N-[chloro(dimethyl)silyl]-N-(chloro-ethenyl-methylsilyl)methanamine | 214844-42-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-[chloro(dimethyl)silyl]-N-(chloro-ethenyl-methylsilyl)methanamine
• CAS: 214844-42-5
• 化学式: C₆H₁₅Cl₂NSi₂
• 分子量: 228.269
• InChiKey: IIPFFPUUTRKDLC-UHFFFAOYSA-N

物化性质

• 沸点：
  194.772±13.00 °C(Press: 760.00 Torr)(predicted)
• 密度：
  1.018±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.89
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  叔丁胺 、 N-[chloro(dimethyl)silyl]-N-(chloro-ethenyl-methylsilyl)methanamine 以 正己烷 为溶剂， 反应 4.0h， 以83%的产率得到C₁₄H₃₅N₃Si₂
  参考文献：
  名称：

  SYNTHESIS OF 1,3-DICHLORO 1,2,3,3-TETRAMETHYL, 1-VINYL DISILAZANE AND ITS REACTIONS WITH PRIMARY AMINES

  摘要：

  Silazadiamines H(Me)N[(Me)(2)Si]N(Me)[Si(Me)(CH2 = CH)]N(Me)H (II) H(n-Pr)N[(Me)(2)Si]N-(Me)[Si(Me)(CH2 = CH)]N(n-Pr)H (III) and H(Bu-t)N[(Me)(2)Si] N(Me) [Si(Me)(CH2 = CH)]N(Bu-t)H (IV) having one vinyl group attached to one of the silicon atoms were prepared by the reaction of 1,3-dichloro 1,2,3,3-tetramethyl 1-vinyl disilazane (I) with methylamine, n-propylamine and t-butylamine respectively. The latter was prepared by the ring opening reaction of nonamethylcyclotrisilazane with dichloromethyl vinyl silane, The compounds were purified by vacuum distillation and characterized by IR,H-1 NMR and mass spectral analysis.

  DOI：

  10.1080/10426509708033711
• 作为产物：
  描述：

  甲基乙烯基二氯硅烷 、 1,2,2,3,4,4,5,6,6-Nonamethyl-[1,3,5,2,4,6]triazatrisilinane 反应 72.0h， 以46%的产率得到N-[chloro(dimethyl)silyl]-N-(chloro-ethenyl-methylsilyl)methanamine
  参考文献：
  名称：

  SYNTHESIS OF 1,3-DICHLORO 1,2,3,3-TETRAMETHYL, 1-VINYL DISILAZANE AND ITS REACTIONS WITH PRIMARY AMINES

  摘要：

  Silazadiamines H(Me)N[(Me)(2)Si]N(Me)[Si(Me)(CH2 = CH)]N(Me)H (II) H(n-Pr)N[(Me)(2)Si]N-(Me)[Si(Me)(CH2 = CH)]N(n-Pr)H (III) and H(Bu-t)N[(Me)(2)Si] N(Me) [Si(Me)(CH2 = CH)]N(Bu-t)H (IV) having one vinyl group attached to one of the silicon atoms were prepared by the reaction of 1,3-dichloro 1,2,3,3-tetramethyl 1-vinyl disilazane (I) with methylamine, n-propylamine and t-butylamine respectively. The latter was prepared by the ring opening reaction of nonamethylcyclotrisilazane with dichloromethyl vinyl silane, The compounds were purified by vacuum distillation and characterized by IR,H-1 NMR and mass spectral analysis.

  DOI：

  10.1080/10426509708033711