1-acryloyl-piperidine-4-carboxylic acid methyl ester | 845907-51-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-acryloyl-piperidine-4-carboxylic acid methyl ester
• 英文别名: Methyl 1-acryloylpiperidine-4-carboxylate；methyl 1-prop-2-enoylpiperidine-4-carboxylate
• CAS: 845907-51-9
• 化学式: C₁₀H₁₅NO₃
• 分子量: 197.234
• InChiKey: XKOYWAJBUZFHDA-UHFFFAOYSA-N

物化性质

• 沸点：
  333.1±31.0 °C(Predicted)
• 密度：
  1.108±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-哌啶甲酸甲酯 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以70%的产率得到1-acryloyl-piperidine-4-carboxylic acid methyl ester
  参考文献：
  名称：

  [EN] ACRYLAMIDE DERIVATIVES AS VLA-1 INTEGRIN ANTAGONISTS AND USES THEREOF
  [FR] DERIVES D'ACRYLAMIDE SERVANT D'ANTAGONISTES DE L'INTEGRINE VLA-1, ET LEURS UTILISATIONS

  摘要：

  公开号：

  WO2005016883A3

文献信息

• FLUOROALKYL GROUP-CONTAINING N-SUBSTITUTED (METH)ACRYLAMIDE COMPOUND, POLYMER THEREOF , AND USE THEREOF
  申请人：Ishiwata Fusae

  公开号：US20120149860A1

  公开（公告）日：2012-06-14

  A compound represented by the following formula (a): CH 2 ═CR 1 —CONJ-CKR 2 —(CH 2 ) n —COO-Q 1 -Rf 1 (a) is provided. This compound is capable of forming a polymer having an oil repellency equivalent to polymers containing a polyfluoroalkyl group containing at least 8 carbon atoms, although the polyfluoroalkyl group contains up to 6 carbon atoms. In the formula, R 1 is hydrogen atom or methyl group, R 2 is hydrogen atom or a group represented by —(CH 2 ) m —COO-Q 2 -Rf 2 (r), n and m are independently an integer of 0 to 4, Rf 1 and Rf 2 are independently a polyfluoroalkyl group or a polyfluoroether group containing 1 to 6 carbon atoms, Q 1 and Q 2 are independently single bond or a divalent linkage group, J is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, K is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, and j and k are independently single bond or an alkylene group containing 1 to 3 carbon atoms with the proviso that j and k are not simultaneously single bond.

  提供了一个由以下化学式（a）表示的化合物：CH2═CR1—CONJ-CKR2—（ ）n—COO-Q1-Rf1(a)。该化合物能够形成一种聚合物，其油脂排斥性与含有至少8个碳原子的聚氟烷基团的聚合物相当，尽管聚氟烷基团仅含有最多6个碳原子。在该式中，R1为氢原子或甲基基团，R2为氢原子或表示为—（ ）m—COO-Q2-Rf2(r)的基团，n和m独立地为0到4的整数，Rf1和Rf2独立地为含有1到6个碳原子的聚氟烷基团或聚氟醚基团，Q1和Q2独立地为单键或双价连接基团，J为氢原子或含有1到3个碳原子的烷基团，K为氢原子或含有1到3个碳原子的烷基团，j和k独立地为单键或含有1到3个碳原子的亚烷基基团，但j和k不同时为单键。
• Composition, accommodating unit, image forming device, and image forming method
  申请人：Hiraoka Takao

  公开号：US10829631B2

  公开（公告）日：2020-11-10

  A composition contains an acrylamide compound A1 having an ester structure and a polymerization initiator B1 having a molecular weight of 800 or more.

  一种组合物含有具有酯结构的丙烯酰胺化合物 A1 和分子量大于等于 800 的聚合引发剂 B1。
• Composition, cured product, image forming apparatus, and image forming method
  申请人：Yamada Hiroaki

  公开号：US10858527B2

  公开（公告）日：2020-12-08

  A composition comprising an acrylamide compound (A1) having an ester structure and a molecular weight of from 150 to 200 and an acylphosphine oxide polymerization initiator (B1) is provided.

  本发明提供了一种由具有酯结构且分子量在 150 到 200 之间的丙烯酰胺化合物 (A1) 和酰基氧化膦聚合引发剂 (B1) 组成的组合物。
• Composition, cured product, composition stored container, image forming apparatus, and image forming method
  申请人：Matsushita Yuuki

  公开号：US11028280B2

  公开（公告）日：2021-06-08

  A composition is provided including an acrylamide compound having an ester structure and a molecular weight of 150 to 200, and a polysilane as a polymerization initiator.

  提供了一种组合物，其中包括具有酯结构且分子量为 150 至 200 的丙烯酰胺化合物，以及作为聚合引发剂的聚硅氧烷。
• Composition, cured product, storage container, image forming apparatus, and image forming method
  申请人：Ricoh Company, Ltd.

  公开号：US11059985B2

  公开（公告）日：2021-07-13

  Provided is a composition including an acrylamide compound (A1) having a molecular weight of 150 or greater but 250 or less, and a trifunctional or higher polymerizable compound (A2), wherein an amount of the trifunctional or higher polymerizable compound (A2) is 1% by mass or greater but 30% by mass or less relative to a total amount of the composition.

  本发明提供了一种组合物，其中包括分子量为 150 或更大但 250 或更小的丙烯酰胺化合物（A1）和三官能或更高的可聚合化合物（A2），其中三官能或更高的可聚合化合物（A2）的用量为组合物总量的 1%（质量分数）或更大但 30%（质量分数）或更小。