1,1,1-三(4-三氟乙烯基氧基苯基)乙烷 | 134130-24-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 中文名称: 1,1,1-三(4-三氟乙烯基氧基苯基)乙烷
• 中文别名: 1,1,1-三s(4-三氟乙烯基氧基苯基)乙烷
• 英文名称: 1,1,1-tris(4-trifluorovinyloxyphenyl)ethane
• 英文别名: 1-[1,1-bis[4-(1,2,2-trifluoroethenoxy)phenyl]ethyl]-4-(1,2,2-trifluoroethenoxy)benzene
• CAS: 134130-24-8
• 化学式: C₂₆H₁₅F₉O₃
• 分子量: 546.389
• InChiKey: XAUHHCMRFFGRMF-UHFFFAOYSA-N

物化性质

• 熔点：
  31 °C

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  38
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  、 、 1,1,1-Tris(4-(2-bromotetrafluoroethoxy)phenyl)ethane 以 乙腈 为溶剂， 生成 1,1,1-三(4-三氟乙烯基氧基苯基)乙烷
  参考文献：
  名称：

  Perfluorocyclobutane ring-containing polymers

  摘要：

  本发明是通过以下步骤制备具有全氟环丁烷环的聚合物的过程：(a)接触至少具有两个可二聚的全氟乙烯基团的单体；(b)将单体暴露于足够的热量和足够的时间，形成含有全氟环丁烷环的聚合物，其中至少约0.05摩尔％的单体具有至少3个可二聚的全氟乙烯基团，以及由此制备的聚合物。

  公开号：

  US05159037A1

文献信息

• Compound for optical materials and methods of fabrication
  申请人：Erben Georg Christoph

  公开号：US20050214479A1

  公开（公告）日：2005-09-29

  A polycyclic or monocyclic perfluorovinyl compound comprising at least one structural unit selected from the group consisting of formula I and formula II wherein M is independently at each occurrence a metal selected from group 14 of the periodic table of the elements; and R is independently at each occurrence a bond, a hydrogen, an aliphatic group, a cycloaliphatic group, or an aromatic group. The polycyclic or monocyclic compound comprises at least two perfluorovinyl groups. A method for making an optical film of the disclosed compound, an electro-optical device comprising a polymer fabricated from the disclosed compound and a polymer fabricated from the disclosed compound are also provided.

  一种多环或单环的全氟乙烯化合物，包括至少一种结构单元，所述结构单元选自公式I和公式II所示的组，其中M在每次出现时是周期表元素14族中选取的金属；R在每次出现时是键，氢，脂肪基，环脂肪基或芳香基中选取的。该多环或单环化合物包括至少两个全氟乙烯基团。还提供了一种制备所述化合物的光学薄膜的方法，包括由所述化合物制备的聚合物制成的电光学器件，以及由所述化合物制备的聚合物。
• AMINOBENZENE COMPOSITIONS AND RELATED DEVICES AND METHODS
  申请人：Plextronics, Inc.

  公开号：US20130075670A1

  公开（公告）日：2013-03-28

  Oligomers and/or polymers comprising a backbone comprising arylamine and fluorinated alkyleneoxy moieties which may be crosslinked. Ink formulations and devices can be formed from the oligomers or polymers, or corresponding monomers. Doped compositions can be formed. Charge injection and transport layers can be formed. Improved stability can be achieved in organic electronic devices such as OLEDs and OPVs.

  由含有芳基胺和氟代烷氧基的骨架组成的寡聚体和/或聚合物，可以交联。可以从这些寡聚体或聚合物，或相应的单体中形成墨水配方和设备。可以形成掺杂的组合物。可以形成电荷注入和传输层。可以在有机电子器件（如OLED和OPV）中实现改善稳定性。
• Sulfonated perfluorovinyl functional monomers
  申请人：3M Innovative Properties Company

  公开号：US20020007083A1

  公开（公告）日：2002-01-17

  The present invention provides a monomer having the formula A-B, wherein A is represented by Formula I: 1 wherein B is selected from —OCF=CF 2 and —A; wherein, when B is—OCF=CF 2 , the orientation of B is meta or para to the trifluorovinyloxy group of A; wherein, when B is A, the bond joining the A groups is para to the trifluorovinyloxy group of each A; and wherein each Z is independently selected from —SO 2 F, —SO 2 Cl, —SO 3 H, —SO 2 —N(M)—SO 2 CF 3 , and —SO 2 —N(M)—SO 2 Rf; wherein M is any suitable cation and Rf is a Cl to CIO fluorocarbon or fluorinated ether group. The present invention also provides a monomer according to Formula II: 2 wherein X is F, Cl, or N(M)SO 2 Rf, wherein M is any suitable cation and R f is a C1 to C10 fluorocarbon or fluorinated ether group.

  本发明提供了一种具有A-B式的单体，其中A由式I表示：1，其中B选自—OCF=CF2和—A；其中，当B为—OCF=CF2时，B的取向为与A的三氟乙烯氧基相对的间位或对位；当B为A时，连接A基团的键为与每个A的三氟乙烯氧基对位；且其中每个Z独立地选自—SO2F、—SO2Cl、—SO3H、—SO2—N(M)—SO2CF3和—SO2—N(M)—SO2Rf，其中M是任何合适的阳离子，Rf是Cl到CIO的氟碳化合物或氟化醚基团。本发明还提供了一种根据式II的单体：2，其中X为F、Cl或N(M)SO2Rf，其中M是任何合适的阳离子，Rf为C1到C10的氟碳化合物或氟化醚基团。
• Laminates of polymers having perfluorocyclobutane rings and polymers containing perfluorocyclobutane rings
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0490335A2

  公开（公告）日：1992-06-17

  A laminate has at least two layers, at least one of which comprises a polymer having more than one perfluorocyclobutane group. Such polymers impart qualities of environmental protection, chemical and solvent resistance, hydrolytic stability, lubricity, low dielectric, hydrostatic stability, weatherability, flame resistance, chemical resistance, scratch resistance, surface passivation, water repellancy, lower surface refractive index, lower surface coefficient of friction, fluid barrier properties, oil repellancy, thermal stability, and/or reduced moisture pick-up. Additionally, the coatings are optically clear, easy to apply either neat, in a solvent or otherwise, have relatively low cure temperatures for their temperature resistance, and exhibit insulating and planarizing capabilities.

  层压板至少有两层，其中至少一层由具有一个以上全氟环丁烷基团的聚合物组成。这种聚合物具有环保、耐化学和耐溶剂、水解稳定性、润滑性、低介电强度、静水稳定性、耐候性、阻燃性、耐化学性、抗划伤性、表面钝化、憎水性、较低的表面折射率等特性、 耐划伤性、表面钝化、憎水性、较低的表面折射率、较低的表面摩擦系数、流体阻隔性、憎油性、热稳定性和/或降低吸湿性。此外，这些涂料还具有光学透明性，易于在溶剂中或以其他方式涂抹，固化温度相对较低，具有耐温性，并具有绝缘和平面化功能。
• Novel processes for the production of 13-ether derivatives of milbemycins, and novel intermediates therefor
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0594291A1

  公开（公告）日：1994-04-27

  57 An intermediate useful in the synthesis of milbemycin derivatives having an ether bond at the 13-position and which is represented by the general formula (IIId) : wherein R represents a methyl group, an ethyl group, an isopropyl group or a sec-butyl group, and R5 and R6' each individually represents a hydrogen atom or a protecting group, and related precursors as well as to a process for producing these intermediates.

  57 一种用于合成在 13 位具有醚键的米贝霉素衍生物的中间体，其通式为(IIId)：其中 R 代表甲基、乙基、异丙基或仲丁基，R5 和 R6'各自代表氢原子或保护基，以及相关的前体和生产这些中间体的工艺。