原子的烷基，具有1到4个—CH = CH—基团，当靠近R的碳饱和时，具有1到2个—CH = CH—基团，当靠近R的碳不饱和时，芳香族，杂环烷基，烷氧基烷基，其中烷基含有1到6个碳原子，或芳氧基烷基，其中烷基含有1到6个碳原子R1是氢，低烷基或药学上可接受的阳离子。这些化合物是白三烯A4（LTA4）水解酶的抑制剂。

  公开号：

  US05990326A1

文献信息

• Natural polyene α-pyrones. Total synthesis of citreomontanin from .
  作者：Prakash Patel、Gerald Pattenden

  DOI：10.1016/s0040-4039(00)94952-9

  日期：1985.1

  A total synthesis of all-E-citreomontanin (7), a novel polyene α-pyrone produced by Penicillium pedomontanum, is described.

  描述了由全青霉产生的一种新型多烯α-吡喃酮全E-瓜氨酸蒙太宁（7）的全合成。
• Beyond the Cyanine Limit:  Peierls Distortion and Symmetry Collapse in a Polymethine Dye
  作者：Laren M. Tolbert、Xiaodong Zhao

  DOI：10.1021/ja9626953

  日期：1997.4.1

  Theory predicts that cyanine dyes and related linear systems undergo symmetry collapse and bond localization at long chain lengths. Beyond this ''cyanine limit'', the properties of these systems do not extrapolate from their shorter counterparts. To test this prediction, dipyridocyanines have been synthesized and shown to undergo such symmetry collapse with chain lengths as short as 13.
• Large Quadratic Hyperpolarizabilities with Donor–Acceptor Polyenes Exhibiting Optimum Bond Length Alternation: Correlation Between Structure and Hyperpolarizability
  作者：M. Blanchard-Desce、V. Alain、P. V. Bedworth、S. R. Marder、A. Fort、C. Runser、M. Barzoukas、S. Lebus、R. Wortmann

  DOI：10.1002/chem.19970030717

  日期：1997.7

  AbstractDonor–acceptor polyenes of various lengths, and that combine aromatic electron‐donating moieties with powerful heterocyclic electron‐withdrawing terminal groups, have been synthesized and characterized as efficient nonlinear optical (NLO) chromophores. Their linear and nonlinear optical properties have been investigated, and variations in these properties have been related to ground‐state polarization (dipole μ) and structure. In particular, unprecedented quadratic hyperpolarizabilities (β) have been achieved (up to β(0) = 1500 × 10−30 esu) by reduction of the bond‐length alternation (BLA) in the polyenic chain. In each series of homologous compounds, increasing the number n of conjugated double bonds in the polyenic chain results in a marked bathochromic shift, more pronounced BLA, and exponential increases in μβ(0) values. As a result, polyenic chromophores displaying excellent optical quadratic nonlinearities (μβ values as large as 100 times that of the quadratic NLO benchmark 4‐dimethyl‐amino‐4′‐nitrostilbene (DANS)), as well as satisfactory solubility, have been obtained.
• SCHWEIKERT, O.;NETSCHER, TH.;KNOTHE, L.;PRINZBACH, H., CHEM. BER., 1984, 117, N 6, 2027-2044
  作者：SCHWEIKERT, O.、NETSCHER, TH.、KNOTHE, L.、PRINZBACH, H.

  DOI：——

  日期：——
• Patel, Prakash; Pattenden, Gerald, Journal of the Chemical Society. Perkin transactions I, 1991, # 8, p. 1941 - 1945
  作者：Patel, Prakash、Pattenden, Gerald

  DOI：——

  日期：——