vanadium oxytriiodide | 22308-44-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: vanadium oxytriiodide
• CAS: 22308-44-7
• 化学式: I₃OV
• 分子量: 447.654
• InChiKey: YPQBIZLNYDAIPY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.54
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  三氯一氧化钒 三氯代氧化钒(V) 、 potassium iodide 以 neat (no solvent) 为溶剂， 生成 vanadium oxytriiodide
  参考文献：
  名称：

  The gas-phase on-line production of vanadium oxytrihalides, VOX3 and their identification by infrared spectroscopy

  摘要：

  A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI at 375, 700 and 550 degreesC, respectively. The products have been characterized by the IR spectra of their vapors. The low resolution gas phase on-line Fourier transform infrared spectra reported for the first time show strong bands with PQR type structure, centered at 1058, 1035, 1030 and 1025 cm(-1) assigned to the v(1)(a(1)), the O=V stretching fundamental mode of VOF3, VOCl3, VOBr3 and VOI3, respectively. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00305-x