(yttrium)3 nickel | 12363-03-0

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: (yttrium)3 nickel
• 英文别名: nickel;yttrium
• CAS: 12363-03-0
• 化学式: NiY₃
• 分子量: 325.408
• InChiKey: FDSUYEJJCWEMLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (yttrium)3 nickel 、 氢气 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Metal–semiconductor–insulator transitions in R3Ni compounds induced by hydrogenation

  摘要：

  Electrical resistivity and ac magnetic susceptibility measurements of R3Ni and their hydrides R3NiHx were carried out. It is shown that the conductivity of R3NiHx compounds with a large amount of hydrogen have semiconductor and insulator conductivity type as compared with metallic conduction in the original compounds R3Ni. The resistivity of the original compounds is discussed on the basis of a conduction electron scattering model. Strongly modified transport processes of the hydrides are discussed on basis of a 'hopping' model. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)01238-x
• 作为产物：
  描述：

  氢化钇 、 镍 以 neat (no solvent) 为溶剂， 生成 (yttrium)3 nickel
  参考文献：
  名称：

  Metal–semiconductor–insulator transitions in R3Ni compounds induced by hydrogenation

  摘要：

  Electrical resistivity and ac magnetic susceptibility measurements of R3Ni and their hydrides R3NiHx were carried out. It is shown that the conductivity of R3NiHx compounds with a large amount of hydrogen have semiconductor and insulator conductivity type as compared with metallic conduction in the original compounds R3Ni. The resistivity of the original compounds is discussed on the basis of a conduction electron scattering model. Strongly modified transport processes of the hydrides are discussed on basis of a 'hopping' model. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)01238-x

文献信息

• Isothermal section of the phase diagram of the ternary system Y–Ni–V at 773K
  作者：Shunkang Pan、Huaiying Zhou、Qin Zhou、Qingrong Yao、Zhongmin Wang

  DOI：10.1016/j.jallcom.2008.04.002

  日期：2009.3

  The isothermal section of the phase diagram of the ternary system Y-Ni-V at 773 K was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectroscopy (EDS) techniques. It consists of 16 single-phase regions, 29 two-phase regions and 14 three-phase regions. At 773 K, the maximum solid solubility of V in Ni, Y2Ni17, YNi5, Y2Ni7, YNi3, and YNi2, is about 17, 1, 2, 2, 2 and 2 at.%, while Y in Ni, Ni3V, Ni2V, Ni2V3, NiV3 and V does not exceed 1 at.%. No ternary compound has been observed in this work. (c) 2008 Published by Elsevier B.V.
• Mozharivskii; Kuz'ma; Sichevich, Inorganic Materials, 1998, vol. 34, # 7, p. 707 - 710
  作者：Mozharivskii、Kuz'ma、Sichevich

  DOI：——

  日期：——
• Metal–semiconductor–insulator transitions in R3Ni compounds induced by hydrogenation
  作者：S.A Nikitin、N.V Tristan、T Palewski、Yu.V Skourski、K Nenkov、V.N Verbetsky、A.A Salamova

  DOI：10.1016/s0925-8388(00)01238-x

  日期：2001.1

  Electrical resistivity and ac magnetic susceptibility measurements of R3Ni and their hydrides R3NiHx were carried out. It is shown that the conductivity of R3NiHx compounds with a large amount of hydrogen have semiconductor and insulator conductivity type as compared with metallic conduction in the original compounds R3Ni. The resistivity of the original compounds is discussed on the basis of a conduction electron scattering model. Strongly modified transport processes of the hydrides are discussed on basis of a 'hopping' model. (C) 2001 Elsevier Science B.V. All rights reserved.