1,1,2,2,3,3-Hexaethyl-trisilan | 50518-30-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,2,2,3,3-Hexaethyl-trisilan
• 英文别名: bis(diethylsilyl)-diethylsilane
• CAS: 50518-30-4
• 化学式: C₁₂H₃₂Si₃
• 分子量: 260.643
• InChiKey: HNDUXVUQWYPUCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.17
• 重原子数：
  15.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  二乙基硅烷 在 Wilkinson's catalyst 作用下， 生成 1,1,2,2,3,3-Hexaethyl-trisilan
  参考文献：
  名称：

  三（三苯基膦）氯铑对聚氢甲硅烷的作用

  摘要：

  DOI：

  10.1016/s0022-328x(00)84018-8

文献信息

• Reactivity of group 4 benzamidinate complexes towards mono- and bis-substituted silanes and 1,5-hexadiene
  作者：Victoria Volkis、Claudia Averbuj、Moris S. Eisen

  DOI：10.1016/j.jorganchem.2007.01.002

  日期：2007.4

  Zirconium and titanium bis(benzamidinate) dimethyl complexes were found to be active catalytic precursors for the oligomerization of mono- and bis-substituted silanes. The activation of such complexes, by an excess of MAO or by an equimolar amount of B(C6F5)(3), increases the catalytic activity of the complexes and the molecular weight of the obtained oligosilanes. The maximum polymerization index that was accomplished (n = 90) is by far the largest obtained with other organometallic complexes. In addition, the activated benzamidinate catalysts were also found to be active for the polymerization of 1,5-hexadiene producing poly(methyl-1,3-cyclopentane). For the latter, the results obtained with C-2-symmetry bis(benzamidinate) dimethyl complexes were compared with a chiral complex bearing a myrtanyl group at the benzamidinate ligand. (c) 2007 Elsevier B.V. All rights reserved.
• CARLSON, C. W.;WEST, R., ORGANOMETALLICS, 1983, 2, N 12, 1801-1807
  作者：CARLSON, C. W.、WEST, R.

  DOI：——

  日期：——
• CARLSON, C. W.;WEST, R., ORGANOMETALLICS, 1983, 2, N 12, 1792-1797
  作者：CARLSON, C. W.、WEST, R.

  DOI：——

  日期：——
• The action of tris(triphenylphosphine)chlororhodium on polyhydromonosilanes
  作者：Iwao Ojima、Shin-Ichi Inaba、Tetsuo Kogure、Yoichiro Nagai

  DOI：10.1016/s0022-328x(00)84018-8

  日期：1973.7