2,6-diethyl-2,3,6-trimethylpiperidine | 61746-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 2,6-diethyl-2,3,6-trimethylpiperidine
• 英文别名: 2,6-diethyl-2,3,6-trimethyl-piperidine
• CAS: 61746-12-1
• 化学式: C₁₂H₂₅N
• 分子量: 183.337
• InChiKey: PUVUYZAAQWYJNL-UHFFFAOYSA-N

物化性质

• 沸点：
  108-110 °C(Press: 23 Torr)
• 密度：
  0.781±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,6-diethyl-2,3,6-trimethylpiperidine 在 过氧乙酸 、 碳酸氢钠 作用下， 以 乙醚 、 水 为溶剂， 反应 12.0h， 以84%的产率得到2,6-diethyl-2,3,6-trimethylpiperidine N-oxyl
  参考文献：
  名称：

  氧化性颈缩丙烯酰化反应用于以硝态氮为氧化剂立体选择性合成四取代烯烃

  摘要：

  一二三 在高度立体选择性氧化的Pd催化的Heck芳基化反应中，一氧化氮和二氧用作氧化剂，其中芳基硼酸用于合成三芳基烷基取代的烯烃。该反应在室温下在非常温和的条件下发生。例如，丙烯酸甲酯的三重顺序芳基化是Z-他莫昔芬立体选择性合成的关键步骤。

  DOI：

  10.1002/anie.201108211

文献信息

• N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：——

  公开号：US20040049043A1

  公开（公告）日：2004-03-11

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polaylkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶化合物，形成开链或环状的酮缩结构，一种聚合物组合物，包括a)至少一种乙烯基不饱和单体和b)含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂化合物。本发明的进一步方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂进行自由基聚合的方法。
• [EN] POLYMERIZABLE COMPOSITIONS<br/>[FR] COMPOSITIONS POLYMÉRISABLES
  申请人：BASF SE

  公开号：WO2010112410A1

  公开（公告）日：2010-10-07

  The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR8R9)-, Z1 is -O-, -NR10-, -CH2-,-(CR11R12)- or -C(=O)- and R1 to R12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.

  该发明涉及使用式(I)中的三氮烯，其中Q是直接键或二价基团-(CR8R9)-，Z1是-O-，-NR10-，-CH2-，-(CR11R12)-或-C(=O)-，R1至R12是可选择取代的碳氢基团，作为自由基引发的反应中有用的自由基前体，例如不饱和单体的聚合和聚烯烃的降解。大多数式(I)中的三氮烯是新颖的并且被声明为专利，还包括制备式(I)中的三氮烯以及包含它们的可聚合组合物。
• [EN] PROCESS FOR THE OXIDATION OF SECONDARY AMINES INTO THE CORRESPONDING NITROXIDES<br/>[FR] PROCEDE D'OXYDATION D'AMINES SECONDAIRES EN NITROXYDES CORRESPONDANTS
  申请人：CIBA SC HOLDING AG

  公开号：WO2004085397A1

  公开（公告）日：2004-10-07

  The invention relates to a process for the preparation of secondary nitroxide radicals from their corresponding secondary amines by oxidation with an organic peracid, comprising the steps a) adding to a reaction vessel a secondary amine, optionally together with an organic solvent and in one batch a base selected from the group consisting of alkali metal, alkaline earth metal or ammonium bicarbonates and alkaline earth metal or ammonium carbonates or mixtures thereof in the form of a solid together with water or as an aqueous slurry; b) dosing a peracid under stirring to the reaction mixture in an amount of 1,0 to 2,5 mol per mol of secondary amine; and c) isolating the organic phase.

  该发明涉及一种从相应的二级胺经过与有机过氧酸氧化制备二级亚硝基自由基的方法，包括以下步骤：a)向反应容器中加入二级胺，可选地与有机溶剂一起，并以一批次加入从碱金属、碱土金属或铵碳酸氢盐以及碱土金属或铵碳酸盐或它们的混合物中选择的碱作为固体形式与水一起或作为水浆；b)在搅拌下向反应混合物中加入1,0至2,5摩尔的过氧酸，每摩尔二级胺；c)分离有机相。
• Stabilization of poly(mono-olefins)
  申请人：Sankyo Company, Limited

  公开号：US04131599A1

  公开（公告）日：1978-12-26

  Sterically hindered piperidines having at least 5 alkyl groups in ring positions 2,3,5 and 6 are usable as light-stabilizers for organic polymers. The nitrogen may be unsubstituted or may bear a mono- to tetravalent substituent. The compounds can be synthesized by a Wolf-Kishner reduction of polyalkyl 4-oxopiperidines optionally followed by a N-substitution reaction in a second step. The stabilizers are added to the polymers in an amount of from 0.01 to 5% by weight. Preferred is the stabilization of polyolefins, styrene polymers, polyamides and polyurethanes.

  具有至少5个烷基基团的立体障碍哌啶在环的2、3、5和6位置可用作有机聚合物的光稳定剂。氮原子可以是未取代的或带有单价到四价的取代基。这些化合物可以通过多烷基4-氧代哌啶的Wolf-Kishner还原反应，随后在第二步进行N-取代反应来合成。稳定剂以0.01至5%的重量添加到聚合物中。首选聚烯烃，苯乙烯聚合物，聚酰胺和聚氨酯的稳定化。
• N-alkoxy-4, 4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：Fuso Francesco

  公开号：US20070173570A1

  公开（公告）日：2007-07-26

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶化合物，形成开链或环状的环缩酮结构，以及包括a) 至少一种乙烯基不饱和单体和b) 含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物进行自由基聚合的方法。