cobalt(2+);[diphenylphosphanylmethyl(dimethyl)silyl]methyl-diphenylphosphane;diisothiocyanate | 202408-11-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: cobalt(2+);[diphenylphosphanylmethyl(dimethyl)silyl]methyl-diphenylphosphane;diisothiocyanate
• CAS: 202408-11-5
• 化学式: C₃₀H₃₀CoN₂P₂S₂Si
• 分子量: 631.74
• InChiKey: ZHJBOLUEQKNJQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(diphenylphosphinomethyl)dimethylsilane 、 cobalt(II) thiocyanate 以 乙醇 、 二氯甲烷 为溶剂， 以62%的产率得到cobalt(2+);[diphenylphosphanylmethyl(dimethyl)silyl]methyl-diphenylphosphane;diisothiocyanate
  参考文献：
  名称：

  Structural and spectroscopic studies of cobalt(II) complexes incorporating the bidentate phosphine ligand Ph2PCH2Si(CH3)2CH2PPh2

  摘要：

  A series of cobalt(II) complexes of general formula [CoX2L2] (X = Cl, Br, I, NO3, ClO4, NCS; L-2 = Ph2PCH2Si(CH3)(2)CH2PPh2) have been synthesised and characterised by electronic and infrared spectroscopy and by magnetic moment studies. The bidentate phosphine ligand is an analogue of 1,3-bis(diphenylphosphino)propane (dppp). X-ray analysis of the [CoBr2L2] complex proves tetrahedral geometry at the metal centre with the bidentate phosphine exhibiting a bite angle of 101.54(6)degrees. A range of evidence supports the existence of tetrahedral geometry about the metal in all the complexes in both the solid state and solution. Electronic spectroscopy is diagnostic for the tetrahedral d(7) metal ion in each case, with the nu(2) and nu(3) transitions clearly visible. Calculations of D-q and B', the RACAH parameter, have been performed for each complex; the relative magnitudes of B' indicate that the metal-phosphorus bonds are of increased covalency in comparison with Co(dppp) analogues. Magnetic moment studies show values of mu(B), in the range 4.4-4.9 B.M., as expected for tetrahedral cobalt(II). IR studies show that the nitrate and perchlorate ions in the respective complexes are bound in monodentate fashion, while the [Co(NCS)(2)(L-2)] complex exhibits N-bonded thiocyanate groups. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00273-8