3,7-Dimethyl-6-methylthiooct-7-en-1-ol acetate | 161013-76-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子
• 英文名称: 3,7-Dimethyl-6-methylthiooct-7-en-1-ol acetate
• 英文别名: 3,7-dimethyl-6-methylthio-7-octen-1-ol acetate；6-methylthio-3,7-dimethyl-7-octen-1-ol acetate；(3,7-dimethyl-6-methylsulfanyloct-7-enyl) acetate
• CAS: 161013-76-9
• 化学式: C₁₃H₂₄O₂S
• 分子量: 244.398
• InChiKey: TZGSPCPSOZQBFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.66
• 重原子数：
  16.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  3,7-Dimethyl-6-methylthiooct-7-en-1-ol acetate 在 吡啶 、 sodium methylate 、 lithium perchlorate 、 silver methanesulfonate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 0.5h， 生成 Acetic acid (Z)-3,7,11-trimethyl-9-methylsulfanyl-dodeca-6,10-dienyl ester
  参考文献：
  名称：

  A new approach to the C5-homologation of linear monoterpenols

  摘要：

  Both possible geometric isomers of 9-oxo-2,3-dihydrofarnesyl acetate, which are structurally related to the natural linear sesquiterpenes bearing the keto-function at position 9, have been prepared by a six-stage procedure starting from citronellyl acetate.

  DOI：

  10.1007/bf00699158
• 作为产物：
  描述：

  (6-acetoxy-1-isopropenyl-4-methylhexyl)dimethylsulfonium perchlorate 在 哌啶 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以77%的产率得到3,7-Dimethyl-6-methylthiooct-7-en-1-ol acetate
  参考文献：
  名称：

  A new approach to the C5-homologation of linear monoterpenols

  摘要：

  Both possible geometric isomers of 9-oxo-2,3-dihydrofarnesyl acetate, which are structurally related to the natural linear sesquiterpenes bearing the keto-function at position 9, have been prepared by a six-stage procedure starting from citronellyl acetate.

  DOI：

  10.1007/bf00699158

文献信息

• Some peculiarities of the preparative electroreduction of allyldimethylsulfonium salts
  作者：L. M. Korotaeva、T. Ya. Rubinskaya、V. P. Gultyai

  DOI：10.1007/bf00698242

  日期：1994.7

  yl-4-methylhexyl)dimethylsulfonium perchlorate concentration on the yield of α-citronellyl acetate and the selectivity of reduction were studied. A mechanism of electrolytic reduction involving preparative electrolysis on a mercury cathode at potentials of the first and second waves was proposed.

  研究了电极电位和高氯酸(6-乙酰氧基-1-异丙烯基-4-甲基己基)二甲基锍浓度对醋酸α-香茅酯收率和还原选择性的影响。提出了一种电解还原机制，包括在第一波和第二波电位下在汞阴极上进行制备电解。
• An ene-type reaction between an unactivated olefin and an ?activated? sulfoxide, and some properties of the resulting sulfonium salts
  作者：A. M. Moiseenkov、V. A. Dragan、V. V. Veselovskii

  DOI：10.1007/bf00953620

  日期：1989.2
• MOISEENKOV, A. M.;DRAGAN, V. A.;VESELOVSKIJ, V. V., IZV. AN CCCP. CEP. XIM.,(1989) N, S. 365-372
  作者：MOISEENKOV, A. M.、DRAGAN, V. A.、VESELOVSKIJ, V. V.

  DOI：——

  日期：——