2-羟基苯甲酸-4-羟基苯酯 | 2553-10-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 中文名称: 2-羟基苯甲酸-4-羟基苯酯
• 英文名称: 4'-hydroxyphenyl salicylate
• 英文别名: salicylic acid-(4-hydroxy-phenyl ester)；Salicylsaeure-(4-hydroxy-phenylester)；Hydrochinonmonosalicylat；4-Hydroxy-phenyl-salicylat；4-Hydroxyphenyl 2-hydroxybenzoate；(4-hydroxyphenyl) 2-hydroxybenzoate
• CAS: 2553-10-8
• 化学式: C₁₃H₁₀O₄
• 分子量: 230.22
• InChiKey: UFNKAYBBJKLRIW-UHFFFAOYSA-N

物化性质

• 熔点：
  102-103 °C
• 沸点：
  386.8±22.0 °C(Predicted)
• 密度：
  1.356±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-羟基苯甲酸-4-羟基苯酯 、 乙酸酐 、 吡啶 生成 (4-acetyloxyphenyl) 2-acetyloxybenzoate
  参考文献：
  名称：

  PATOLIA, R.;TRIVEDI, K. N., INDIAN J. CHEM., 1983, 22, N 5, 444-447

  摘要：

  DOI：
• 作为产物：
  描述：

  水杨酸苯酯 、 对苯二酚 生成 2-羟基苯甲酸-4-羟基苯酯
  参考文献：
  名称：

  Cohn,G., Journal fur praktische Chemie (Leipzig 1954), 1900, vol. <2> 61, p. 552

  摘要：

  DOI：

文献信息

• Stretched film structure of the poly-1,3-phenylene terephthalate type
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0052927A2

  公开（公告）日：1982-06-02

  A monoaxially or biaxially stretched film structure, or a heat-set structure thereof, of an unstretched film of an aromatic polyester having an intrinsic viscosity, determined in p-chlorophenol at 50°C, of 0.4 to 2.0 and composed of [A] polybasic carboxylic acid component units consisting of terephthalic acid units (a1) and units (a2) of a polybasic carboxylic acid otherthan terephthalic acid, the proportion of the units (a2) being up to 25 mole% based on the units (a,) and units (a2) combined, and [B] polyol component units consisting of resorcinol units (b1) and units (b2) of a polyol other than resorcinol, the proportion of the units (b2) being up to 25 mole% based on the units (b1) and (b2) combined.

  一种单轴或双轴拉伸薄膜结构，或其热固结构，由芳香族聚酯的未拉伸薄膜组成，其固有粘度（在对氯苯酚中于 50℃测定）为 0.4 至 2.A] 由对苯二甲酸单元（a1）和对苯二甲酸以外的多基性羧酸单元（a2）组成的多基性羧酸组分单元，单元（a2）的比例为单元（a. ）和单元（a2）总和的 25 摩尔%、)和单元(a2)的总和，单元(a2)的比例不超过 25 摩尔%，以及 [B] 由间苯二酚单元(b1)和间苯二酚以外的多元醇单元(b2)组成的多元醇组分单 元，单元(b2)的比例不超过 25 摩尔%，单元(b1)和单元(b2)的总和。
• Aromatic polycarbonate resins and process for the preparation thereof
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0584801A2

  公开（公告）日：1994-03-02

  Disclosed herein is an aromatic polycarbonate resin containing benzophenone and benzoate ester derivatives which have a molecular weight less than 1,000, each in an amount of 100 ppm or less. Also disclosed is a process for preparing an aromatic polycarbonate resin from an aromatic dihydroxy compound and a carbonate diester in which the benzophenone derivative content is 100 ppm or less by transesterification, comprising preparing a polycarbonate prepolymer having a viscosity average molecular weight of 5,000 to 20,000 using an iminocarboxylic acid or salt thereof as a transesterification catalyst and polymerizing the prepolymer in an extruder. Phosphoric acid mono- or diesters, phosphorous acid diesters or phosphorous acid are optionally added as stabilizers during the preparation process. The aromatic polycarbonate is colorless and transparent and is suitable for extrusion molding.

  本发明公开了一种芳香族聚碳酸酯树脂，其中含有二苯甲酮和苯甲酸酯衍生物，这两种衍生物的分子量小于 1,000，含量均为 100 ppm 或更少。本发明还公开了一种通过酯交换反应从芳香族二羟基化合物和碳酸酯二酯制备芳香族聚碳酸酯树脂的工艺，其中二苯甲酮衍生物含量为 100 ppm 或更少，该工艺包括使用亚氨基甲酸酯或其盐作为酯交换反应催化剂制备粘度平均分子量为 5,000 至 20,000 的聚碳酸酯预聚物，并在挤压机中聚合该预聚物。在制备过程中，可选择添加磷酸单酯或磷酸二酯、磷酸二酯或磷酸作为稳定剂。 芳香族聚碳酸酯无色透明，适合挤出成型。
• Ultraviolet filter coating
  申请人：——

  公开号：US20030170467A1

  公开（公告）日：2003-09-11

  The application discloses a two-layered coating system using an ultraviolet absorber in its inner layer (called the blocking layer), furthest away from the source of ultraviolet exposure, with a fluorescent material that reflects ultraviolet radiation back as blue light. The ultraviolet absorber in the inner layer is used in sufficient concentration to have an ultraviolet cutoff, which can be extended with the fluorescent material. The ultraviolet block material of the present invention has transmittance of the light within a range of wavelength of 300-380 nm of 10% or less, preferably transmittance of the light within a range of wavelength of 300-390 nm of 10% or less, and, particularly preferably, transmittance of the light within a range of 300-400 nm of 10% or less, while it has a transmittance of the light within a range of 420-800 nm wavelength of 90% or more, or, preferably, 95% or more.

  该申请公开了一种双层涂层系统，其内层（称为阻挡层）使用紫外线吸收剂，距离紫外线照射源最远，内层使用的荧光材料可将紫外线辐射反射为蓝光。内层紫外线吸收剂的使用浓度足以产生紫外线截止点，荧光材料可以延长紫外线截止点。本发明的紫外线阻隔材料对波长 300-380 纳米范围内的光的透过率为 10%或更低，最好对波长 300-390 纳米范围内的光的透过率为 10%或更低，尤其最好对波长 300-400 纳米范围内的光的透过率为 10%或更低，而对波长 420-800 纳米范围内的光的透过率为 90%或更高，最好为 95%或更高。
• PHARMACEUTICAL FORMULATIONS CONTAINING SOLUBILIZED HYDROQUINONE, SALICYLIC ACID AND HYDROCORTISONE FOR THE TREATMENT OF MELASMA AND RELATED DERMATOLOGICAL PROBLEMS
  申请人：Lila Gruber Research Foundation

  公开号：US20030194385A1

  公开（公告）日：2003-10-16

  Abstract of the Disclosure There are provided dermatological compositions achieved by combining solubilized, stabilized hydroquinone salicylic acid and hydrocortisone by dissolving the three ingredents in dimethyl isosorbide. These preparations are intended for the treatment of melasma and related disorders of the skin such as freckles, senile lentigines, chloasma, ultraviolet induced dyschromia and discoloration resulting from ingestion of oral contraceptives or hormonal replacement therapy.

  本发明公开的内容提要 本发明提供了通过将溶解稳定的氢醌水杨酸和氢化可的松三种成分溶解在二甲基异山梨醇中而制得的皮肤科组合物。这些制剂用于治疗黄褐斑和相关的皮肤疾病，如雀斑、老年斑、黄褐斑、紫外线引起的色素沉着以及口服避孕药或激素替代疗法引起的色素沉着。
• Patolia, Ravji J.; Trivedi, K. N., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1983, vol. 22, # 5, p. 444 - 447
  作者：Patolia, Ravji J.、Trivedi, K. N.

  DOI：——

  日期：——