N-[methyl-(methylamino)-phenylsilyl]methanamine | 17864-80-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-[methyl-(methylamino)-phenylsilyl]methanamine
• CAS: 17864-80-1
• 化学式: C₉H₁₆N₂Si
• 分子量: 180.325
• InChiKey: PEXMKRNOXXXMLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-二甲基-1,1,2,2-四氯二硅烷 、 N-[methyl-(methylamino)-phenylsilyl]methanamine 生成 1,2,3,3a,4,5,6,6a-Octamethyl-2,5-diphenyl-octahydro-1,3,4,6-tetraaza-2,3a,5,6a-tetrasila-pentalene
  参考文献：
  名称：

  双环[3.3.0] -tetrasila-1,3,5,7-四z烷

  摘要：

  通过双（烷基氨基）硅烷与1,2-二甲基四氯乙硅烷的反应，首次制备了双环[3.3.0]四硅-1,3,5,7-四硅氮烷（A）。描述了化合物A的性质。从1 H NMR光谱和X-射线结构分析，特别是Si-六甲基-N-四甲苯基取代的化合物，建议双环结构优先于双（环二硅氮烷基）结构。

  DOI：

  10.1016/s0022-328x(00)87862-6

文献信息

• Multinucleus NMR characterization of new silylamines and their corresponding lithium silylamides
  作者：S Bruzaud、A.-F Mingotaud、A Soum

  DOI：10.1016/s0022-328x(98)00506-3

  日期：1998.6

  A series of linear silylamines R'Me2Si-NMe-SiMe(R)-NHMe (R, R' = Me, Vi or Ph) has been synthesized, as well as their corresponding lithium silylamides. They all have been analyzed by H-1-,C-13-, Si-29-, N-15- and Li-7-NMR, in order to characterize the changes of electronic density in the molecules induced either by the silicon group or by the formation of the negative charge on the nitrogen atom. These changes give information about the nature of the [Si-N] or [Si-C] bonds. More particularly, a strong influence of the vinyl group on [-MeViSi-NHMe] has been observed, both in the silylamine and the corresponding silylamide. Indeed, in this case, the variations of the chemical shifts might be related to a 'delocalization' of the negative charge from nitrogen to silicon and the vinyl group. (C) 1998 Elsevier Science S.A. All rights reserved.
• Bicyclo[3.3.0]-tetrasila-1,3,5,7-tetrazane
  作者：Ulrich Wannagat、Siegbert Klemke、Dietrich Mootz、Horst Dieter Reski

  DOI：10.1016/s0022-328x(00)87862-6

  日期：1979.9

  Bicyclo[3.3.0]tetrasila-1,3,5,7-tetrasilazanes (A) are prepared, for the first time, by the reaction of bis(alkylamino)silanes with 1,2-dimethyltetrachlorodisilane. The properties of compounds A are described. From 1H NMR spectra and X-ray structure analysis, especially of the Si-hexamethyl-N-tetratolyl substituted compounds, the bicyclic structure is suggested in preference of a bis(cyclodisilazanyl)

  通过双（烷基氨基）硅烷与1,2-二甲基四氯乙硅烷的反应，首次制备了双环[3.3.0]四硅-1,3,5,7-四硅氮烷（A）。描述了化合物A的性质。从1 H NMR光谱和X-射线结构分析，特别是Si-六甲基-N-四甲苯基取代的化合物，建议双环结构优先于双（环二硅氮烷基）结构。