Bis-[2-(2-{2-[2-(2-{2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-dimethyl-silane | 592471-65-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Bis-[2-(2-{2-[2-(2-{2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-dimethyl-silane
• 英文别名: 27,27-Dimethyl-2,5,8,11,14,17,20,23,26,28,31,34,37,40,43,46,49,52-octadecaoxa-27-silatripentacontane；bis[2-[2-[2-[2-[2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]-dimethylsilane
• CAS: 592471-65-3
• 化学式: C₃₆H₇₆O₁₈Si
• 分子量: 825.074
• InChiKey: QNAUEDIPHBRZJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.25
• 重原子数：
  55
• 可旋转键数：
  50
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  166
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  八甘醇单甲醚 、 二氯二甲基硅烷 生成 Bis-[2-(2-{2-[2-(2-{2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-dimethyl-silane
  参考文献：
  名称：

  硅多足体：强大的金属阳离子络合剂和新一代固液相转移催化剂

  摘要：

  硅多键5 – 7是低极性溶剂中的强碱金属盐络合剂，在固液PTC条件下阴离子促进的反应中是非常有效的催化剂。催化活性与环状聚醚PHDB18C6 8相当。

  DOI：

  10.1016/s0040-4039(03)00838-4

文献信息

• Silicon polypodands: powerful metal cation complexing agents and solid–liquid phase-transfer catalysts of new generation
  作者：Angelamaria Maia、Dario Landini、Boguslawa Leska、Grzegorz Schroeder

  DOI：10.1016/s0040-4039(03)00838-4

  日期：2003.5

  Silicon polypodands 5–7 are found to be powerful complexing agents of alkali metal salts in low polarity solvents and very efficient catalysts in anion-promoted reactions under solid–liquid PTC conditions. The catalytic activity is comparable with that of the cyclic polyether PHDB18C6 8.

  硅多键5 – 7是低极性溶剂中的强碱金属盐络合剂，在固液PTC条件下阴离子促进的反应中是非常有效的催化剂。催化活性与环状聚醚PHDB18C6 8相当。
• The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and monovalent cations
  作者：Bogusława Łęska、Piotr Przybylski、Joanna Wyrwał、Bogumił Brzezinski、Grzegorz Schroeder、Volodimir Rybachenko、Angelamaria Maia

  DOI：10.1016/j.molstruc.2004.08.021

  日期：2005.1

  Silicon podands (1-10) were synthesised and their complexation reaction of Na+ cations were studied by calorimetric and PM5 theoretical methods. Both methods provide evidence for formation of the respective complexes with Na+ cations of different stoichiometry. In most cases, only formation of the complexes of 1:1 stoichiometry has been observed. For compounds with longer oxaalkyl chains (9 and 10) the formation of 1:4 and 1:6 complexes has been found. The structures of the complexes are visualised and discussed. (C) 2004 Elsevier B.V. All rights reserved.