4-(6-bromohexyloxy)-phenyl-4-[[6-(acryloyloxy)hexyl]oxy]benzoate | 1011466-26-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(6-bromohexyloxy)-phenyl-4-[[6-(acryloyloxy)hexyl]oxy]benzoate
• 英文别名: 4-(6-bromohexyloxy)phenyl 4-{[6-(acryloyloxy)hexyl]oxy}benzoate；4-(6-Bromo hexyloxy)phenyl 4-{[6-(acryloyloxy)hexyl]oxy}benzoate；[4-(6-bromohexoxy)phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 1011466-26-4
• 化学式: C₂₈H₃₅BrO₆
• 分子量: 547.486
• InChiKey: RCRMRLOWDWHSKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  35
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  {{[(4-n-hexyl-phenyl)diazenyl]-1-naphthyl}diazenyl}-4-phenol 、 4-(6-bromohexyloxy)-phenyl-4-[[6-(acryloyloxy)hexyl]oxy]benzoate 在 2,6-二叔丁基-4-甲基苯酚 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 生成 {{[(4-n-hexyl-phenyl-diazine)-1-naphthyl-diazine]-phenyloxy}-6-hexyloxy}-4-phenyl-4-{[6-(acryloyloxy)hexyl]oxy}benzoate
  参考文献：
  名称：

  WO2008/63033

  摘要：

  公开号：
• 作为产物：
  描述：

  4-(6-溴-己氧基)-苯酚 、 2-丙烯酸,6-[4-(氯羰基)苯氧基]己基酯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成 4-(6-bromohexyloxy)-phenyl-4-[[6-(acryloyloxy)hexyl]oxy]benzoate
  参考文献：
  名称：

  WO2008/63033

  摘要：

  公开号：

文献信息

• DICHROIC DYE FOR POLARIZATION FILM, COMPOSITION COMPRISING THE SAME FOR POLARIZATION FILM, METHOD FOR FORMING POLARIZATION PLATE AND POLARIZATION PLATE PREPARED THEREBY
  申请人：Cho Yong-Il

  公开号：US20090290214A1

  公开（公告）日：2009-11-26

  Disclosed are a new dichroic dye having liquid crystal properties and dichroic properties and capable of being used for forming a polarization film with excellent heat resistance, durability, and polarizing properties, a composition including the same for a polarization film, a method for forming a polarization plate with excellent durability using the composition, and a polarization plate prepared thereby. The new dichroic dye has a structure of R1-L1-(M,L,D) (where, D is a dichroic structure, M is a structure with liquid crystal properties, R1 is a reactive end functional group, and L and L1 are linking structures). The composition for a polarization film includes the dichroic dye. In the method for forming the polarization plate, the composition for a polarization film is applied to a substrate and cured to prepare the polarization plate. The polarization plate has excellent dichroic ratio, heat resistance, durability, and polarizing properties.

  本发明公开了一种新的具有液晶性能和双折射性能的二色染料，可用于形成具有优异耐热性、耐久性和偏振性能的偏振膜的组合物，以及使用该组合物制备具有优异耐久性的偏振板的方法和所制备的偏振板。新的二色染料具有R1-L1-(M,L,D)的结构（其中，D是双折射结构，M是具有液晶性能的结构，R1是反应性末端功能团，L和L1是连接结构）。偏振膜的组合物包括该二色染料。在制备偏振板的方法中，将偏振膜的组合物涂覆在基板上并固化以制备偏振板。该偏振板具有优异的双折射比、耐热性、耐久性和偏振性能。
• COMPOSITION COMPRISING CURABLE DICHROIC DYE FOR FORMING OPTICAL COMPONENT AND AN OPTICAL COMPONENT PRERARED USING THE SAME
  申请人：Cho Yong Il

  公开号：US20100055353A1

  公开（公告）日：2010-03-04

  The present invention relates to a composition comprising a curable dichroic dye and a curable liquid crystal compound, which are used to prepare an optical component that is vertically oriented to give a narrow viewing angle, to form an optical component, and an optical component comprising an optical component layer prepared using the same. There is provided a composition for forming an optical component comprising 0.1-90 parts by weight of a dichroic dye and 10-98.85 parts by weight of a curable liquid crystal compound, and there is also provided an optical component comprising an optical component layer in which a curable liquid crystal compound and a curable dichroic dye are vertically oriented. The optical component comprising an optical component layer in which a curable dichroic dye and a curable liquid crystal compound are vertically oriented and which is made of the composition comprising a curable dichroic dye and a curable liquid crystal compound for forming an optical component has excellent physical properties such as heat resistance, durability to high temperature and high moisture, vertical orientation and dichroic ratio, and also adjust a narrow viewing angle. The durability in the high temperature and high moisture is due to the cross linking shape of the optical component layer.

  本发明涉及一种组合物，包括可固化的二色性染料和可固化的液晶化合物，用于制备垂直定向的、具有狭窄视角的光学组件，形成光学组件，以及包含使用相同的光学组件层的光学组件。提供了一种用于形成光学组件的组合物，包括0.1-90重量份的二色性染料和10-98.85重量份的可固化液晶化合物，还提供了一种光学组件，其中包含垂直定向的可固化液晶化合物和可固化二色性染料的光学组件层。由可固化二色性染料和可固化液晶化合物组成的用于形成光学组件的组合物制成的光学组件，具有优异的物理性能，如耐高温、耐高湿、垂直定向和二色性比，还可以调节狭窄的视角。在高温和高湿环境下的耐久性是由于光学组件层的交联形状。
• DICHROIC DYE FOR COLOR FILTER, COMPOSITION COMPRISING THE SAME FOR COLOR FILTER AND COLOR FILTER ARRAY PREPARED THEREFROM
  申请人：Cho Yong-Il

  公开号：US20100066950A1

  公开（公告）日：2010-03-18

  There is provided a novel dichroic dye having liquid crystal properties, dichroic properties and polymerizable reactivity, the dichroic dye being used to form a color filter layer having excellent physical properties such as dichroic ratio, heat resistance, durability, high contrast ratio and polarizing properties, a composition comprising the same for color filter, a color filter array plate (an upper plate) prepared therefrom, and a liquid crystal display comprising the color filter array plate. The dichroic dye has a structure of R1-L1-M-L2-D (wherein, D is a dichroic structure, M is a structure with liquid crystal properties, R1 is a reactive end functional group, and L and L1 are linking structures that link R1, M, and D), and the composition for forming a color filter layer includes the dichroic dye. Also, the color filter array plate, which comprises color filter layer formed of the composition of this invention and the liquid crystal display, which comprise the color filter array plate but does not requires an upper alignment film and/or a polarization plate are provided. The color filter array plate and the liquid crystal display comprising the same have excellent physical properties such as durability, polarizing degree, resolution and contrast ratio.

  本发明提供了一种新型二色性染料，具有液晶性能、二色性和可聚合反应性，该二色性染料用于形成具有优异物理性能的彩色滤光层，如二色比、耐热性、耐久性、高对比度比和极化性能，以及包含该二色性染料的彩色滤光器组成物、由此制备的彩色滤光器阵列板（上板）和包括彩色滤光器阵列板的液晶显示器。该二色性染料具有R1-L1-M-L2-D的结构（其中，D为二色性结构，M为具有液晶性能的结构，R1为反应末端官能团，L和L1为连接R1、M和D的连接结构），用于形成彩色滤光层的组成物包括该二色性染料。此外，本发明提供了包括由本发明组成物形成的彩色滤光层的彩色滤光器阵列板和不需要上部对准膜和/或偏振板的液晶显示器。包括彩色滤光器阵列板的液晶显示器具有耐久性、极化度、分辨率和对比度等优异的物理性能。
• Dichroic dye for color filter, composition comprising the same for color filter and color filter array prepared therefrom
  申请人：Cho Yong-Il

  公开号：US08465671B2

  公开（公告）日：2013-06-18

  There is provided a novel dichroic dye having liquid crystal properties, dichroic properties and polymerizable reactivity, the dichroic dye being used to form a color filter layer having excellent physical properties such as dichroic ratio, heat resistance, durability, high contrast ratio and polarizing properties, a composition comprising the same for color filter, a color filter array plate (an upper plate) prepared therefrom, and a liquid crystal display comprising the color filter array plate. The dichroic dye has a structure of R1-L1-M-L2-D (wherein, D is a dichroic structure, M is a structure with liquid crystal properties, R1 is a reactive end functional group, and L and L1 are linking structures that link R1, M, and D), and the composition for forming a color filter layer includes the dichroic dye. Also, the color filter array plate, which comprises color filter layer formed of the composition of this invention and the liquid crystal display, which comprise the color filter array plate but does not requires an upper alignment film and/or a polarization plate are provided. The color filter array plate and the liquid crystal display comprising the same have excellent physical properties such as durability, polarizing degree, resolution and contrast ratio.

  提供了一种新型的二色性染料，具有液晶性能、二色性能和可聚合反应性，该二色性染料用于形成具有卓越物理性能（如二色比、耐热性、耐久性、高对比度比和偏振性能）的彩色滤光层，包括该染料的组合物用于彩色滤光器，以及由此制备的彩色滤光器阵列板（上板），以及包括该彩色滤光器阵列板的液晶显示器。该二色性染料具有R1-L1-M-L2-D的结构（其中，D是二色结构，M是具有液晶性能的结构，R1是反应端官能团，L和L1是连接R1、M和D的连接结构），用于形成彩色滤光层的组合物包括该二色性染料。此外，提供了包括本发明组合物形成的彩色滤光层的彩色滤光器阵列板和不需要上层对准膜和/或偏振板的液晶显示器。该彩色滤光器阵列板和包括其的液晶显示器具有卓越的物理性能，如耐久性、偏振度、分辨率和对比度。
• Composition comprising curable dichroic dye for forming optical component and an optical component prepared using the same
  申请人：Cho Yong Il

  公开号：US08545717B2

  公开（公告）日：2013-10-01

  The present invention relates to a composition comprising a curable dichroic dye and a curable liquid crystal compound, which are used to prepare an optical component that is vertically oriented to give a narrow viewing angle, to form an optical component, and an optical component comprising an optical component layer prepared using the same. There is provided a composition for forming an optical component comprising 0.1-90 parts by weight of a dichroic dye and 10-98.85 parts by weight of a curable liquid crystal compound, and there is also provided an optical component comprising an optical component layer in which a curable liquid crystal compound and a curable dichroic dye are vertically oriented. The optical component comprising an optical component layer in which a curable dichroic dye and a curable liquid crystal compound are vertically oriented and which is made of the composition comprising a curable dichroic dye and a curable liquid crystal compound for forming an optical component has excellent physical properties such as heat resistance, durability to high temperature and high moisture, vertical orientation and dichroic ratio, and also adjust a narrow viewing angle. The durability in the high temperature and high moisture is due to the cross linking shape of the optical component layer.

  本发明涉及一种包含可固化二色性染料和可固化液晶化合物的组合物，用于制备垂直取向的光学组件，以提供狭窄的视角，形成光学组件，以及包含使用相同的光学组件层的光学组件。提供了一种用于形成光学组件的组合物，包括0.1-90重量份的二色性染料和10-98.85重量份的可固化液晶化合物，并且还提供了一种包含可固化液晶化合物和可固化二色性染料垂直取向的光学组件层的光学组件。使用包含可固化二色性染料和可固化液晶化合物的组合物制备的光学组件具有优异的物理性能，如耐热性、高温高湿耐久性、垂直取向和二色性比，还可以调节狭窄的视角。在高温高湿条件下的耐久性是由于光学组件层的交联形状所致。