1,2-dichloro-1,1-dihexyl-2,2-dimethylsilane | 129064-84-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-dichloro-1,1-dihexyl-2,2-dimethylsilane
• 英文别名: 1,2-Dichloro-1,1-dihexyl-2,2-dimethyldisilane；chloro-[chloro(dihexyl)silyl]-dimethylsilane
• CAS: 129064-84-2
• 化学式: C₁₄H₃₂Cl₂Si₂
• 分子量: 327.485
• InChiKey: BKUGDADDOMZRLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.85
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  联苯 、 1,2-dichloro-1,1-dihexyl-2,2-dimethylsilane 在 lithium 作用下， 以 四氢呋喃 为溶剂， 以62%的产率得到1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene
  参考文献：
  名称：

  Alkoxide initiation of anionic polymerization of masked disilenes to polysilanes

  摘要：

  The polymerization of masked disilenes initiated by potassium alkoxides in the presence of cryptand[2.2.2] in benzene proceeded in a living manner, especially when using potassium (-)-menthoxide. The molecular weights of the polysilanes thus obtained were in good agreement with the calculated values. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00486-1

文献信息

• Alkoxide initiation of anionic polymerization of masked disilenes to polysilanes
  作者：Takanobu Sanji*、Kiichi Kawabata、Hideki Sakurai*

  DOI：10.1016/s0022-328x(00)00486-1

  日期：2000.10

  The polymerization of masked disilenes initiated by potassium alkoxides in the presence of cryptand[2.2.2] in benzene proceeded in a living manner, especially when using potassium (-)-menthoxide. The molecular weights of the polysilanes thus obtained were in good agreement with the calculated values. (C) 2000 Published by Elsevier Science S.A. All rights reserved.