4-Formyl-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid) | 177536-55-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-Formyl-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid)
• CAS: 177536-55-9
• 化学式: C₁₅H₁₅N₃O₄S
• 分子量: 333.368
• InChiKey: YZMMKIRJSUNLST-ISLYRVAYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.83
• 重原子数：
  23.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  97.19
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  4-Formyl-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid) 在 potassium carbonate 作用下， 以 丙酮 、 甲苯 为溶剂， 反应 17.5h， 生成 4-(1'',3''Dioxolan-2''-yl)-2-methoxyazobenzol-4'-(N-allyl-N-methylsulfonsaeureamid)
  参考文献：
  名称：

  Synthese und Solvatochromie einiger Azofarbstoffe mit Ferrocen als Elektronendonor-Gruppe f�r die optische Datenspeicherung

  摘要：

  We synthesized the arylazo compounds 3a-c, 5a,b, 5d, 5f, 6b, 6d, 6f, 7-9 containing ferrocene as electron donor group and different electron accepters or donors in order to tune the absorption wavelength. Compounds 5f, 6f, 8, 9 were incorporated as side chains in liquid crystalline polymers. As holographic experiments showed these materials are not superior to polymers containing arylazochromophores without the ferrocene moiety like compounds 10, 11. In addition, the solvatochromism of the ferrocene azo compounds has been measured as a first test of their first order NLO activity. Only compound 9 showed remarkable values.

  DOI：

  10.1002/prac.19963380126
• 作为产物：
  描述：

  4-硝基-N-甲基-苯磺酰胺 在 sodium hydroxide 、 氯化铵 、 锌 作用下， 以 水 、 溶剂黄146 为溶剂， 反应 48.67h， 生成 4-Formyl-2-methoxyazobenzol-4'-(N-methylsulfonsaeureamid)
  参考文献：
  名称：

  Synthese und Solvatochromie einiger Azofarbstoffe mit Ferrocen als Elektronendonor-Gruppe f�r die optische Datenspeicherung

  摘要：

  We synthesized the arylazo compounds 3a-c, 5a,b, 5d, 5f, 6b, 6d, 6f, 7-9 containing ferrocene as electron donor group and different electron accepters or donors in order to tune the absorption wavelength. Compounds 5f, 6f, 8, 9 were incorporated as side chains in liquid crystalline polymers. As holographic experiments showed these materials are not superior to polymers containing arylazochromophores without the ferrocene moiety like compounds 10, 11. In addition, the solvatochromism of the ferrocene azo compounds has been measured as a first test of their first order NLO activity. Only compound 9 showed remarkable values.

  DOI：

  10.1002/prac.19963380126