2-amino-4,6-bis (n-butylamino)-1,3,5-triazine | 5606-17-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-amino-4,6-bis (n-butylamino)-1,3,5-triazine
• 英文别名: 2,4-dibutylamino-6-amino-s-triazine；N,N'-dibutylmelamine；N²,N⁴-dibutyl-[1,3,5]triazine-2,4,6-triyltriamine；N²,N⁴-Dibutyl-[1,3,5]triazin-2,4,6-triyltriamin；2,4-bis(n-butylamino)-6-amino-1,3,5-triazine；2-amino-4,6-bis(n-butylamino)-1,3,5-triazine；2-Amino-4,6-bis(monobutylamino)-1,3,5-triazine；2-N,4-N-dibutyl-1,3,5-triazine-2,4,6-triamine
• CAS: 5606-17-7
• 化学式: C₁₁H₂₂N₆
• 分子量: 238.336
• InChiKey: NIHZJKGHPMGDFS-UHFFFAOYSA-N

物化性质

• 熔点：
  203 °C
• 沸点：
  429.7±28.0 °C(Predicted)
• 密度：
  1.138±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  2-amino-4,6-bis (n-butylamino)-1,3,5-triazine 在 zinc(II) chloride 作用下， 反应 2.5h， 生成 2-[3-[4,6-bis(butylamino)-1,3,5-triazin-2-yl]-2-(4-hydroxyphenyl)-4-oxo-1,3-thiazolidin-5-yl]acetic acid
  参考文献：
  名称：

  Mehta; Parekh, Journal of the Indian Chemical Society, 1988, vol. 65, # 1, p. 65 - 67

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4-bis(butylamino)-6-chloro-1,3,5-triazine 在 氨 作用下， 以 1,4-二氧六环 为溶剂， 反应 1.5h， 以80%的产率得到2-amino-4,6-bis (n-butylamino)-1,3,5-triazine
  参考文献：
  名称：

  Mehta; Parekh, Journal of the Indian Chemical Society, 1988, vol. 65, # 1, p. 65 - 67

  摘要：

  DOI：

文献信息

• Method for modifying 1,3,5-triazine derivatives
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US06127538A1

  公开（公告）日：2000-10-03

  A method for modifying 1,3,5-triazine derivatives characterized by heating and reacting a 1,3,5-triazine derivatives having at least one amino or mono-substituted amino group on a carbon atom or atoms on its ring with an alcohol in the presence of a metal catalyst and a hydrogen atom to introduce an alkyl group or an alkenyl group into each amino or mono-substituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by heating and reacting a 1,3,5-triazine derivatives having at least one amino or mono-substituted amino group on a carbon atom or atoms on its ring with a dihydric alcohol in the presence of a metal catalyst and a hydrogen atom to introduce an alkyl group having a hydroxyl group into each amino or mono-substituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified sustituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as compounds having high-purity by a normal separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification.

  一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与醇反应，将烷基基团或烯基基团引入每个氨基或单取代氨基团；另一种用于修改1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢原子的存在下，通过加热并将至少具有一个氨基或单取代氨基团的1,3,5-三嗪衍生物与二元醇反应，将具有羟基的烷基基团引入每个氨基或单取代氨基团；以及通过这些方法获得的1,3,5-三嗪衍生物。因此产生的各种改性取代的1,3,5-三嗪衍生物通常作为混合物获得。这些衍生物可以通过常规有机化合物分离方法分离为高纯度的化合物，并且这些化合物可用于规范中提到的各种应用。
• CYANOETHYLMELAMINE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0945446A1

  公开（公告）日：1999-09-29

  The present invention relates to a cyanoethylmelamine derivatives of the formula I: wherein 1 to 5 of the substituents X' to X6 represent a cyanoethyl group and at least one remaining group represents a C1-20 alkyl group, a C2-20 alkenyl group (said alkyl or alkenyl group may optionally have an alicyclic group or a phenyl group in its structure), a C5-6 cycloalkyl group or a phenyl group, or two of the substituent groups bonded to the same nitrogen atom together may form an alkylene chain having 2 to 7 carbon atoms, and the remaining substituent or substituents represents a hydrogen atom}. The production of cyanoethylmelamine derivatives can be obtained at high yield by reacting N-substituted melamine derivatives with acrylonitrile or reacting mono- or di-halogeno-N-substituted triazine derivative with aminopropionitrile. The compounds of the formula (I) are useful compounds as intermediates for fine chemicals such as agricultural chemicals, medicines, dye stuffs, paints, etc. and as crosslinking intermediates for resins.

  本发明涉及一种公式I的氰乙基三聚氰胺衍生物：其中取代基X'至X6中的1至5个代表氰乙基基团，至少一个剩余基团代表C1-20烷基基团，C2-20烯基基团（该烷基或烯基基团的结构中可能含有环烷基或苯基），C5-6环烷基基团或苯基，或两个结合到同一氮原子的取代基团可共同形成具有2至7个碳原子的烷基链，其余的取代基或取代基团代表氢原子}。通过将N-取代三聚氰胺衍生物与丙烯腈反应或将单取代或双卤代N-取代三嗪衍生物与氨基丙腈反应，可以高产率地获得氰乙基三聚氰胺衍生物。公式（I）的化合物是作为农药、药物、染料、涂料等精细化学品的中间体以及树脂的交联中间体的有用化合物。
• Expoxy/acid anhydride composition
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US06124381A1

  公开（公告）日：2000-09-26

  An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [I] ##STR1## (wherein X is an amino group, C.sub.1-18 monoalkylamino group, di C.sub.1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R.sup.1 and R.sup.2 independently each represent C.sub.1-12 alkyl group, C.sub.1-12 hydroxyalkyl group, C.sub.4-8 cycloalkyl group, C.sub.5-9 cycloalkylmethyl group or C.sub.5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  一种环氧树脂/酸酐组合物，其特征在于其含有一种取代三嗪的固化促进剂，该取代三嗪的化学式为[I] ##STR1## （其中X为氨基，C.sub.1-18单烷基氨基，二C.sub.1-18烷基氨基，吗啉基，哌啶基，甲基或苯基；R.sup.1和R.sup.2各自独立地表示C.sub.1-12烷基，C.sub.1-12羟基烷基，C.sub.4-8环烷基，C.sub.5-9环烷基甲基或C.sub.5-9甲基环烷基）在环氧树脂/酸酐组合物中，该组合物中含有环氧化合物和酸酐固化剂，并通过热固化制备的环氧树脂/酸酐组合物。
• Method of alkylating triazine derivatives
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US06130332A1

  公开（公告）日：2000-10-10

  The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.

  本发明的目的是提供一种高产率生产取代-1,3,5-三嗪衍生物的方法，其中其环中的至少一个碳原子被具有至少一个烷基的二级胺基取代。本发明的方法是一种1,3,5-三嗪衍生物的烷基化方法，其特征在于将至少具有一个或更多氨基或环上单取代氨基的1,3,5-三嗪衍生物（三聚氰胺，三聚氰胺衍生物，各种脲衍生物等）与醛或酮醇在周期表中的第VII和/或第VIII族金属催化剂和含氢气体的存在下反应，以烷基化所述至少一个氨基或单取代氨基。这些衍生物广泛用于精细化学品的中间体，如农药，药物，染料，涂料等，并广泛用于树脂材料和阻燃材料。
• Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers
  申请人：Wehner Wolfgang

  公开号：US20090105387A1

  公开（公告）日：2009-04-23

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物的稳定剂体系，特别是PVC，包括至少一种配位聚合三乙醇胺高氯酸盐（三氟乙酸盐）金属内部络合物，该络合物包括式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和恒化酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和道森石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，磷酸酯或/和立体阻隔胺或/和NOR-HALS化合物也可能存在。