Bis(trimethylsilyl)azanide;propan-2-yl-(7-propan-2-yliminocyclohepta-1,3,5-trien-1-yl)azanide;yttrium(3+) | 204933-67-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Bis(trimethylsilyl)azanide;propan-2-yl-(7-propan-2-yliminocyclohepta-1,3,5-trien-1-yl)azanide;yttrium(3+)
• CAS: 204933-67-5
• 化学式: C₃₂H₅₆N₅Si₂Y
• 分子量: 655.907
• InChiKey: IOHFHVXFBQFQRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.85
• 重原子数：
  40
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  、 双(三甲基硅烷基)氨基钾 以 甲苯 为溶剂， 以71%的产率得到Bis(trimethylsilyl)azanide;propan-2-yl-(7-propan-2-yliminocyclohepta-1,3,5-trien-1-yl)azanide;yttrium(3+)
  参考文献：
  名称：

  (Aminotroponiminato)yttrium Amides as Catalysts in Alkyne Hydroamination

  摘要：

  The synthesis and characterization of the mono-and bis(N-isopropyl-2-(isopropylamino)troponiminato)yttrium amides [(iPr)(2)ATI]Y[N(SiMe3)(2)](2) and [(iPr)(2)ATI](2)Y[N(SiMe3)(2)], with the corresponding chloro precursors [[(iPr)(2)ATI]YCl2(THF)(2)](2) and [(iPr)(2)ATI](2)YCl as starting materials, is reported together zuith their application as precatalysts for the hydroamination/cyclization of aminoalkynes.

  DOI：

  10.1021/om9711077

文献信息

• (Aminotroponiminato)yttrium Amides as Catalysts in Alkyne Hydroamination
  作者：Markus R. Bürgstein、Helga Berberich、Peter W. Roesky

  DOI：10.1021/om9711077

  日期：1998.4.1

  The synthesis and characterization of the mono-and bis(N-isopropyl-2-(isopropylamino)troponiminato)yttrium amides [(iPr)(2)ATI]Y[N(SiMe3)(2)](2) and [(iPr)(2)ATI](2)Y[N(SiMe3)(2)], with the corresponding chloro precursors [[(iPr)(2)ATI]YCl2(THF)(2)](2) and [(iPr)(2)ATI](2)YCl as starting materials, is reported together zuith their application as precatalysts for the hydroamination/cyclization of aminoalkynes.