| 51956-20-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 51956-20-8
• 化学式: 6C₂H₆N*2Mo
• 分子量: 456.338
• InChiKey: HXJPRZWGHJKVRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.62
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  14.1
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  、 5,11,17,23-tetra-tertbutyl 25,26,27,28-tetra-hydroxycalix{4}arene*C7H8 以 甲苯 为溶剂， 以85%的产率得到bis(dimethylammonium) di-μ(2)-κ(2)O.,.kappa(2)O-p-tert-butylcalix[4]arenedimolybdate(III)
  参考文献：
  名称：

  Dinuclear Molybdenum(III) and Tungsten(III) Calix[4]arene Complexes − Metal-Metal Triple Bonds Supported by Bridging Calix[4]arene Ligands

  摘要：

  DOI：

  10.1002/(sici)1099-0682(199803)1998:3<299::aid-ejic299>3.0.co;2-q

文献信息

• Synthesis and structural characterization of some novel metalloboroxides bearing boron-bound mesityl and fluoromesityl substituents: the molecular structure of the first metallaboroxane complex
  作者：Vernon C. Gibson、Carl Redshaw、William Clegg、Mark R.J. Elsegood

  DOI：10.1016/s0277-5387(96)00601-8

  日期：1997.1

  Treatment of the new boronous acid HOB(fmes)(2) (1) (fmes = 2,4,6-(CF3)(3)C6H2) with n-butyllithium in diethyl ether/pentane affords after work-up the dimer [Li(thf)OB(fmes)(2)](2) (2). Reaction of [Mo-2(NMe2)(6)] with two equivalents of 1 in toluene gives the amido-boroxide complex Mo-2(NMe2)(4)[OB(fmes)(2)](2) (3). Treatment of CuBr2 with LiOB(Mes)(2) (mes = 2,4,6-Me3C6H2) in tetrahydrofuran affords after work-up and addition of excess pyridine the monomeric copper(II) boroxide Cu[O3B2(mes)(2)](2)[Li(CH3CN)(C5H5N)](2)} (4), containing the new ligand mesB(O)OB(O)mes, as a result of loss of mesitylene and formation of a B--O--B bond. 2 and 4 have been structurally characterized. (C) 1997 Elsevier Science Ltd.
• Chisholm; Corning; Huffman, Inorganic Chemistry, <hi>1982</hi>, vol. 21, # 1, p. 286 - 289
  作者：Chisholm、Corning、Huffman

  DOI：——

  日期：——
• Dinuclear Molybdenum(III) and Tungsten(III) Calix[4]arene Complexes − Metal-Metal Triple Bonds Supported by Bridging Calix[4]arene Ligands
  作者：Udo Radius、Juri Attner

  DOI：10.1002/(sici)1099-0682(199803)1998:3<299::aid-ejic299>3.0.co;2-q

  日期：1998.3