[Ru(II)Cl(CO)(PMe3)3]2(μ-CH=CH-C6H2(O-n-C6H13)2-CH=CH) | 1215068-98-6

• 英文名称: [Ru(II)Cl(CO)(PMe3)3]2(μ-CH=CH-C6H2(O-n-C6H13)2-CH=CH)
• CAS: 1215068-98-6
• 化学式: C₄₂H₈₆Cl₂O₄P₆Ru₂
• 分子量: 1114.03
• InChiKey: DROXDAWTYMBPSJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 1,4-diethynyl-2,5-bis-hexyloxy-benzene 、 三甲基膦 以 四氢呋喃 、 二氯甲烷 为溶剂， 以48%的产率得到[Ru(II)Cl(CO)(PMe3)3]2(μ-CH=CH-C6H2(O-n-C6H13)2-CH=CH)
  参考文献：
  名称：

  Bimetallic Ruthenium Complexes: Synthesis, Characterization, and the Effect of Appending Long Carbon Chains to Their Bridges

  摘要：

  A series of binuclear ruthenium complexes [RuCl(CO)(PMe3)(3)](2)(mu-CH=CH-Ar-CH=CH) (Ar = C6H2(OR)(2)-2,5; R = CH3 (4a), (C4H9)-C-n (4b), (C6H13)-C-n (4c), (C8H17)-C-n (4d), (C10H21)-C-n (4e), (C12H25)-C-n (4f), (C14H29)-C-n (4g)), [RuCl(CO)(PMe3)(3)](2)(mu-CH=CH-Ar--Ar-CH=CH) (Ar = C6H2(R)(2)-2,5; R = OCH3 (10a), (OC8H17)-C-n (10b), H (10c)), and [RuCl(CO)(PMe3)(3)](2)(mu-CH=CH-Ar--Ar--Ar-CH=CH) (Ar = C6H2(R)(2)-2,5; R = OCH3 (13a), (OC8H17)-C-n (13b), H (13c)) have been synthesized. These complexes have been characterized by elemental analysis, NMR, and UV/vis spectrophotometry. The structures of 4b and 4d have been determined by X-ray crystallography. Electrochemical studies have shown that long carbon chains attached to the bridges of the complexes facilitate the stability of mixed-valence bimetallic ruthenium complexes.

  DOI：

  10.1021/om901025q