1,2,3-己烷三醇 | 25323-24-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 原羧酸衍生物
• 中文名称: 1,2,3-己烷三醇
• 英文名称: Hexanetriol
• 英文别名: hexane-1,1,1-triol
• CAS: 25323-24-4
• 化学式: C₆H₁₄O₃
• 分子量: 134.17
• InChiKey: TZMQHOJDDMFGQX-UHFFFAOYSA-N

物化性质

• 熔点：
  67-69 °C(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

安全信息

• 危险品标志：
  Xi

文献信息

• Process for producing a deprotected alkoxylated polyol
  申请人：ARCO Chemical Technology, L.P.

  公开号：EP0506424A1

  公开（公告）日：1992-09-30

  An improved process for the hydrolysis and purification of an alkoxylated polyol containing a ketal protective functionality, and which may be employed to prepare reduced calorie esterified alkoxylated polyol fat mimetics useful in cooking and in food compositions, comprises contacting an aqueous mixture of the protected alkoxylated polyol with an acid to hydrolyse and thus deprotect the alkoxylated polyol,adding a base to neutralise the acid and cause the mixture to form a first phase containing the deprotected alkoxylated polyol and a second phase containing predominantly water, and separating the phases. The protected alkoxylated polyol may be formed by alkoxylating a protected polyol. The deprotected alkoxylated polyol may subsequently be esterified.

  一种改进的工艺用于水解和纯化含有酮缩保护官能基的烷氧基聚醇，可用于制备在烹饪和食品组合中有用的低热量酯化烷氧基聚醇脂肪模拟物，包括将受保护的烷氧基聚醇的水混合物与酸接触以水解和去保护烷氧基聚醇，添加碱以中和酸并使混合物形成含有去保护的烷氧基聚醇的第一相和主要含水的第二相，并分离相。受保护的烷氧基聚醇可以通过烷氧基化受保护的聚醇形成。然后可以对去保护的烷氧基聚醇进行酯化处理。
• Macrocyclic carbodiimides (MC-CDI) and their derivatives, syntheses and applications of the same
  申请人：Dai Shenghong A.

  公开号：US20080161554A1

  公开（公告）日：2008-07-03

  Disclosed are a macrocyclic carbodiimide (MC-CDI) and a process for synthesizing the same through condensation of a molecule with multiple-isocyanate terminal functional groups under high dilution in the presence of a phospholene catalyst such as phospholene or arsenic catalyst. Also disclosed are MC-CDI derivatives, such as MC-urea (MC-U), MC-acylurea (MC-ACU), acid functionalized MC-ACU, and anhydride functionalized MC-ACU, processes for synthesizing the same, and the applications of such derivatives as hydrolysis stabilizers in organic polymeric materials, such as polyurethane (PU) and polyesters, as well as the applications in the syntheses of the amide- and imide-modified polyurethane by ring-opening reaction of the MC-ACU.

  本文披露了一种大环碳二亚胺（MC-CDI）及其合成方法，通过在高稀释条件下，在磷烯或砷催化剂的存在下，将具有多个异氰酸酯末端官能基的分子进行缩合反应来合成MC-CDI。还披露了MC-CDI衍生物，如MC-脲（MC-U）、MC-酰脲（MC-ACU）、酸官能化的MC-ACU和酐官能化的MC-ACU，以及其合成方法，以及这些衍生物作为有机聚合材料（如聚氨酯（PU）和聚酯）中的水解稳定剂的应用，以及在通过MC-ACU的环开反应合成酰胺和亚酰胺改性聚氨酯的合成中的应用。
• [EN] PIGMENT, AND PIGMENT COMPOSITION, COLORING COMPOSITION AND COLOR FILTER USING THE SAME<br/>[FR] PIGMENT, ET COMPOSITION DE PIGMENT, COMPOSITION DE COLORATION ET FILTRE DE COULEUR L'UTILISANT
  申请人：FUJIFILM CORP

  公开号：WO2013146332A1

  公开（公告）日：2013-10-03

  Provided are a pigment excellent in the light stability, heat resistance, dispersibility, and color reproducibility without containing any metal-containing compound, a compound composing the pigment, and a pigment composition, a coloring composition, a colored radiation-sensitive composition, a color filter, an inkjet ink using the same, and a method of manufacturing colored radiation-sensitive composition. A pigment comprising at least either a compound represented by the formula (I) or a compound represented by the formula (II) below, the compound showing an absorbance of 0.5 or below at a wavelength of absorption maximum in the range from 300 to 700 nm, when contained in a filtrate obtained after adding 0.01% by weight of the compound into water, and, obtained after adding 0.01% by weight of the compound into 1-monomethyl ether 2-acetate, respectively followed by stirring at 25°C for 10 minutes, and filtering through a filter with a pore size of 0.20 µm. In the formulae (I) and (II), each of R1 to R12 independently represents a monovalent substituent.

  提供了一种在不含任何含金属化合物的情况下具有光稳定性、耐热性、分散性和颜色再现性的颜料，一种构成该颜料的化合物，以及颜料组合物、着色组合物、着色辐射敏感组合物、彩色滤光片、使用该颜料的喷墨墨水，以及一种制备着色辐射敏感组合物的方法。一种颜料包括下面的式(I)或式(II)所代表的化合物中至少一种，当这种化合物被加入水中后得到的滤液中，以及分别在加入0.01%重量的该化合物到1-甲基乙醚-2-乙酸酯中后在25°C搅拌10分钟，并通过孔径为0.20微米的滤器过滤后，在300到700纳米范围内吸收最大波长时，该化合物的吸光度为0.5或以下。在式(I)和(II)中，R1至R12中的每一个独立代表一价取代基。
• [EN] PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS<br/>[FR] PROCÉDÉ DE CARBONYLATION DE COMPOSÉS À INSATURATION ÉTHYLÉNIQUE, NOUVEAUX LIGANDS DE CARBONYLATION, ET SYSTÈMES CATALYSEURS COMPRENANT CES LIGANDS
  申请人：LUCITE INT UK LTD

  公开号：WO2010001174A1

  公开（公告）日：2010-01-07

  A novel bidentate catalytic ligand of general formula (I) is described. R represents a hydrocarbyl aromatic structure having at least one aromatic ring to which Q 1 and Q 2 are each linked, via the respective linking group, if present, on available adjacent atoms of the at least one aromatic ring. The groups X 3 and X 4 represent radicals joined via tertiary carbon atoms to the respective atom Q 1 and the groups X 1 and X 2 represent radicals joined via primary, or substituted aromatic ring carbon atom(s) to the respective atom Q 2. A and B represent an optional lower alkylene linking group. Q 1 and Q 2 each represent phosphorus, arsenic or antimony. A process for the carbonylation of ethylenically unsaturated compounds comprising reacting the compound with carbon monoxide in the presence of a source of hydroxyl groups, optionally, a source of anions and catalyst system obtainable by combining a metal of Group 8, 9 or 10 or a compound thereof and the bidentate ligand of general formula (I) is also described.

  描述了一种一般式(I)的新型双齿催化配体。其中，R代表至少具有一个芳香环的烃基芳香结构，其中Q1和Q2分别通过至少一个芳香环上可用的相邻原子的相应连接基（如果存在）连接。基团X3和X4代表通过第三级碳原子连接到相应原子Q1的基团，基团X1和X2代表通过主要或取代的芳香环碳原子连接到相应原子Q2的基团。A和B代表可选的较低烷基连接基。Q1和Q2分别代表磷、砷或锑。还描述了一种用于乙烯基不饱和化合物的羰基化的方法，包括将该化合物与一氧化碳在羟基源的存在下反应，可选地，与阴离子源和由结合第8、9或10族金属或其化合物以及一般式(I)的双齿配体的催化系统获得的催化剂。
• Dye and ink jet printing ink
  申请人：KONICA MINOLTA HOLDINGS, INC.

  公开号：US20040106782A1

  公开（公告）日：2004-06-03

  A dye is disclosed, which is represented by the following formula: 1 wherein Z is an atomic group necessary to form a 6-membered nitrogen containing aromatic ring; R 11 is a hydrogen bonding group; R 12 , R 13 and R 14 are independently a hydrogen atom or a substituent; n11 and n13 are each an integer of 1 to 4; n12 is an integer of 1 to 3. There is also disclosed an ink for ink jet printing which contains the foregoing dye.

  揭示了一种染料，其表示为以下公式：1其中Z是形成一个含氮6元环芳香环所必需的原子基团；R11是一个氢键结合基团；R12、R13和R14分别是氢原子或取代基；n11和n13各自是1至4的整数；n12是1至3的整数。还披露了一种喷墨打印墨水，其中包含上述染料。