Gold--vanadium (1/3) | 12256-58-5

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Gold--vanadium (1/3)
• 英文别名: gold;vanadium
• CAS: 12256-58-5
• 化学式: AuV₃
• 分子量: 349.791
• InChiKey: XDFOOIDHSOAGTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  钒 、 金 以 neat (no solvent) 为溶剂， 生成 Gold--vanadium (1/3)
  参考文献：
  名称：

  Study of the electronic structure of Au–V bimetallics using X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES)

  摘要：

  Core-level binding energy shifts and valence band behaviour for Au-V intermetallic compounds have been studied with X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES). It is found that both the Au 4f and V 2p core levels exhibit a positive binding energy shift, relative to the pure metals. These results can be explained with the charge compensation model (Watson et al., Phys. Rev. B4 (1971) 4139): there is an increase in the number of sp-like conduction electrons accompanied by a decrease in the d-electron count at the Au site resulting in a small net charge flow onto the Au site in accord with electronegativity and electroneutrality considerations. Au L-edge X-ray absorption near-edge structures (XANES) provide direct evidence for d-charge depletion at the gold site confirming the XPS results. V g-edge XANES indicate d-charge depletion at the V site, as well. These results are compared with those for Au-Ti and Au-Ta alloys. (C) 1999 Published by Elsevier Science S.A.

  DOI：

  10.1016/s0925-8388(98)00908-6

文献信息

• Study of the electronic structure of Au–V bimetallics using X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES)
  作者：S.J. Naftel、A. Bzowski、T.K. Sham

  DOI：10.1016/s0925-8388(98)00908-6

  日期：1999.2

  Core-level binding energy shifts and valence band behaviour for Au-V intermetallic compounds have been studied with X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES). It is found that both the Au 4f and V 2p core levels exhibit a positive binding energy shift, relative to the pure metals. These results can be explained with the charge compensation model (Watson et al., Phys. Rev. B4 (1971) 4139): there is an increase in the number of sp-like conduction electrons accompanied by a decrease in the d-electron count at the Au site resulting in a small net charge flow onto the Au site in accord with electronegativity and electroneutrality considerations. Au L-edge X-ray absorption near-edge structures (XANES) provide direct evidence for d-charge depletion at the gold site confirming the XPS results. V g-edge XANES indicate d-charge depletion at the V site, as well. These results are compared with those for Au-Ti and Au-Ta alloys. (C) 1999 Published by Elsevier Science S.A.