Erbium--nickel (1/5) | 12357-24-3

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间镧系化合物
• 英文名称: Erbium--nickel (1/5)
• 英文别名: erbium;nickel
• CAS: 12357-24-3
• 化学式: ErNi₅
• 分子量: 460.71
• InChiKey: DKJVODFEQNFQKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  镍 、 氢化铒 以 melt 为溶剂， 生成 Erbium--nickel (1/5)
  参考文献：
  名称：

  Magnetocaloric effect in theRNi5(R=Pr, Nd, Gd, Tb, Dy, Ho, Er) series

  摘要：

  In this paper, the magnetocaloric effect in the hexagonal intermetallic compounds belonging to the RNi5 series was calculated using a Hamiltonian including the crystalline electrical field, exchange interaction, and the Zeeman effect. Experimental work was performed and the two thermodynamics quantities, namely, isothermal entropy change and adiabatic temperature change were obtained for polycrystalline samples, using heat capacity measurements, and compared to the theoretical predictions.

  DOI：

  10.1103/physrevb.70.134428

文献信息

• The isothermal section of the Er–Mn–Ni ternary system at 803 K
  作者：Jingqi Liu、Fangwei Jiao、Yinghong Zhuang、Fengquan Ma、Zhihui Sun

  DOI：10.1016/j.jallcom.2004.04.086

  日期：2004.12

  The isothermal section of the phase diagram of the Er-Mn-Ni ternary system at 803 K was investigated by X-ray powder diffraction with the aid of microanalysis and electron probe microanalysis techniques. It consists of 14 single-phase regions, 24 two-phase regions, and 11 three-phase regions. At 803 K, the maximum solid solubility of Mn in Ni, Er2Ni17,ErNi5,Er2Ni7,ErNi3, and ErNi2 is about 31, 13, 8,4, 3, and 2 at.% Mn, respectively. The maximum solid solubility of Ni in Mn, ErMn12, and Er6Mn23 is about 3 at.% Ni, for all three compounds. The existence of ErNi4, Er4Ni17, and Er5Ni22 has not been confirmed. The existence of any ternary compound of the Er-Mn-Ni was not observed. (C) 2004 Elsevier B.V. All rights reserved.
• The 773 K isothermal section of Er–Ni–Sb phase diagram
  作者：Lingmin Zeng、Lizhen Tan

  DOI：10.1016/s0925-8388(02)00522-4

  日期：2002.11

  The isothermal section of the Er-Ni-Sb ternary system at 773 K has been investigated mainly by X-ray powder diffraction with the aid of differential thermal analysis and scanning electron microscopy. The formation of the previously reported ErNiSb and Er5Ni2Sb, was confirmed. No new ternary compounds were observed. (C) 2002 Elsevier Science B.V. All rights reserved.
• Magnetocaloric effect in the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:msub><mml:mi mathvariant="normal">Ni</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">Pr</mml:mi></mml:mrow></mml:math>, Nd, Gd, Tb, Dy, Ho, Er) series
  作者：P. J. von Ranke、M. A. Mota、D. F. Grangeia、A. Magnus G. Carvalho、F. C. G. Gandra、A. A. Coelho、A. Caldas、N. A. de Oliveira、S. Gama

  DOI：10.1103/physrevb.70.134428

  日期：——

  In this paper, the magnetocaloric effect in the hexagonal intermetallic compounds belonging to the RNi5 series was calculated using a Hamiltonian including the crystalline electrical field, exchange interaction, and the Zeeman effect. Experimental work was performed and the two thermodynamics quantities, namely, isothermal entropy change and adiabatic temperature change were obtained for polycrystalline samples, using heat capacity measurements, and compared to the theoretical predictions.
• Ternary system Er–Ni–In at T=870K
  作者：M. Dzevenko、Yu. Tyvanchuk、L. Bratash、V. Zaremba、L. Havela、Ya. Kalychak

  DOI：10.1016/j.jssc.2011.08.006

  日期：2011.10

  Isothermal section of the Er-Ni-In system at T=870 K was constructed by means of X-ray powder diffraction and EDX-analyses. Nine ternary compounds, namely ErNi9In2 (YNi9In2-type), Er1-1.22NI4In1-0.78 (MgCu4Sn-type), Er10Ni9.07In20 (Ho10Ni9In20-type), ErNi1-0.60In1-1.40 (ZrNiAl-type), Er2Ni2In (Mn(2)AIB(2)-type), Er2Ni1.78In (Mo2FeB2-type), Er5Ni2In4 (Lu5Ni2In4-type), Er5Ni2In (Mo5SiB2-type), and Er13.53Ni3.14In3.33 (Lu14Co2In3-type), exist in the Er-Ni-In system at this temperature. The substitution of Ni for In was observed for ErNi1-0.60In1-1.40 and In for Er in the case of related compounds ErNi2 and ErNi4In. Er can enter NiIn (CoSn-type) leading to including-substitution type of compound Er0-0.12NiIn1-0.89. Basic magnetic properties of the Er0.04NiIn0.97, ErNi2, Er0.9Ni2In0.1, and ErNi4In phases were inspected. Electrical-resistivity studies were performed on the ErNiIn, ErNi0.9In1.1, and ErNi4In phases. (C) 2011 Elsevier Inc. All rights reserved.
• Yermolenko; Korolev; Kuchin, Physics of Metals and Metallography, 1984, vol. 57, # 5, p. 70 - 75
  作者：Yermolenko、Korolev、Kuchin

  DOI：——

  日期：——