2,4,6-tris(phenylseleno)-1,3,5-triazine | 142312-16-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,4,6-tris(phenylseleno)-1,3,5-triazine
• 英文别名: 2,4,6-Tris(phenylselanyl)-1,3,5-triazine
• CAS: 142312-16-1
• 化学式: C₂₁H₁₅N₃Se₃
• 分子量: 546.25
• InChiKey: PZYISBPDNSAICZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.16
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 二苯基二硒醚 在 sodium hydroxide 、 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 2.25h， 以95%的产率得到2,4,6-tris(phenylseleno)-1,3,5-triazine
  参考文献：
  名称：

  An efficient and facile one-pot synthesis of structurally unique 2,4,6-tris(arylchalcogeno)-1,3,5-triazine and 1,3,5-tris(arylchalcogeno)-2,4,6-trimethylbenzene

  摘要：

  An efficient one-pot synthesis of a novel class of 2,4,6-tris(arylchalcogeno)-1,3,5-triazine (sulfur, selenium and tellurium) and 1,3,5-tris(arylchalcogeno)-2,4,6-trimethylbenzene (sulfur and selenium)-containing ligands has been developed based on the reaction of 2,4,6-trichloro-1,3,5-triazine and 1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene with the corresponding arylchalcogenide anions generated in aqueous tetrahydrofuran. (C) 2004 Publishd by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2004.06.128

文献信息

• Synthesis and Attempted [4+2] Cycloaddition Reaction of 2,4,6-Tris(phenylseleno and aryltelluro)-1,3,5-triazines with Diethyl Acetylenedicarboxylate
  作者：Hiroyuki Tani、Tokuo Inamasu、Hitomi Suzuki

  DOI：10.3987/com-91-5926

  日期：——

  2,4,6-Tris(phenylseleno and aryltelluro)-1,3,5-triazines were synthesized by the reaction of 2,4,6-trichloro-1,3,5-triazine with corresponding arylchalcogenide anions. These 2,4,6-tris(arylchalcogeno)-1,3,5-triazines failed to undergo the Diels-Alder reaction with diethyl acetylenedicarboxylate.