[Ag(5,6,7-trimethyl-[1,2,4]triazolo[1,5-a]pyrimidine)(NO3)]2 | 1267687-75-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡唑并三嗪类
• 英文名称: [Ag(5,6,7-trimethyl-[1,2,4]triazolo[1,5-a]pyrimidine)(NO3)]2
• 英文别名: [Ag(tmtp)(NO3)]2
• CAS: 1267687-75-1
• 化学式: C₁₆H₂₀Ag₂N₁₀O₆
• 分子量: 664.135
• InChiKey: ZBJLNCXWOLKNPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,6,7-trimethyl-1,2,4-triazolo[1,5-a]pyrimidine 、 silver nitrate 以 乙醇 为溶剂， 生成 [Ag(5,6,7-trimethyl-[1,2,4]triazolo[1,5-a]pyrimidine)(NO3)]2
  参考文献：
  名称：

  A dinuclear silver compound with 5,6,7-trimethyl-[1,2,4]triazolo[1,5-a]pyrimidine with a short Ag–Ag bond. Synthesis, characterization, single-crystal structure analysis and cytostatic activity

  摘要：

  A new dinuclear coordination compound with the ligand 5,6,7-trimethyl[1,2,4] triazolo[1,5-a]pyrimidine (abbreviated as tmtp) is described, together with its 3D crystal structures and spectroscopic properties. The compound shows a high cytostatic activity in ovarian cancer cell lines.The solid state structure of the compound is dinuclear based, in which the ligand tmtp uses two nitrogens (N3 and N4) to chelate to two different Ag(I) ions. The Ag-Ag distance is relatively short (3.109 angstrom), but is considered as too long for M-M bonding. The Ag(I) coordination is completed by weakly coordinated, asymmetric bidentate nitrate anions (Ag-O = 2.481-2.819 angstrom). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.014