tetrakis[2-(tri(2-methylacetylenyl)stannyl)ethyl]silane | 916452-83-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: tetrakis[2-(tri(2-methylacetylenyl)stannyl)ethyl]silane
• CAS: 916452-83-0
• 化学式: C₄₄H₅₂SiSn₄
• 分子量: 1083.82
• InChiKey: KETLSNHXMMEHKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  49
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  tetrakis[2-(tribromostannyl)ethyl]silane 、 1-丙炔溴化镁 以 四氢呋喃 为溶剂， 以89%的产率得到tetrakis[2-(tri(2-methylacetylenyl)stannyl)ethyl]silane
  参考文献：
  名称：

  Synthesis and characterization of new silicon-centred tin-dendrimers Si[CH2CH2SnR3]4. Single-crystal X-ray structure of the tetrahydrofuran adduct of tetrakis[2-(tribromostannyl)ethyl]silane

  摘要：

  A series of novel first-generation silicon-centred tin dendrimers Si(CH2CH2SnR3)(4) [R = CH3 (3), Bu-i (4), C CCH3 (5), C6H4CH3-4 (6), C6H4OCH3-4 (7), (CH2)(4)OCH2CH2OCH3 (8), CH2SiMe3 (9)] was prepared by the reaction of Si(CH2CH2SnBr3)(4) (2) with the appropriate Grignard reagent or LiCH2SiMe3 in tetrahydrofuran. The new compounds were characterized by multinuclear NMR studies (H-1, C-13, Sn-119), mass spectrometry (MALDI-TOF, EI) and elemental analyses. The molecular structure of Si[CH2CH2SnBr3(THF)(2)](2)[CH2CH2SnBr3(THF)](2) (2a) was determined by single-crystal X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.017

文献信息

• Synthesis and characterization of new silicon-centred tin-dendrimers Si[CH2CH2SnR3]4. Single-crystal X-ray structure of the tetrahydrofuran adduct of tetrakis[2-(tribromostannyl)ethyl]silane
  作者：Herbert Schumann、Yilmaz Aksu、Stefan Schutte、Birgit C. Wassermann、Stefan H. Mühle

  DOI：10.1016/j.jorganchem.2006.07.017

  日期：2006.11

  A series of novel first-generation silicon-centred tin dendrimers Si(CH2CH2SnR3)(4) [R = CH3 (3), Bu-i (4), C CCH3 (5), C6H4CH3-4 (6), C6H4OCH3-4 (7), (CH2)(4)OCH2CH2OCH3 (8), CH2SiMe3 (9)] was prepared by the reaction of Si(CH2CH2SnBr3)(4) (2) with the appropriate Grignard reagent or LiCH2SiMe3 in tetrahydrofuran. The new compounds were characterized by multinuclear NMR studies (H-1, C-13, Sn-119), mass spectrometry (MALDI-TOF, EI) and elemental analyses. The molecular structure of Si[CH2CH2SnBr3(THF)(2)](2)[CH2CH2SnBr3(THF)](2) (2a) was determined by single-crystal X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.