1-ethyl-1-octyl-piperidinium bromide | 23489-01-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-ethyl-1-octyl-piperidinium bromide
• 英文别名: EOPipBr；1-Aethyl-1-n-octylpiperidiniumbromid；1-Ethyl-1-octylpiperidinium bromide；1-ethyl-1-octylpiperidin-1-ium;bromide
• CAS: 23489-01-2
• 化学式: Br*C₁₅H₃₂N
• 分子量: 306.33
• InChiKey: OYVULUZBDZCRFD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933399090

反应信息

• 作为反应物：
  描述：

  1-ethyl-1-octyl-piperidinium bromide 、 bis(trifluoromethane)sulfonimide lithium 以 水 为溶剂， 反应 5.0h， 生成 1-ethyl-1-octyl-piperidinium bis(trifluoromethylsulfonyl)imide
  参考文献：
  名称：

  H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound

  摘要：

  The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis. (C) 2012 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jcat.2012.04.016
• 作为产物：
  描述：

  N-乙基哌啶 、 1-溴辛烷 以 乙酸乙酯 为溶剂， 反应 15.0h， 生成 1-ethyl-1-octyl-piperidinium bromide
  参考文献：
  名称：

  H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound

  摘要：

  The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis. (C) 2012 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jcat.2012.04.016

文献信息

• LACKO I.; DEVINSKY F.; MLYNARCIK D.; KRASNEC L., CS. FARM., 1977, 26, NO 5, 150-153
  作者：LACKO I.、 DEVINSKY F.、 MLYNARCIK D.、 KRASNEC L.

  DOI：——

  日期：——
• H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound
  作者：Gregory Chatel、Catherine Goux-Henry、Anaïs Mirabaud、Thomas Rossi、Nathalie Kardos、Bruno Andrioletti、Micheline Draye

  DOI：10.1016/j.jcat.2012.04.016

  日期：2012.7

  The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis. (C) 2012 Elsevier Inc. All rights reserved.
• Electrodeposition of stoichiometric bismuth telluride Bi2Te3 using a piperidinium ionic liquid binary mixture
  作者：Jonathan Szymczak、Sophie Legeai、Stéphanie Michel、Sébastien Diliberto、Nicolas Stein、Clotilde Boulanger

  DOI：10.1016/j.electacta.2014.06.036

  日期：2014.8