[Ag(trifluoroacetate)(As(cyclohexyl)3)(2,2'-bipyridyl)] | 935509-79-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯嗪
• 英文名称: [Ag(trifluoroacetate)(As(cyclohexyl)3)(2,2'-bipyridyl)]
• 英文别名: [Ag(tfa)(Ascy3)(bpy)]
• CAS: 935509-79-8
• 化学式: C₃₀H₄₁AgAsF₃N₂O₂
• 分子量: 701.453
• InChiKey: MDIIUOUYKRVICL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 tricyclohexyl-arsine 、 silver trifluoroacetate 以 乙腈 为溶剂， 以78%的产率得到[Ag(trifluoroacetate)(As(cyclohexyl)3)(2,2'-bipyridyl)]
  参考文献：
  名称：

  Synthesis and structural characterization of adducts of silver(I) carboxylate salts AgX (X=CF3COO, CH3COO) with ER3 (E=P, As; R=Ph, cy, o-tolyl) and oligodentate aromatic bases derivative of 2,2′-bipyridyl, L, AgX:PR3:L (1:1:1)

  摘要：

  Twenty-one adducts of the form AgX:ER3:L (1: 1: 1) (X = CF3COO 'tfa'), CH3COO ('ac'), E = P, As; R = Ph, cy, o-tolyl; L = 2,2'bipyridyl ('bpy')-based ligand) have been synthesized and characterized by analytical, spectroscopic (IR, far-IR, H-1, F-19 and P-31 NMR) and single crystal X-ray diffraction studies. The resulting complexes are predominantly of the form [(R3E)AgL]X+-, with a trigonal EAgN2 coordination environment, the planarity of which may be perturbed by the approach of anion or solvent. The carboxylate anions have been found to be uni-, or semi-bidentate, or also completely ionic, as in the complexes [Ag(PPh3)(bpy)(H2O)](tfa) and [Ag(PPh3)(dpk (.) H2O(tfa) ('dpk - H2O' = bis(2-pyridyl)ketone (hydrated)). The complexes Agac:PPh3:dpa (1: 1: 1) and Agac:P(o-tol)(3): dpa:MeCN (1: 1: 1: 1) are dinuclear, with bridging unidentate acetate and terminal unidentate dpa ('dpa' = bis(2-pyridyl)amine). (c) 2006 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2006.07.015