1-氯-9h-噻吨酮 | 38605-72-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 中文名称: 1-氯-9h-噻吨酮
• 英文名称: 1-chlorothioxanthen-9-one
• 英文别名: 1-chloro-9H-thioxanthen-9-one；chlorothioxanthen-9-One；1-chloro-thioxanthen-9-one；1-Chlor-thioxanthen-9-on；1-Chlorthioxanthen-9-on；1-Chlorthioxanthon
• CAS: 38605-72-0
• 化学式: C₁₃H₇ClOS
• mdl: MFCD01245732
• 分子量: 246.717
• InChiKey: YNSNJGRCQCDRDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2932999099

反应信息

• 作为反应物：
  描述：

  1-氯-9h-噻吨酮 在 sodium hydroxide 、 三氯化铝 、 3-Cl-C₁₃H₇SO 作用下， 以 吡啶 、 甲醇 、 甲酸 、 二氯甲烷 、 水 为溶剂， 生成 (2-(Diethylamino)ethyl]-2H-[1]-benzothiopyrano[4,3,2-cd]indazole-5-methanamine
  参考文献：
  名称：

  Cyclic variations of SR 233377 (WIN 33377) and effects on antitumor activity

  摘要：

  Novel derivatives of SR 233377 (1, WIN 33377) where a pyrazolo ring fusion has been incorporated at the 1- and 9-positions of the thioxanthone ring displayed outstanding in vivo efficacy against the murine solid tumor Pane 03 (T/C values of 0% with log cell kill greater than or equal to 2.0). No relationship between structure and Pane 03 activity was observed because all analogues studied were highly active. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0960-894x(96)00230-2
• 作为产物：
  描述：

  间氯溴苯 在 硫酸 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 生成 1-氯-9h-噻吨酮
  参考文献：
  名称：

  三重态衰变诱导的负温度依赖性与热激活延迟荧光发射体的瞬态光致发光衰变†

  摘要：

  研究了在TXO单元上苯基的不同取代位置上具有PhCz供体的三个TX基D–A异构体（TXO-PhCz1，TXO-PhCz3和TXO-PhCz4）的光物理性质。PhCz单元的取代位置会显着影响这些异构体的光物理性质。TXO-PhCz1在未掺杂和掺杂的薄膜中均显示非常弱的发射，而TXO-PhCz3和TXO-PhCz4在TADF发射器中具有必需的特性，具有强发射，包括小的ΔE ST和瞬态PL衰减曲线，并具有快速和稳定的特性。延迟的荧光成分。TXO-PhCz4与TXO-PhCz3相比，它表现出更强的轨道耦合，然后磷光发射引起瞬态PL衰减的反温度依赖性，这与TXO-PhCz3和其他TADF发射器相反。TXO-PhCz4在室温下的ΔE ST小，为23 meV，衰减时间短，为14μs，这比TXO-PhCz3小得多且短得多。基于TXO-PhCz4的多层OLED显示出非常低的效率衰减，最大电流效率为49.2 cd

  DOI：

  10.1039/c7tc04025c

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• CURABLE COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20200385582A1

  公开（公告）日：2020-12-10

  Provided are a curable composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm, or a polymer having a structure represented by Formula 2 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm; a polymerizable compound; and a chromatic colorant different from the compound represented by Formula 1 and the polymer represented by Formula 2, as well as a cured product of the curable composition; a color filter including the cured product; a method for producing a color filter; a solid-state imaging element; and an image display device.

  提供一种可治愈的组合物，包括由式1表示的化合物，其最大吸收波长在600纳米或更大且小于700纳米范围内，或者具有由式2表示的结构的聚合物，其最大吸收波长在600纳米或更大且小于700纳米范围内；一种可聚合的化合物；和一种与式1表示的化合物和式2表示的聚合物不同的色素染料，以及所述可治愈组合物的固化产物；包括所述固化产物的彩色滤光片；生产彩色滤光片的方法；固态成像元件；和图像显示装置。
• NOVEL PHOTOINITIATORS
  申请人：Madsen Niels Joergen

  公开号：US20130296577A1

  公开（公告）日：2013-11-07

  Novel photoinitiators provide for polyurethane formation, in which a photoinitiator moiety and a tertiary amine are incorporated into the photoinitiator structure, and thus the polyurethane polymer.

  新型光引发剂可用于聚氨酯的形成，其中光引发剂基团和三级胺被并入光引发剂结构，从而形成聚氨酯聚合物。
• COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, IMAGE DISPLAY DEVICE, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20200392343A1

  公开（公告）日：2020-12-17

  Provided are a composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 750 nm and a polymerizable compound; as well as a cured product of the composition, a color filter including the cured product, a method for producing the color filter, a solid-state imaging element including the color filter, an image display device including the color filter, and a compound. In Formula 1, Z's each independently represent a specific group, n represents an integer of 4 to 16, and R's each independently represent a hydrogen atom or a monovalent substituent which is different from Z, m represents an integer of 0 to 12, and m+n is 16.

  提供了一个组合物，包括由式1表示的化合物，其具有最大吸收波长在600纳米或更大且小于750纳米的范围内，以及一种可聚合的化合物；以及该组合物的固化产物，包括该固化产物的彩色滤光片，制备该彩色滤光片的方法，包括该彩色滤光片的固态成像元件，包括该彩色滤光片的图像显示装置，以及一种化合物。在式1中，Z分别独立表示特定基团，n表示4到16的整数，R分别独立表示氢原子或与Z不同的一价取代基，m表示0到12的整数，且m+n为16。
• NOVEL POLYMERIC PHOTOINITIATORS AND PHOTOINITIATOR MONOMERS
  申请人：Coloplast A/S

  公开号：US20150148441A1

  公开（公告）日：2015-05-28

  The present invention provides polymeric photoinitiators being co-polymers of photoinitiator monomers and at least one further monomer, as well as photoinitiator monomers being intermediates in the preparation of such polymeric photoinitiators. Additionally, there is provided polyacrylate obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of such polymeric photoinitiators. In the photoinitiator monomers and polymeric photoinitiators, a photoinitiator moiety, a hydrolytic stable linker and two polymerisable functional groups are incorporated into the photoinitiator structure.

  本发明提供了聚合物光引发剂，其为光引发剂单体与至少一种进一步单体的共聚物，以及作为这种聚合物光引发剂制备过程中的中间体的光引发剂单体。此外，还提供了通过在存在这种聚合物光引发剂的情况下，通过至少一种丙烯酸酯单体（Ac）的自由基聚合得到的聚丙烯酸酯。在光引发剂单体和聚合物光引发剂中，光引发剂基团、水解稳定连接物和两个可聚合功能基团被结合到光引发剂结构中。