[Bis(trimethylsilyl)amino]phosphanylidene-trimethylsilylmethane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [Bis(trimethylsilyl)amino]phosphanylidene-trimethylsilylmethane
• 化学式: C₁₀H₂₈NPSi₃
• 分子量: 277.569
• InChiKey: JOMRVNPHZHLJRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [Bis(trimethylsilyl)amino]phosphanylidene-trimethylsilylmethane 在 n-butyllithium 作用下， 以 四氢呋喃 、 正己烷 、 苯 为溶剂， 生成 {μ-(trimethylsilyl)2CHPNHSiMe3}(μ-tert-butylsulfido)diiron(carbonyl)6
  参考文献：
  名称：

  Wisian-Neilson, Patty; Onan, Kay D.; Seyferth, Dietmar, Organometallics, 1988, vol. 7, # 4, p. 917 - 921

  摘要：

  DOI：
• 作为产物：
  描述：

  Trimethylsilylmethylphosphonigsaeuredichlorid 、 sodium hexamethyldisilazane 以 乙醚 为溶剂， 以86%的产率得到[Bis(trimethylsilyl)amino]phosphanylidene-trimethylsilylmethane
  参考文献：
  名称：

  Lutsenko, I. F.; Prishchenko, A. A.; Borisenko, A. A., Doklady Chemistry, 1981, vol. 256, p. 70 - 73

  摘要：

  DOI：

文献信息

• Heterocyclizations of hydroxyketones with two-coordinated (trimethylsilylamino)phosphines, (Me3Si)2N?P?E?SiMe3
  作者：Petar Y. Petrov、Christo M. Angelov、Galin Petrov、Alexi Alexiev、Ronald G. Cavell

  DOI：10.1002/hc.20033

  日期：——

  The reaction of two-coordinated (trimethylsilylamino)phosphines (Me3Si)2NPESiMe31 (E = N) and 2 (E = CH) with hydroxycarbonyl compounds proceeded with four- or five-member heterocyclization to yield derivatives of oxaphosphetane, oxaphospholanes, and oxaphospholes. The reaction rate depends on the structure of hydroxyketones as well as on the type of the two-coordinated phosphorus compound in accordance

  二配位（三甲基甲硅烷基氨基）膦 (Me3Si)2NPESiMe31 (E = N) 和 2 (E = CH) 与羟基羰基化合物的反应通过四元或五元杂环化反应生成氧杂膦、氧杂膦和氧杂磷的衍生物。根据 P=N 和 P=C 键的极性，反应速率取决于羟基酮的结构以及双配位磷化合物的类型。因此，在邻羰基苯氧基衍生物与膦 1 的情况下，反应在 30 分钟内完成，但在烷基羟基羰基的情况下需要 2 小时。与膦 2 的所有反应大约需要 24 小时。© 2004 Wiley Periodicals, Inc. 杂原子化学 15:413–417, 2004; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20033
• Methylenethioxophosphoranes and 1,2-λ⁵-thiaphosphirans
  作者：Edgar Niecke、Dirk-A. Wildbredt

  DOI：10.1039/c39810000072

  日期：——

  The synthesis of methylenethioxophosphoranes and the [1 + 2] cycloaddition of sulphur to the ylidic P–C bond is described.

  介绍了亚甲基硫氧磷烷的合成以及硫与亚甲基 PâC 键的[1 + 2]环加成反应。
• Hydrozirconation of phospha-alkenes and phosphaimines. Evidence for the formation of P–C–Zr and P–N–Zr three-membered rings
  作者：Jean Pierre Majorai、Nathalie Dufour、Franc Meyer、Anne-Marie Caminade、Robert Choukroun、Danièle Gervais

  DOI：10.1039/c39900000507

  日期：——

  Addition of bis(η-cyclopentadienyi)zirconium hydride (Cp2ZrHCl) to phospha-alkenes and phosphaimines leads either to a functionalized bis(η-cyclopentadienyl)zirconium phosphirane and azaphosphirane or to a protonated dico-ordinated phosphorus species.

  将双（η-环戊二烯基）氢化锆（Cp 2 ZrHCl）添加到磷化烯烃和磷亚胺中会导致官能化的双（η-环戊二烯基）锆膦和氮杂膦烷或质子化的二配位磷物种。
• Niecke, Edgar; Leuer, Martina; Nieger, Martin, Chemische Berichte, 1989, vol. 122, p. 453 - 462
  作者：Niecke, Edgar、Leuer, Martina、Nieger, Martin

  DOI：——

  日期：——
• Hydro- and carbozirconation of multiple-bonded low-coordinated phosphorus species
  作者：Nathalie Dufour、Anne Marie Caminade、Mario Basso-Bert、Alain Igau、Jean Pierre Majoral

  DOI：10.1021/om00039a019

  日期：1992.3

  Hydrozirconation of phosphaimines RP = NR' (2a-c) (2a, R = N(SiMe3)2, R' = SiMe3; 2b, R = N(SiMe3)(tBu), R' = tBu; 2c, R = tetramethylpiperidino, R' = SiMe3), phosphaalkene (Me3Si)2NP = C(H)SiMe3 (17), or bis(imino)phosphorane (Me3Si)2NP(= NSiMe3)2 (30) by means of Cp2ZrHCl takes place with the formation either of the three-membered rings zirconaazaphosphirane Cp2 activated Zr(Cl)N(R')P(H)R (3a-c) and zirconaphosphirane Cp2 activated Zr(Cl)C(H)(SiMe3)P(H)N(SiMe3)2 (18) or the four-membered ring zirconadiazaphosphetidine Cp2Zr(Cl)N(SiMe3)P(H)[N(SiMe3)2]N(SiMe3) (31). Similarly, carbozirconation of phosphaimine 2a leads to the zirconaazaphosphirane Cp2 activated Zr(Me)N(SiMe3)P(Me)N(SiMe3)2 (7). On the other hand, hydrozirconation of 2a with Cp2ZrH2 or hydrozirconation of the thioiminophosphorane Me3Si(tBu)NP(= S)(= NtBu) (13) gives rise respectively to the acyclic phosphine (Me3Si)2NP(H)NHSiMe3 (6) or to the acyclic phosphine sulfide Me3Si(tBu)NP(S)HN(H)tBu (10b). Addition of Cp2ZrHCl to the chlorophosphaalkene ClP = C(SiMe3)2 (19) affords the diphosphene (Me3Si)2CHP = PCH(SiMe3)2 (20) and the diphosphirane (Me3Si)2CHPC(SiMe3)2PH (21). An easy hydride-chlorine exchange involving Cp2ZrHCl and free or complexed halogenated phosphines is observed and allows obtention of the corresponding P-H phosphines. Ligand exchange occurs when the zirconaphosphirane 18 is treated either with the phosphaimine 2a or the bis(imino)phosphorane 30, leading to the zirconaazaphosphirane 3a or the zirconadiazaphosphetidine 31, respectively. Synthesis of stable cationic cyclic zirconium species, the zirconaazaphosphirane cations [(CH3C = N)Cp2 activated ZrN(SiMe3)P(H)[N(SiMe3)2][X] (15, 16) (15, X = CF3SO3; 16, X = BPh4) or the zirconadiazaphosphetidine cation [CH3C = N)Cp2 activated ZrN(SiMe3)P(H)[N(SiMe3)2]N(SiMe3)][CF3SO3] (38), involving dissociation of a covalent zirconium-oxygen bond, are also reported.