N,N'-dihexyl-[1,3,5]triazine-2,4,6-triamine | 30072-53-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: N,N'-dihexyl-[1,3,5]triazine-2,4,6-triamine
• 英文别名: 2-N,4-N-dihexyl-1,3,5-triazine-2,4,6-triamine
• CAS: 30072-53-8
• 化学式: C₁₅H₃₀N₆
• 分子量: 294.443
• InChiKey: BDFVHIQFWIGDBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-氨基-4,6-二氯-S-三嗪 、 正己胺 在 碳酸氢钠 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 生成 N,N'-dihexyl-[1,3,5]triazine-2,4,6-triamine
  参考文献：
  名称：

  Hierarchical Self-Organization of Perylene Bisimide–Melamine Assemblies to Fluorescent Mesoscopic Superstructures

  摘要：

  A series of three perylene tetracarboxylic acid bisimide dyes 3a-c bearing phenoxy substituents at the four bay positions of the perylene core were synthesized and their complexation behavior to complementary ditopic dialkyl melamines 8a-c was investigated. Binding constants and Gibbs binding energies for the hydrogen bonds between the imide and the complementary melamine moiety have been determined in several solvents by NMR and UV/Vis titration experiments with monotopic model compounds 5 and 9. The effects of the solvent polarity and specific solvent-solute interactions on the degree of polymerization of (3.8)(n), are discussed, and a general formula to estimate the chain length of [AA - BB](n) nylon-type supramolecular polymers is derived. In addition to the formation of a hydrogen-bonded supramolecular chain, pi-pi interactions were observed for perylene bisimide - melamine assemblies 3b.8b and 3b.8c in aliphatic solvents. The orthogonal nature of hydrogen bonding and pi-pi interactions leads to three-dimensional growth yielding large-sized aggregates already in dilute solution. On suitable substrates, densely intertwined networks of nano- to mesoscopic strands are formed which have been investigated by electron microscopy, confocal fluorescence microscopy and optical polarization microscopy. The high fluorescence and excellent photostability of these superstructures is promising for future studies on energy migration and artificial light harvesting at the nano- and mesoscopic length scale.

  DOI：

  10.1002/1521-3765(20001103)6:21<3871::aid-chem3871>3.3.co;2-w

文献信息

• VERFAHREN ZUR HERSTELLUNG EINER VERBINDUNG MIT MINDESTENS EINER ZUMINDEST EINFACH SUBSTITUIERTEN AMINOGRUPPE
  申请人：Borealis Agrolinz Melamine GmbH

  公开号：EP2268610A1

  公开（公告）日：2011-01-05
• Method for Producing a Compound with at Least One at Least Monosubstituted Amino Group
  申请人：Dicke Rene

  公开号：US20110178212A1

  公开（公告）日：2011-07-21

  The invention relates to a method for producing at least one compound having at least one at least monosubstituted amino group. According to the invention, a starting substance having at least one amino group is reacted with an alcohol in a reaction mixture in the presence of ammonia.
• US8871842B2
  申请人：——

  公开号：US8871842B2

  公开（公告）日：2014-10-28
• [DE] VERFAHREN ZUR HERSTELLUNG EINER VERBINDUNG MIT MINDESTENS EINER ZUMINDEST EINFACH SUBSTITUIERTEN AMINOGRUPPE<br/>[EN] METHOD FOR PRODUCING A COMPOUND WITH AT LEAST ONE AT LEAST MONOSUBSTITUTED AMINO GROUP<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN COMPOSÉ AYANT AU MOINS UN GROUPE AMINO AU MOINS MONOSUBSTITUÉ
  申请人：BOREALIS AGROLINZ MELAMINE GMB

  公开号：WO2009121603A1

  公开（公告）日：2009-10-08

  Die Erfindung betrifft ein Verfahren zur Herstellung einer Verbindung mit mindestens einer zumindest einfach substituierten Aminogruppe. Erfindungsgemäß wird dazu eine mindestens eine Aminogruppe tragende Ausgangssubstanz mit einem Alkohol in einer Reaktionsmischung in Gegenwart von Ammoniak umgesetzt.