Trimethyl-(1-methyl-octyloxy)-silane | 39789-11-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Trimethyl-(1-methyl-octyloxy)-silane
• 英文别名: Trimethyl(nonan-2-yloxy)silane
• CAS: 39789-11-2
• 化学式: C₁₂H₂₈OSi
• 分子量: 216.439
• InChiKey: WKZIKTBRBGHLEP-UHFFFAOYSA-N

物化性质

• 沸点：
  90-91 °C(Press: 25 Torr)
• 密度：
  0.804±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.59
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Trimethyl-(1-methyl-octyloxy)-silane 在 ammonium cerium(IV) nitrate sodium bromate 作用下， 以 水 、 乙腈 为溶剂， 以85%的产率得到2-壬酮
  参考文献：
  名称：

  Synthetic Methods and Reactions; 95¹. Ceric Ammonium Nitrate-Catalyzed Oxidative Cleavage of Alkyl and Silyl Ethers with Sodium Bromate

  摘要：

  DOI：

  10.1055/s-1980-29258
• 作为产物：
  描述：

  2-壬醇 、 六甲基二硅氮烷 在 magnesium hydrogen sulfate 作用下， 以 乙腈 为溶剂， 反应 0.22h， 以91%的产率得到Trimethyl-(1-methyl-octyloxy)-silane
  参考文献：
  名称：

  Magnesium Hydrogensulfate [Mg(HSO₄)₂] as an Efficient Catalyst for the Preparation of Silyl Ethers, Dibenzo[a,j]xanthenes, and Octahydroxanthene Derivatives

  摘要：

  Magnesium hydrogensulfate [Mg(HSO4)(2)], as a heterogeneous solid acid catalyst, has been used for the mild formation of trimethylsilyl (TMS) ethers from various primary, secondary, and tertiary aliphatic alcohols; aromatic alcohols; and oximes using hexamethyldisilazane (HMDS) under ambient conditions. In addition, 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo- octahydroxanthene derivatives were synthesized in the presence of Mg(HSO4)(2) with short reaction times in high to excellent yield under solvent-free conditions.

  DOI：

  10.1080/10426500902758329

文献信息

• Catalysis by Solid Superacids; 19¹. Simplified and Improved Polymeric Perfluorinated Resin Sulfonic Acid (Nafion-H) Catalyzed Protection-Deprotection Reactions
  作者：George A. Olah、Altaf Husain、Brij P. Singh

  DOI：10.1055/s-1983-30553

  日期：——
• OLAH, G. A.;HUSAIN, A.;SINGH, B. P., SYNTHESIS, BRD, 1983, N 11, 892-895
  作者：OLAH, G. A.、HUSAIN, A.、SINGH, B. P.

  DOI：——

  日期：——
• Magnesium Hydrogensulfate [Mg(HSO₄)₂] as an Efficient Catalyst for the Preparation of Silyl Ethers, Dibenzo[a,j]xanthenes, and Octahydroxanthene Derivatives
  作者：Hamid Reza Shaterian、Razieh Doostmohammadi、Fahimeh Khorami、Majid Ghashang

  DOI：10.1080/10426500902758329

  日期：2009.12.29

  Magnesium hydrogensulfate [Mg(HSO4)(2)], as a heterogeneous solid acid catalyst, has been used for the mild formation of trimethylsilyl (TMS) ethers from various primary, secondary, and tertiary aliphatic alcohols; aromatic alcohols; and oximes using hexamethyldisilazane (HMDS) under ambient conditions. In addition, 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo- octahydroxanthene derivatives were synthesized in the presence of Mg(HSO4)(2) with short reaction times in high to excellent yield under solvent-free conditions.
• Synthetic Methods and Reactions; 95¹. Ceric Ammonium Nitrate-Catalyzed Oxidative Cleavage of Alkyl and Silyl Ethers with Sodium Bromate
  作者：George A. Olah、B. G. Balaram Gupta、Alexander P. Fung

  DOI：10.1055/s-1980-29258

  日期：——