triphenyl-[(E)-3-prop-2-enoxyprop-1-enyl]silane | 1026847-01-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: triphenyl-[(E)-3-prop-2-enoxyprop-1-enyl]silane
• CAS: 1026847-01-7
• 化学式: C₂₄H₂₄OSi
• 分子量: 356.539
• InChiKey: OUTDAYDFLPBCFA-CIAFOILYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.45
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  allyl propargyl ether 、 三苯基硅烷 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 、 三叔丁基膦 作用下， 以 四氢呋喃 为溶剂， 以97%的产率得到triphenyl-[(E)-3-prop-2-enoxyprop-1-enyl]silane
  参考文献：
  名称：

  Tri(t-butyl)phosphine-assisted selective hydrosilylation of terminal alkynes

  摘要：

  A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt(DVDS)-tri(t-butyl)phosphine catalyst system at room temperature. Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed. (C) 2009 Wei Wu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2009.11.040

文献信息

• Tri(t-butyl)phosphine-assisted selective hydrosilylation of terminal alkynes
  作者：Wei Wu、Xiao Yun Zhang、Shou Xing Kang、Yan Min Gao

  DOI：10.1016/j.cclet.2009.11.040

  日期：2010.3

  A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt(DVDS)-tri(t-butyl)phosphine catalyst system at room temperature. Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed. (C) 2009 Wei Wu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.