(2-Dimethylsilanyl-benzyl)-diphenyl-phosphane | 143629-02-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (2-Dimethylsilanyl-benzyl)-diphenyl-phosphane
• 英文别名: (2-dimethylsilylphenyl)methyl-diphenylphosphane
• CAS: 143629-02-1
• 化学式: C₂₁H₂₃PSi
• 分子量: 334.473
• InChiKey: UGFNIIWHRGISNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.01
• 重原子数：
  23.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  bis(acetonitrile)decacarbonyltriosmium 、 (o-diphenylphosphinobenzyl)dimethylsilane 、 (2-Dimethylsilanyl-benzyl)-diphenyl-phosphane 以 二氯甲烷 为溶剂， 生成 、
  参考文献：
  名称：

  Phosphinobenzyl- and aryl-silanes and their triosmium cluster carbonyl derivatives

  摘要：

  The Grignard reagents MgR(Br) (R = C6H4CH2SiMe2H-o or C6H4CH2SiMeH2-o) have been found to undergo unusual reactions with Ph2PCl to afford o-Ph2PC6H4CH2SiMe2H I and o-HMe2SiC6H4CH2PPh2 II and o-Ph2PC6H4CH2SiMeH2 III and o-H2MeSiC6H4CH4PPh2 IV respectively. Reactions of the respective bidentate ligands I, II, III and IV with [Os3(CO)10(MeCN)2] gave the novel triosmium clusters [Os3(mu-H)(CO)10(L-L)] 1, 2, 3 and 4 involving cleavage of one Si-H bond. Similar reactions of ligands II and IV with [Os3(mu-H)2(CO)10)] afforded two new clusters [Os3(mu-H)3(CO)8(L-L)] 5 and 6 respectively. The structures of 1, 2, 4 and 5 have been determined by single-crystal X-ray diffraction techniques. In each case, the ligand assumes a chelating mode across the long edge of the osmium triangle which is also bridged by a hydride. The high-performance liquid chromatographic behaviour of these clusters has also been determined and correlated with the size and nature of the ligands.

  DOI：

  10.1039/dt9920002161
• 作为产物：
  描述：

  (邻溴苄基)二甲基硅烷 、 二苯基氯化膦 在 magnesium 作用下， 生成 (o-diphenylphosphinobenzyl)dimethylsilane 、 (2-Dimethylsilanyl-benzyl)-diphenyl-phosphane
  参考文献：
  名称：

  Phosphinobenzyl- and aryl-silanes and their triosmium cluster carbonyl derivatives

  摘要：

  The Grignard reagents MgR(Br) (R = C6H4CH2SiMe2H-o or C6H4CH2SiMeH2-o) have been found to undergo unusual reactions with Ph2PCl to afford o-Ph2PC6H4CH2SiMe2H I and o-HMe2SiC6H4CH2PPh2 II and o-Ph2PC6H4CH2SiMeH2 III and o-H2MeSiC6H4CH4PPh2 IV respectively. Reactions of the respective bidentate ligands I, II, III and IV with [Os3(CO)10(MeCN)2] gave the novel triosmium clusters [Os3(mu-H)(CO)10(L-L)] 1, 2, 3 and 4 involving cleavage of one Si-H bond. Similar reactions of ligands II and IV with [Os3(mu-H)2(CO)10)] afforded two new clusters [Os3(mu-H)3(CO)8(L-L)] 5 and 6 respectively. The structures of 1, 2, 4 and 5 have been determined by single-crystal X-ray diffraction techniques. In each case, the ligand assumes a chelating mode across the long edge of the osmium triangle which is also bridged by a hydride. The high-performance liquid chromatographic behaviour of these clusters has also been determined and correlated with the size and nature of the ligands.

  DOI：

  10.1039/dt9920002161

文献信息

• Phosphinobenzyl- and aryl-silanes and their triosmium cluster carbonyl derivatives
  作者：How Ghee Ang、Betty Chang、Whei Lu Kwik

  DOI：10.1039/dt9920002161

  日期：——

  The Grignard reagents MgR(Br) (R = C6H4CH2SiMe2H-o or C6H4CH2SiMeH2-o) have been found to undergo unusual reactions with Ph2PCl to afford o-Ph2PC6H4CH2SiMe2H I and o-HMe2SiC6H4CH2PPh2 II and o-Ph2PC6H4CH2SiMeH2 III and o-H2MeSiC6H4CH4PPh2 IV respectively. Reactions of the respective bidentate ligands I, II, III and IV with [Os3(CO)10(MeCN)2] gave the novel triosmium clusters [Os3(mu-H)(CO)10(L-L)] 1, 2, 3 and 4 involving cleavage of one Si-H bond. Similar reactions of ligands II and IV with [Os3(mu-H)2(CO)10)] afforded two new clusters [Os3(mu-H)3(CO)8(L-L)] 5 and 6 respectively. The structures of 1, 2, 4 and 5 have been determined by single-crystal X-ray diffraction techniques. In each case, the ligand assumes a chelating mode across the long edge of the osmium triangle which is also bridged by a hydride. The high-performance liquid chromatographic behaviour of these clusters has also been determined and correlated with the size and nature of the ligands.