(N->B)-diphenyl[2-(1-piperidylethoxy)]borane | 207730-11-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: (N->B)-diphenyl[2-(1-piperidylethoxy)]borane
• CAS: 207730-11-8
• 化学式: C₁₉H₂₄BNO
• 分子量: 293.217
• InChiKey: VZGKJDAAZVMYIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-羟乙基哌啶 、 二苯基二烃基硼酸 以 氯仿 为溶剂， 以42%的产率得到(N->B)-diphenyl[2-(1-piperidylethoxy)]borane
  参考文献：
  名称：

  Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography

  摘要：

  A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00636-0

文献信息

• Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography
  作者：Herbert Höpfl、Norberto Farfán、Dolores Castillo、Rosa Santillan、Atilano Gutierrez、Jean-Claude Daran

  DOI：10.1016/s0022-328x(97)00636-0

  日期：1998.2

  A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.