(E)-hept-4-en-2-yne | 128459-52-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (E)-hept-4-en-2-yne
• CAS: 128459-52-9
• 化学式: C₅H₅LiO
• 分子量: 88.0351
• InChiKey: YEGKXOAXIYVFJQ-FXRZFVDSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.28
• 重原子数：
  7.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (4R,5S)-2,2-dimethyl-5-pentyl-1,3-dioxolane-4-carbaldehyde 、 (E)-hept-4-en-2-yne 生成 (2E,4E)-5-((4S,5S)-2,2-Dimethyl-5-pentyl-[1,3]dioxolan-4-yl)-penta-2,4-dienal
  参考文献：
  名称：

  Synthesis of lipoxin b

  摘要：

  DOI：

  10.1016/s0040-4039(00)84105-2

文献信息

• Synthesis of the spiroketal fragment of avermectin B1b
  作者：Michael T. Crimmins、Rosemary O'Mahony

  DOI：10.1016/s0040-4039(01)93836-5

  日期：1989.1

  A new synthesis of the spiroketal fragment of the potent antiparasitic agent, avermectin B1b, utilizing an improved procedure for the preparation of unsaturated spiroketals from lactones is described.

  描述了一种新的有效抗寄生虫药阿维菌素B 1b的螺环酮片段的合成方法，该方法利用一种改进的方法从内酯制备不饱和螺环酮。
• Wrackmeyer, Bernd; Kundler, Sabine; Milius, Wolfgang, Chemische Berichte, 1994, vol. 127, # 2, p. 333 - 342
  作者：Wrackmeyer, Bernd、Kundler, Sabine、Milius, Wolfgang、Boese, Roland

  DOI：——

  日期：——
• New phosphabenzenes by [4 + 2] cycloaddition of stannoles to 1-phospha-1-alkynes — determination of signs of coupling constants
  作者：Bernd Wrackmeyer、Uwe Klaus

  DOI：10.1016/0022-328x(96)06316-4

  日期：1996.8

  Stannoles bearing dialkylboryl groups in 3-position react with 1-phospha-1-alkynes P=C-(t)Bu (1) and P=C-CH(2)(t)Bu (2) by [4 + 2] cycloaddition and elimination of stannylene to give phosphabenzenes in high yield. The stannylenes oligomerise to give [R(2)(1)Sn](n) with n greater than or equal to 7 (R = Me, Et, -(CH2)(5)- or, in the case of R(1) = (t)Bu, react with the stannole itself. All phosphabenzenes are characterised by their consistent sets of NMR data. The absolute signs of the coupling constants (n)J(P-31, H-1), (n)J(P-31, C-13), (2)J(P-31, Si-29) and (2)J(Sn-119, P-31) were determined by appropriate 1D and 2D NMR experiments.
• CRIMMINS, MICHAEL T.;OMAHORY, ROSEMARY, TETRAHEDRON LETT., 30,(1989) N4, C. 5993-5996
  作者：CRIMMINS, MICHAEL T.、OMAHORY, ROSEMARY

  DOI：——

  日期：——
• CRIMMINS, MICHAEL T.;HOLLIS, W. GARY, JR.;BANKAITIS-DAVIS, DANUTE M., TETRAHEDRON LETT., 28,(1987) N 32, 3651-3654
  作者：CRIMMINS, MICHAEL T.、HOLLIS, W. GARY, JR.、BANKAITIS-DAVIS, DANUTE M.

  DOI：——

  日期：——