3,4-bis(phenyl)thiophene-2-carboxylic acid | 40133-45-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 3,4-bis(phenyl)thiophene-2-carboxylic acid
• 英文别名: 3,4-diphenyl-thiophene-2-carboxylic acid；3,4-Diphenyl-thiophen-2-carbonsaeure；3,4-Diphenylthiophene-2-carboxylic acid
• CAS: 40133-45-7
• 化学式: C₁₇H₁₂O₂S
• 分子量: 280.347
• InChiKey: ITQNBSSZWAKUAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,4-diphenyl-thiophene-2-carboxylic acid methyl ester 生成 3,4-bis(phenyl)thiophene-2-carboxylic acid
  参考文献：
  名称：

  Melles; Backer, Recueil des Travaux Chimiques des Pays-Bas, 1953, vol. 72, p. 314,321

  摘要：

  DOI：

文献信息

• De novo synthesis of thiophenes on a polymeric support
  作者：Antonio Traversone、Wolfgang K.-D. Brill

  DOI：10.1016/j.tetlet.2007.03.111

  日期：2007.5

  The Hinsberg thiophene synthesis was expanded to support bound thioglycolic acid derived synthons, which reacted with arils to give thiophenes in high purity. (C) 2007 Elsevier Ltd. All rights reserved.
• HETEROCYCLIC METALLOCENE COMPOUNDS AND USE THEREOF IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS
  申请人：Basell Technology Company B.V.

  公开号：EP1157027A1

  公开（公告）日：2001-11-28
• [EN] HETEROCYCLIC METALLOCENE COMPOUNDS AND USE THEREOF IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS<br/>[FR] COMPOSES DE METALLOCENE HETEROCYCLIQUES ET LEUR UTILISATION DANS DES SYSTEMES CATALYTIQUES POUR PRODUIRE DES POLYMERES D'OLEFINES
  申请人：BASELL TECHNOLOGY CO BV

  公开号：WO2001047939A1

  公开（公告）日：2001-07-05

  A metallocene compound of general formula (I): LGZMXp, wherein L is a divalent group, Z is a moiety of formula (II), wherein R?3 and R4¿ are selected from hydrogen and hydrocarbon groups; A and B are selected from S, O or CR5, wherein R5 is selected from hydrogen and hydrocarbon groups, either A or B being different from CR5; G is a moiety of formula (III), wherein R?6, R7, R8 and R9¿ are selected from hydrogen and hydrocarbon groups, M is an atom of a transition metal, X is selected from a halogen atom, a R?10, OR10, OSO¿2CF3, OCOR10, SR?10, NR10¿2 or PR102 group, wherein the substituents R10 is hydrogen and a hydrocarbon group; p is an integer from 0 to 3.