N-chloro-N-(dimethylsilyl)-1,1-dimethylsilanamine | 135764-61-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-chloro-N-(dimethylsilyl)-1,1-dimethylsilanamine
• CAS: 135764-61-3
• 化学式: C₄H₁₄ClNSi₂
• 分子量: 167.786
• InChiKey: JJEIDWHHNKMFEI-UHFFFAOYSA-N

物化性质

• 沸点：
  119.2±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.41
• 重原子数：
  8.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  苯基三氟硅烷 、 四甲基二硅氮烷 反应 24.0h， 以61%的产率得到1,1-dimethyl-3-phenyl-3,3-difluorodisilazane
  参考文献：
  名称：

  Reactions of organylhalosilanes with 1,1,3,3-tetra- and hexamethyldisilazane

  摘要：

  Organylchlorosilanes, and also SiCl4, decompose 1,1,3,3-tetra- and hexamethyl-disilazanes with formation of hitherto unknown organylchlorosilazanes of general formulas R4-nSiCln-1NHSiH(CH3)2 and R4-nSiCln-1NHSi(CH3)3 (n = 2-4) in yields of 54-98%. The IR and mass spectra of the prepared compounds were studied.

  DOI：

  10.1007/bf00961370

文献信息

• Reactions of organylhalosilanes with 1,1,3,3-tetra- and hexamethyldisilazane
  作者：S. V. Basenko、I. A. Gebel'、D. D. Toryashinova、V. Yu. Vitkovskii、R. G. Mirskov、M. G. Voronkov

  DOI：10.1007/bf00961370

  日期：1991.5

  Organylchlorosilanes, and also SiCl4, decompose 1,1,3,3-tetra- and hexamethyl-disilazanes with formation of hitherto unknown organylchlorosilazanes of general formulas R4-nSiCln-1NHSiH(CH3)2 and R4-nSiCln-1NHSi(CH3)3 (n = 2-4) in yields of 54-98%. The IR and mass spectra of the prepared compounds were studied.