phenyl(chloromethyl)dichlorosilane | 5489-23-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: phenyl(chloromethyl)dichlorosilane
• 英文别名: chloromethylphenyldichlorosilane；chloromethyl(dichloro)phenylsilane；Dichlor-chlormethyl-phenyl-silan；Phenyl-chlormethyl-dichlor-silan；Chlormethyl-phenyl-dichlorsilan；Dichlor-chlormethyl-phenylsilan；Silane, dichloro(chloromethyl)phenyl-；dichloro-(chloromethyl)-phenylsilane
• CAS: 5489-23-6
• 化学式: C₇H₇Cl₃Si
• 分子量: 225.577
• InChiKey: OEQIEAZLCJWDRM-UHFFFAOYSA-N

物化性质

• 沸点：
  108-109 °C(Press: 11 Torr)
• 密度：
  1.3170 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.59
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  phenyl(chloromethyl)dichlorosilane 在 三氯化铁 、 magnesium 、 乙酰氯 作用下， 生成 1,3-Dichloro-1,3-diphenyl-1,3-disiletane
  参考文献：
  名称：

  Cross-Linkable Carbosilane Polymers with Imbedded Disilacyclobutane Rings Derived by Acyclic Diene Metathesis Polymerization

  摘要：

  Cyclolinear carbosilane polymers with disilacyclobutane (DSCB) rings in the main-chain structure were prepared by means of acyclic diene metathesis (ADMET) polymerization of the corresponding 1,3-dibutenyl-1,3-disilacyclobutanes. The copolymerization of a monomer of this type with a noncyclic organosilane diene allowed for the incorporation of a varying number of DSCB rings into the polymer backbone. Subsequent hydrogenation of the double bonds with p-toluenesulfonhydrazide resulted in a saturated hydrocarbon structure in the main chain without affecting the DSCB ring. All of the resultant polymers are well-defined materials with DSCB rings incorporated into the backbone structure, as evidenced by NMR spectroscopy and GPC analyses. The thermal behavior of these polymers was characterized by DSC and TGA. DSC indicated low T(g)s, and TGA evidenced high thermal stability in an inert atmosphere. In addition, large exothermic peaks were observed in the DSC, which indicated, along with the IR and solid-state Si-29 NMR spectra, that cross-linking occurs during heating to ca. 250 degreesC via opening of the imbedded DSCB rings. The swelling properties of the resultant, thermally stable, carbosilane network materials on exposure to various solvents were also examined.

  DOI：

  10.1021/ma049760a
• 作为产物：
  描述：

  (氯甲基)三氯硅烷 、 phenylmagnesium bromide 以 乙醚 为溶剂， 以89%的产率得到phenyl(chloromethyl)dichlorosilane
  参考文献：
  名称：

  Silaethane：II：1,3-disilacyclobutanen的Darstellung und charakterisierung von silaethane：II：Darstellung und charakterisierung von 1,3-disilacyclobutanen

  摘要：

  类型的1,3- Disilacyclobutanes被制备：（a）由环合成从chloromethylchlorosilanes - [R 1 - [R 2的Si（CH 2由monosilacyclobutanes的热分解- [R Cl）的氯，（b）中1 - [R 2 ħ 2 CH 2，和（c）通过用步骤（a）或（b）获得的含SiCl的1，3-二硅环丁烷中的烷基取代氯。该化合物已通过分析和光谱研究表征。严格比较了合成方法。

  DOI：

  10.1016/s0022-328x(00)82810-7

文献信息

• Fungicidal imidazole derivatives
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04496551A1

  公开（公告）日：1985-01-29

  Silicon-containing imidazoles having broad-spectrum fungicidal activity have been discovered.

  已发现具有广谱杀真菌活性的含硅咪唑类化合物。
• Fungicidal 1,2,4-triazole derivatives
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04510136A1

  公开（公告）日：1985-04-09

  Silicon-containing 1,2,4-triazoles having broad-spectrum fungicidal activity have been discovered.

  已发现具有广谱杀真菌活性的含硅1,2,4-三唑化合物。
• Pentacoordinate hydrochlorosilanes with lactamomethyl ligand
  作者：Vadim A. Pestunovich、Svetlana V. Kirpichenko、Natal’ya F. Lazareva、Aleksander I. Albanov、Mikhail G. Voronkov

  DOI：10.1016/j.jorganchem.2007.01.035

  日期：2007.5

  The synthesis and reaction behavior of pentacoordinate hydrochlorosilanes LCH2SiRHCl (L- 2-piperidonyl ligand, R = Me, Ph, Bn) are described. The intramolecular O–Si and N–Si coordination is discussed on the basis of the NMR data. The strength of the O–Si coordinate bond is nearly the same for chelates 5, 6, 8 irrespective of the equatorial substituent R at the silicon atom. However, the nature of

  描述了五配位氢氯硅烷LCH 2 SiRHCl（L-2-哌啶基配体，R = Me，Ph，Bn）的合成和反应行为。分子内的O-Si和N-Si配位在NMR数据的基础上进行了讨论。O型的Si配位键的强度几乎为螯合物同5，6，8，不论在硅原子上的赤道取代基R的。但是，R取代基的性质显着影响具有N-Si分子内键的配合物的稳定性。
• Highly Enantioselective Construction of Multifunctional Silicon‐Stereogenic Silacycles by Asymmetric Enamine Catalysis
  作者：Xue‐Xin Zhang、Yang Gao、Yan‐Xue Zhang、Jian Zhou、Jin‐Sheng Yu

  DOI：10.1002/anie.202217724

  日期：2023.2.20

  The enantioselective construction of silicon-stereocenter by asymmetric enamine catalysis is reported. The reaction proceeds via an unprecedented desymmetric intramolecular aldolization of prochiral siladials for the diverse synthesis of multifunctional silicon-stereogenic silacycles.

  报道了通过不对称烯胺催化对映选择性构建硅立体中心。该反应通过前手性 siladials 前所未有的不对称分子内醛缩化反应进行，用于多功能硅-立体硅环的多样化合成。
• AUNER N.; GROBE J., J. ORGANOMETAL. CHEM., 1980, 188, NO 2, 151-177
  作者：AUNER N.、 GROBE J.

  DOI：——

  日期：——