triethenylstannane | 163273-06-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: triethenylstannane
• 英文别名: tris(ethenyl)stannane
• CAS: 163273-06-1
• 化学式: C₆H₁₀Sn
• 分子量: 200.855
• InChiKey: ZBTNNYHWNLQCPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.39
• 重原子数：
  7.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  dichloroaluminum hydride 、 氯三乙烯基锡烷 以 not given 为溶剂， 生成 triethenylstannane
  参考文献：
  名称：

  Vinylstannanes: synthesis and characterization

  摘要：

  Primary, secondary and tertiary vinylstannanes 2a-2f are synthesized by reduction of the corresponding chloro(vinyl)stannanes. They are characterized by their spectral data (IR, NMR (Sn-119, C-13, H-1) spectroscopy and mass spectrometry). The Sn-119 chemical shifts and (1)J(SnH) and (1)J(SnC) of vinylstannanes are compared with the data reported for the corresponding alkyl- and aryl-stannanes. Compounds 2 decompose slowly at room temperature in benzene (tau(1/2) 1-3 days). The formation of divinylchlorostannane and the use of trivinylstannane as a reducing agent are also reported.

  DOI：

  10.1016/0022-328x(94)05057-i

文献信息

• Vinylstannanes: synthesis and characterization
  作者：Tajdine Janati、Jean-Claude Guillemin、Mohammed Soufiaoui

  DOI：10.1016/0022-328x(94)05057-i

  日期：1995.1

  Primary, secondary and tertiary vinylstannanes 2a-2f are synthesized by reduction of the corresponding chloro(vinyl)stannanes. They are characterized by their spectral data (IR, NMR (Sn-119, C-13, H-1) spectroscopy and mass spectrometry). The Sn-119 chemical shifts and (1)J(SnH) and (1)J(SnC) of vinylstannanes are compared with the data reported for the corresponding alkyl- and aryl-stannanes. Compounds 2 decompose slowly at room temperature in benzene (tau(1/2) 1-3 days). The formation of divinylchlorostannane and the use of trivinylstannane as a reducing agent are also reported.