2-Dicyanmethylen-1,3-dithiol | 5634-08-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: 2-Dicyanmethylen-1,3-dithiol
• 英文别名: 1,3-Dithiol-2-ylidenepropanedinitrile；2-(1,3-dithiol-2-ylidene)propanedinitrile
• CAS: 5634-08-2
• 化学式: C₆H₂N₂S₂
• 分子量: 166.227
• InChiKey: PZBVFWGVGHNQMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  98.2
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof
  申请人：Gao Xike

  公开号：US20120253045A1

  公开（公告）日：2012-10-04

  Sulfur containing heterocycle-fused naphthalenetetracarboxylic acid diimide derivatives represented by formula (I) are disclosed, in which, R 1 and R 2 are C 1 -C 30 and C 1 -C 12 linear alkyl or branched alkyl, respectively; R 3 is H or halogen atom. The preparation method of the derivatives and the use thereof in manufacture of organic thin film field effect transistor or organic solar batteries are also disclosed.

  公开了由式(I)表示的含硫杂环融合萘四羧酸二亚胺衍生物，其中，R1和R2分别为C1-C30和C1-C12的线性或支链烷基；R3为H或卤素原子。还公开了这些衍生物的制备方法以及它们在制造有机薄膜场效应晶体管或有机太阳能电池中的用途。
• [EN] 3,7-BIS(2-OXOINDOLIN-3-YLIDENE)BENZO[1,2-B:4,5-B']DIFURAN-2,6-DIONE DICYANIDE-BASED MATERIALS AND USES THEREOF IN ORGANIC ELECTRONIC DEVICES<br/>[FR] MATÉRIAUX À BASE DE DICYANIDE DE 3,7-BIS(2-OXOINDOLIN-3-YLIDÈNE)BENZO[1,2-B:4,5-B']DIFURAN-2,6-DIONE ET LEURS UTILISATIONS DANS DES DISPOSITIFS ÉLECTRONIQUES ORGANIQUES
  申请人：NAT RES COUNCIL CANADA

  公开号：WO2019175804A1

  公开（公告）日：2019-09-19

  The development of air-stable unipolar n-type semiconductors with good solubility in organic solvents at room temperature remains a critical issue in the field of organic electronics. Moreover, most of the existing semiconducting materials exhibit LUMO energy levels higher than -4.0 eV, making electron transport sensitive to both moisture and oxygen. Bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof are disclosed herein. More specifically, bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof for use in organic electronics are disclosed. A process for the preparation of bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide and derivatives is also disclosed. The bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof are characterized by high electron mobilities and are suitable for use as n-type semiconductors in organic electronics.

  在有机电子学领域，开发具有良好溶解度且在室温下稳定的n型半导体仍然是一个关键问题。此外，大多数现有的半导体材料的LUMO能级高于-4.0 eV，使得电子传输对水分和氧气都非常敏感。本文介绍了双(2-氧代吲哚-3-亚甲基)苯二呋喃酮二氰化物或其衍生物。更具体地，本文介绍了用于有机电子学的双(2-氧代吲哚-3-亚甲基)苯二呋喃酮二氰化物或其衍生物。还介绍了一种制备双(2-氧代吲哚-3-亚甲基)苯二呋喃酮二氰化物和其衍生物的方法。双(2-氧代吲哚-3-亚甲基)苯二呋喃酮二氰化物或其衍生物具有高电子迁移率，并适用于有机电子学中的n型半导体。
• [EN] NAPHTHALENE DIIMIDE CONTAINING 2-(1,3-DITHIO/SELENO-2-SUBUNIT)ETHYLCYANIDE CONJUGATE STRUCTURAL UNIT AND DERIVATIVES THEREOF<br/>[FR] NAPHTALÈNE DIIMIDE CONTENANT UN MOTIF STRUCTUREL CONJUGUÉ DE CYANURE DE 2-(1,3-DITHIO/SÉLÉNO-2-SOUS-MOTIF)ÉTHYLE ET SES DÉRIVÉS<br/>[ZH] 含2-（1,3-二硫/硒-2-亚基）乙氰共轭结构单元的萘二酰亚胺及其衍生物
  申请人：SHANGHAI INST OF ORGANIC CHENMISTRY CHINESE ACADEMY OF SCIENCES

  公开号：WO2016029843A1

  公开（公告）日：2016-03-03

  一种含2-(1,3-二硫/硒-2-亚基)乙氰共轭结构单元的萘二酰亚胺及其衍生物。具体地，一种如下式(A)所示的化合物，其中各基团定义如说明书所述。该单体可以制备一系列拥有优良器件性能的聚合物（二聚物或多聚物），所述聚合物可用于制备性能良好的有机光电器件。
• SULFUR CONTAINING HETEROCYCLE-FUSED NAPHTHALENE TETRACARBOXYLIC ACID DIIMIDE DERIVATIVES, PREPARATION METHOD AND USE THEREOF
  申请人：Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences

  公开号：EP2492271B1

  公开（公告）日：2018-05-09
• 3,7-BIS(2-OXOINDOLIN-3-YLIDENE)BENZO[1,2-B:4,5-B']DIFURAN-2,6-DIONE DICYANIDE-BASED MATERIALS AND USES THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：National Research Council of Canada

  公开号：EP3765457A1

  公开（公告）日：2021-01-20