bis(μ-η(2)-thianthrene)disilver(I) bis(perchlorate) | 205746-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二硫类化合物
• 英文名称: bis(μ-η(2)-thianthrene)disilver(I) bis(perchlorate)
• 英文别名: Disilver;thianthrene;diperchlorate
• CAS: 205746-16-3
• 化学式: C₂₄H₁₆Ag₂Cl₂O₈S₄
• 分子量: 847.293
• InChiKey: UNNVPHGDTXWJOE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.91
• 重原子数：
  40
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  250
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  silver perchlorate 、 噻蒽 以 四氢呋喃 为溶剂， 生成 bis(μ-η(2)-thianthrene)disilver(I) bis(perchlorate)
  参考文献：
  名称：

  Synthesis and structure of a novel bis(μ-η2-thianthrene)disilver(I) bis(perchlorate)

  摘要：

  A novel bis(thianthrene)disilver(I)bis(perchlorate), [Ag-2(TA)(2)(ClO4)(2)] (1) (TA = thianthrene), was prepared and characterized by single-crystal X-ray diffraction methods, H-1 and C-13 NMR: IR and UV spectra analysis. Complex 1 is triclinic, space group , a = 9.244(1), b = 9.275(1), c = 8.343(2) Angstrom, alpha = 101.22(1)degrees, beta = 110.63(1)degrees, gamma = 97.15(i)degrees, V = 679.8(2) Angstrom(3), Z = 2, R = 0.028 and R-w = 0.042. The silver is tetrahedrally coordinated to an oxygen of ClO4-, a phenylene ring of one TA, and to two sulfur atoms of the other TA. The average distance of silver to the phenylene ring in complex 1 is 2.55 Angstrom. Both H-1 and C-13 NMR Studies indicate that the silver-phenylene ring bond is broken in acetone solution. The complex 1 is an insulator, while the I-2-doped blue complex shows a new absorption band at 478 nm and an electric conductivity of 5.0 x 10(-4) S cm(-1). (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05953-7