[Mn(hexafluoroacetylacetonate)2((CH2NH(2,2,6,6-tetramethylpiperidinyl-1-oxy))2)] | 956408-79-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: [Mn(hexafluoroacetylacetonate)2((CH2NH(2,2,6,6-tetramethylpiperidinyl-1-oxy))2)]
• 英文别名: [Mn(hfac)2((CH2NH(C5H5N)(O)(CH3)4)2)]
• CAS: 956408-79-0
• 化学式: C₃₀H₄₂F₁₂MnN₄O₆
• 分子量: 837.606
• InChiKey: FHEFGKBJMFZIKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(haxafluoroacetylacetonato)manganese(II) trihydrate 、 4,4'-(ethane-1,2-diyldiimino)bis(2,2,6,6-tetramethylpiperidin-1-oxidanyl) 以 甲醇 、 二氯甲烷 为溶剂， 以44%的产率得到[Mn(hexafluoroacetylacetonate)2((CH2NH(2,2,6,6-tetramethylpiperidinyl-1-oxy))2)]
  参考文献：
  名称：

  Structures and magnetic properties of Mn(hfac)2 complexes derived from Bis-TEMPO-substituted diamines

  摘要：

  Structures and properties of three Mn(hfac)(2) (hfac = hexafluoroacetylacetonate) complexes derived from two kinds of bis-TEMPO (2,2,6,6-tetramethylpiperdinyl-1-oxy)-substituted diamines are reported. In a complex derived from bis-TEMPO-substituted ethylenediamine, the unit is coordinated to the manganese atom to afford a spin system with weak antiferromagnetic intermolecular interactions, while apparent ligations of both TEMPO groups to the metal atom are observed in a couple of Mn(hfac)2 complexes derived from bis-TEMPO-substituted piperadine to result in spin systems with fairly large antiferromagnetic interactions. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.005