N-isopropyl dichloroacetimidoyl chloride | 79166-98-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 亚胺酰卤
• 英文名称: N-isopropyl dichloroacetimidoyl chloride
• 英文别名: N-isopropyldichloroacetimidoyl chloride；2,2-dichloro-N-propan-2-ylethanimidoyl chloride
• CAS: 79166-98-6
• 化学式: C₅H₈Cl₃N
• 分子量: 188.484
• InChiKey: NAFZIDSHKMQJRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-isopropyl dichloroacetimidoyl chloride 、 3,5-二氯苯胺 以 丙酮 为溶剂， 以92.7%的产率得到N-isopropyldichloroacetimidoyl chloride N-3',5'-Dichlorophenyl-N'-isopropyldichloroacetamidine
  参考文献：
  名称：

  Haloacetamidines and the herbicidal use thereof

  摘要：

  二氯乙酰胺亚胺的化学式为##STR1##其中A和B分别选自氢、氟、氯、溴和甲基，但至少A或B之一不是氢；M为氢或甲基；X选自三氟甲基、低碳基、硝基、氯、溴、氟、氰基、低碳氧基乙酰基、低碳硫基、三氟甲基硫基和3,3-二低碳基脲基；Y选自氢、低碳基、氯、氟、硝基、三氟甲基和低碳氧基；Z选自氢和氯；R.sub.1选自氢、烷基和烯丙基；R.sub.2选自烷基、烯丙基、苄基、羟基烷基、炔基、N-烷基酰胺、烷氧基烷基、二烷氧基烷基、烷氧基、氰基烷基、取代苯基，其中取代基选自三氟甲基、二氯甲基和3,3-二甲基脲基；R.sub.1和R.sub.2连同氮原子选自烷基取代的噁唑基、吗啉基、哌啶基和吡咯啉基；以及其盐；可用作除草剂。

  公开号：

  US04670593A1
• 作为产物：
  描述：

  N-Isopropyl-2,2-dichloroacetamide 、 盐酸 、 三氯氧磷 以 五氯化磷 为溶剂， 以gave 360 grams (65% yield) of N-isopropyldichloroacetimidoyl chloride, b.p. 63°-72° C.的产率得到N-isopropyl dichloroacetimidoyl chloride
  参考文献：
  名称：

  Haloacetamidines compositions and the herbicidal use thereof

  摘要：

  具有以下式子的二氯乙酰胺类化合物：##STR1## 其中A和B独立地选自氢、氟、氯、溴和甲基，但至少其中一个不是氢；M为氢或甲基；X选自三氟甲基、低碳基、硝基、氯、溴、氟、氰、低碳氧乙酰基、低碳硫基、三氟甲基硫基和3,3-二低碳基脲基；Y选自氢、低碳基、氯、氟、硝基、三氟甲基和低碳氧基；Z选自氢和氯；R.sub.1选自氢、烷基和烯丙基；R.sub.2选自烷基、烯丙基、苄基、羟基烷基、炔基、N-烷基酰胺基、烷氧基烷基、二烷氧基烷基、烷氧基、氰基烷基、取代苯基，其中取代基选自三氟甲基、二氯和3,3-二甲基脲基；R.sub.1和R.sub.2与氮一起被选自烷基取代的噁唑烷基、吗啉基、哌啶基和吡咯烷基的群体中；以及它们的盐；作为除草剂有用。

  公开号：

  US04781752A1

文献信息

• Dichloromethyl oxadiazole herbicide antidotes
  申请人：Stauffer Chemical Company

  公开号：US04488897A1

  公开（公告）日：1984-12-18

  A novel class of 2-dichloromethyl-5-phenyl or substituted phenyl 1,3,4-oxadiazole compounds having the formula ##STR1## wherein R is unsubstituted phenyl or phenyl mono-, di-, or tri-substituted with halogen, hydroxy or nitro, which are useful as antidotes for thiocarbamate herbicidal crop injury.

  一种新型的2-二氯甲基-5-苯基或取代苯基1,3,4-噁二唑化合物，其化学式为##STR1##其中R是未取代的苯基或卤素、羟基或硝基单、二或三取代的苯基，可用作对硫代氨基甲酸酯除草剂对作物的损伤的解毒剂。
• Haloacetamidines and the herbicidal use thereof
  申请人：Stauffer Chemical Co.

  公开号：US04670593A1

  公开（公告）日：1987-06-02

  Dichloroacetamidines having the formula ##STR1## in which A and B are independently selected from hydrogen, fluorine, chlorine, bromine and methyl, provided that at least one of A or B is other than hydrogen; M is hydrogen or methyl; X is selected from the group consisting of trifluoromethyl, lower alkyl, nitro, chloro, bromo, fluoro, cyano, lower alkoxy acetyl, lower alkylthio, trifluoromethylthio, and 3,3-diloweralkyl ureido; Y is selected from the group consisting of hydrogen, lower alkyl, chloro, fluoro, nitro, trifluoromethyl, and lower alkoxy; Z is selected from the group consisting of hydrogen and chloro; R.sub.1 is selected from the group consisting of hydrogen, alkyl and allyl; R.sub.2 is selected from the group consisting of alkyl, allyl, benzyl, hydroxyalkyl, alkynyl, N-alkyl amido, alkoxyalkyl, dialkoxyalkyl, alkoxy, cyano alkyl, substituted phenyl wherein the substituent is selected from the group trifluoromethyl, dichloro and 3,3-dimethylureido; and R.sub.1 and R.sub.2 taken together with the nitrogen is selected from the group consisting of alkyl substituted oxazolidyl, morpholinyl, piperidinyl and pyrrolidinyl; and salts thereof; useful as herbicides.

  二氯乙酰胺亚胺的化学式为##STR1##其中A和B分别选自氢、氟、氯、溴和甲基，但至少A或B之一不是氢；M为氢或甲基；X选自三氟甲基、低碳基、硝基、氯、溴、氟、氰基、低碳氧基乙酰基、低碳硫基、三氟甲基硫基和3,3-二低碳基脲基；Y选自氢、低碳基、氯、氟、硝基、三氟甲基和低碳氧基；Z选自氢和氯；R.sub.1选自氢、烷基和烯丙基；R.sub.2选自烷基、烯丙基、苄基、羟基烷基、炔基、N-烷基酰胺、烷氧基烷基、二烷氧基烷基、烷氧基、氰基烷基、取代苯基，其中取代基选自三氟甲基、二氯甲基和3,3-二甲基脲基；R.sub.1和R.sub.2连同氮原子选自烷基取代的噁唑基、吗啉基、哌啶基和吡咯啉基；以及其盐；可用作除草剂。
• Haloacetamidines compositions and the herbicidal use thereof
  申请人：Stauffer Chemical Company

  公开号：US04781752A1

  公开（公告）日：1988-11-01

  Dichloroacetamidines having the formula ##STR1## in which A and B are independently selected from hydrogen, fluorine, chlorine, bromine and methyl, provided that at least one of A or B is other than hydrogen; M is hydrogen or methyl; X is selected from the group consisting of trifluoromethyl, lower alkyl, nitro, chloro, bromo, fluoro, cyano, lower alkoxy acetyl, lower alkylthio, trifluoromethylthio, and 3,3-diloweralkyl ureido; Y is selected from the group consisting of hydrogen, lower alkyl, chloro, fluoro, nitro, trifluoromethyl, and lower alkoxy; Z is selected from the group consisting of hydrogen and chloro; R.sub.1 is selected from the group consisting of hydrogen, alkyl and allyl; R.sub.2 is selected from the group consisting of alkyl, allyl, benzyl, hydroxyalkyl, alkynyl, N-alkyl amido, alkoxyalkyl, dialkoxyalkyl, alkoxy, cyano alkyl, substituted phenyl wherein the substituent is selected from the group trifluoromethyl, dichloro and 3,3-dimethylureido; and R.sub.1 and R.sub.2 taken together with the nitrogen is selected from the group consisting of alkyl substituted oxazolidyl, morpholinyl, piperidinyl and pyrrolidinyl; and salts thereof; useful as herbicides.

  具有以下式子的二氯乙酰胺类化合物：##STR1## 其中A和B独立地选自氢、氟、氯、溴和甲基，但至少其中一个不是氢；M为氢或甲基；X选自三氟甲基、低碳基、硝基、氯、溴、氟、氰、低碳氧乙酰基、低碳硫基、三氟甲基硫基和3,3-二低碳基脲基；Y选自氢、低碳基、氯、氟、硝基、三氟甲基和低碳氧基；Z选自氢和氯；R.sub.1选自氢、烷基和烯丙基；R.sub.2选自烷基、烯丙基、苄基、羟基烷基、炔基、N-烷基酰胺基、烷氧基烷基、二烷氧基烷基、烷氧基、氰基烷基、取代苯基，其中取代基选自三氟甲基、二氯和3,3-二甲基脲基；R.sub.1和R.sub.2与氮一起被选自烷基取代的噁唑烷基、吗啉基、哌啶基和吡咯烷基的群体中；以及它们的盐；作为除草剂有用。